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Hydrochemical Characterization,Controlling Factors and Water Quality of Surface Water in Shandong Province,North China

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Journal of Earth Science 2024年第1期35卷 155-166页

作者： Ran An Jiutan Liu Zongjun Gao Changsuo Li Yuming Peng School of Earth Sciences and Resources China University of GeosciencesBeijing 100083China college of Earth Science and Engineering Shandong University of Science and TechnologyQingdao 266590China 801.Institute of Hydrogeology and Engineering geology Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Key Laboratory of Groundwater Resources and Environment Shandong Provincial Bureau of Geology&Mineral ResourcesJinan 250014China Shandong Engineering Research Center for Groundwater Environmental Protection and Remediation Jinan 250014China

In this study,90 surface water samples were collected from Shandong Province(SDP)in the dry and wet seasons and analyzed using statistical analysis,hydrochemical methods and water quality index(WQI).The content of main ions showed seasonal variations,with a higher average value in the dry season than in the wet *** points exhibiting high contents of the main chemical components were mainly distributed in areas southwest of SDP,north of Weifang,and around *** saturation index of carbonate minerals was greater than zero,while that of evaporite minerals was less than *** hydrochemical characteristics of surface water are mainly dominated by rock weathering as well as cation *** addition,surface water in SDP has significantly been affected by anthropogenic *** of the surface water could be classified as weakly alkaline soft-fresh water,with the hydrochemical types of SO_(4)·Cl-Ca·Mg and SO_(4)·*** terms of WQI,47.88% and 37.88% of the water samples in SDP were classified as poor water in the dry and wet seasons,*** the whole,the water quality is higher in the wet season than in the dry season,and surface water in SDP is generally suitable for agricultural irrigation.

关键词： surface water hydrochemical characteristics controlling factors water quality Shandong Province

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Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs

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Petroleum Science 2024年第4期21卷 2485-2501页

作者： Zhao-Bin Zhang Maryelin Josefina Brice?o Montilla Shou-Ding Li Xiao Li Jian-Peng Xing Yan-Zhi Hu Key Laboratory of Shale Gas and Geoengineering Institute of Geology and Geophysics Chinese Academy of Sciences Institute of Earth Sciences Chinese Academy of Sciences college of Earth and Planetary Sciences University of Chinese Academy of Sciences Institute of Energy Peking University

In-situ conversion presents a promising technique for exploiting continental oil shale formations,characterized by highly fractured organic-rich rock. A 3D in-situ conversion model, which incorporates a discrete fracture network, is developed using a self-developed thermal-flow-chemical(TFC) *** of the model elucidates the in-situ conversion process in three stages and defines the transformation of fluids into three distinct outcomes according to their end stages. The findings indicate that kerogen decomposition increases fluid pressure, activating fractures and subsequently enhancing permeability. A comprehensive analysis of activated fracture permeability and heating power reveals four distinct production modes, highlighting that increasing heating power correlates with higher cumulative fluid production. Activated fractures, with heightened permeability, facilitate the mobility of heavy oil toward production wells but hinder its cracking, thereby limiting light hydrocarbon ***, energy efficiency research demonstrates the feasibility of the in-situ conversion in terms of energy utilization, especially when considering the surplus energy from high-fluctuation energy sources such as wind and solar power to provide heating.

关键词： In-situ conversion Continental shale oil Natural fracture network TFC model

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Method to measure tree-ring width,density,elemental composition,and stable carbon and oxygen isotopes using one sample

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Journal of Forestry Research 2024年第3期35卷 167-174页

作者： Chenxi Xu Yaru Zhao Wenling An Qingyu Zhao Yucheng Liu Masaki Sano Takeshi Nakatsuka Key Laboratory of Cenozoic geology and Environment Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029People's Republic of China CAS Center for Excellence in Life and Paleoenvironment Beijing 100044People's Republic of China college of Earth Sciences University of Chinese Academy of SciencesBeijing 100049People's Republic of China Graduate School of Environment Studies Nagoya UniversityNagoya 4648601Japan

Tree-ring width(RW),density,elemental com-position,and stable carbon and oxygen isotope(δ^(1.)C,δ^(1.)O)are widely used as proxies to assess climate change,ecology,and environmental pollution;however,a specific pretreat-ment has been needed for each ***,we developed a method by which each proxy can be measured in the same ***,the sample is polished for ring width *** obtaining the ring width data,the sample is cut to form a 1.mm-thick wood *** sample is then mounted in a vertical sample holder,and gradually scanned by an X-ray ***,the count rates of the fluorescent photons of elements(for chemical characteriza-tion)and a radiographic grayscale image(for wood density)are obtained,*** density and the element content are ***,cellulose is isolated from the 1.mm wood plate by removal of lignin,and *** producing this cellulose plate,cellulose subsamples are separated by knife under the microscope for inter-annual and intra-annual stable carbon and oxygen isotope(δ^(1.)C,δ^(1.)O)*** on this method,RW,density,elemental composition,δ^(1.)C,and δ^(1.)O can be measured from the same sample,which reduces sample amount and treatment time,and is helpful for multi-proxy comparison and combination research.

关键词： Tree-ring width Tree-ring density Tree-ring elemental composition Tree-ring stable carbon and oxygenisotopes

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Intricate Fault Systems in Longmenshan Structural Belt's Northern End: Exploring Structural Evolution and Seismic Rupture Behavior in the Eastern Tibetan Plateau

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Journal of Earth Science 2024年

作者： Hanyu Huang Renqi Lu Dengfa He Jinliang Gao Weikang Zhang Lingyu Kang State Key Laboratory of Earthquake Dynamics， Institute of geology China Earthquake Administration State Key Laboratory of Oil and Gas Reservoir geology and Exploitation， Institute of Sedimentary geology， Chengdu University of Technology college of Energy Resources， China University of Geosciences PetroChina Research Institute of Petroleum Exploration and Development

The Longmenshan Structural Belt on the eastern edge of the Tibetan Plateau experienced the impactful Mw 7.9 2008 Wenchuan earthquake， causing a 350 km surface rupture. Traditional models attribute this to the Beichuan and Pengguan faults， but our research reveals a complex fault system at the northern end， with inconsistencies in surface rupture， aftershock distribution， and focal mechanisms. We integrates shallow geology， active source seismic reflection， and magnetotelluric profiling to establish a deep structural model for the northern end of the Longmenshan Structural Belt. This area exhibits dominant reverse thrust nappe tectonics， and analyzing the tectonic evolution history provides insights into deformation propagation from the orogenic belt toward the Sichuan Basin. Focal mechanism analysis and relocated aftershock data reveals two distinct types of seismogenic structures in the northern end of the Longmenshan Structural Belt. In the middle to northern segments， the reverse fault type is attributed to reactivated pre-existing faults. Conversely， at the northern end， the strike-slip fault type originates from high-angle co-seismic rupture cutting through pre-existing reverse faults. This study enhances our understanding of fault complexity and seismic mechanisms in the northeastern Longmenshan Structural Belt， providing new insights into regional tectonics.

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Distribution, burial fluxes and carbon sink effect of sedimentary organic carbon in the eastern China seas

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Science China Earth Sciences 2024年第10期67卷 3062-3082页

作者： Xuefa SHI Bin WU Shuqing QIAO Zhengquan YAO Limin HU Yazhi BAI Shan HU Jie SHENG Yanguang LIU Shengfa LIU Kunshan WANG Jianjun ZOU Key Laboratory of Marine geology and Metallogeny First Institute of OceanographyMinistry of Natural ResourcesQingdao 266061China Laboratory for Marine geology Qingdao Marine Science and Technology CenterQingdao 266237China Key Laboratory of Deep Sea Mineral Resources Development Shandong Province(Preparatory)Qingdao 266061China Key Laboratory of Submarine Geosciences and Technology College of Marine GeosciencesOcean University of ChinaQingdao 266100China

The ocean is the largest active carbon reservoir on Earth. Organic carbon(OC), as the primary species of carbon sequestration in the ocean, plays an important role in the global carbon cycle through its deposition and burial. In this study,sedimentary OC data from 5796 stations, together with relevant geochemical and sedimentological parameters in the Bohai Sea,Yellow Sea, and East China Sea(BYES) were used to summarize and elucidate the distribution and burial patterns of sedimentary OC, and assess carbon sink effect of sedimentary OC burial. The results show that the OC content in the sediments of the BYES ranges from 0.00% to 2.1.%, with an average content of 0.47%±0.26%. OC content is significantly correlated with finegrained sediments, with an average OC content in mud areas being 39% higher than that in non-mud areas. Modern OC buried in the BYES are mainly deposited in 7 major mud areas, with a total sedimentary OC burial flux of approximately 8.20 Mt C yr^(–1..Among them, the burial flux of biospheric OC is 6.92 Mt C yr^(–1., equivalent to the OC consumption amount of silicate weathering of the 9 major river basins in the eastern China. In its natural state, the annually sequestered OC in the sediments of the eastern China seas is equivalent to 25.37 Mt of atmospheric CO_(2), indicating a significant carbon sink effect. The distribution and burial of terrigenous OC in the BYES are mainly influenced by the large river inputs and complex marine hydrodynamic environment,while human activities such as dam construction have significantly altered the OC burial in these coastal mud areas.

关键词： Sedimentary organic carbon Burial flux Carbon sink effect Carbon cycle Eastern China seas

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First SHRIMP zircon U-Pb dating constraints for the Ediacaran Wenghui Biota

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Journal of Earth Science 2024年

作者： Mingsheng Zhao Feng Tang Giovanni Mussini Yulan Li Heng Zhang Jianshu Chen Linzhi Gao Department of Earth Sciences， University of Cambridge State Key Laboratory of Palaeobiology and Stratigraphy (Nanjing Institute of geology and Palaeontology， CAS) 1.1.Geological Brigade， Guizhou Bureau of geology and Mineral Resources college of Paleontology， Shenyang Normal University Institute of geology， Chinese Academy of Geological Sciences Guizhou Geological Survey

The Ediacaran period records a significant turning point in the evolution of life on Earth， witnessing the rise to ecological dominance of macroscopic tissue-grade organisms. The Wenghui biota from the Doushantuo Formation of South China hosts abundant multicellular algal macrofossils and problematica， some of which might be closely related to taxa from classic late Ediacaran assemblages from South Australia and the White Sea biota of Russia. However， a lack of well-resolved isotopic age estimates has hampered efforts to constrain the timing of appearance of the Wenghui biota， obfuscating its significance to our understanding of Ediacaran macroevolution in the aftermath of the Snowball Earth events. Here， we present the first SHRIMP zircon U-Pb dating results for samples obtained from a laminated tuff ash layer at the base of the Wenghui biota in the Doushantuo Formation， Jiangkou County， Tongren City， Guizhou Province， China. Our analyses yield an age of 595.4 ± 5.3 Ma for the first appearance of Wenghui biota， suggesting that its appearance postdated that of the Lantian- and Weng’an biotas， but preceded that of the Miaohe biota. These newly obtained age proxies offer an independent test of previous isotopic estimates for the age of the Wenghui biota， providing new chronostratigraphic evidence to map the succession of Ediacaran fossil assemblages on the Yangtze Platform during the Doushantuo interval. These data suggest that the Lantian， Weng’an， Wenghui， and Miaohe biotas may record a sequence of biotic assemblages attesting to successive phases in the radiation of Ediacaran macroscopic organisms， particularly macroalgae.

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A wave-shaped electrode flexible sensor capable of sensitively responding to wrinkle excitation for a multifunctional human-computer interaction system

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Nano Research 2024年第5期17卷 4454-4461页

作者： Yongyang Chen Zhiyi Wu Chengcheng Han Zhi Cao Yiran Hu Ping Zhao Yuanyu Wang college of Materials and Metallurgy Guizhou UniversityGuizhou 550025China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400China Geological Brigade 1.5 Bureau of Geology and Mineral Exploration and Development of Guizhou ProvinceGuiyang 550018China

Human-machine interactions(HMIs)have advanced rapidly in recent decades in the fields of healthcare,work,and ***,people with disabilities and other mobility problems do not have corresponding high-tech aids for them to enjoy the convenience of *** this paper,we propose a sensor with a wave-shaped(corrugated)electrode embedded in a friction layer,which exhibits high sensitivity to skin fold excitation and enormous potential in *** to the wave-shaped electrode design,it has no built-in cavities,and its small size allows it to flexibly cope with folds at different *** specifying the carbon nanotube hybrid silicone film as the electrode layer material and silicone film as the friction layer,good electrical output performance,tensile properties,and biocompatibility can be ***,the sensor is tested on various joints and skin folds of the human body,the output signals of which can be distinguished between normal physiological behavior and test *** on this sensor,we designed a medical alarm system,a robotic arm assistive system,and a cell phone application control system for the disabled to help them in the fields of healthcare,work,and *** conclusion,our research presents a feasible technology to enhance HMIs and makes a valuable contribution to the development of high-tech aids for the disabled.

关键词： flexible sensors multifunctionality wrinkle excitation triboelectric nanogenerator human-machine interaction

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Effects of thawing-induced softening on fracture behaviors of frozen rock

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第3期16卷 979-989页

作者： Ting Wang Hailiang Jia Qiang Sun Xianjun Tan Liyun Tang college of {1. and Environment Xi’an University of Science and TechnologyXi’an710054China college of Architecture and Civil Engineering Xi’an University of Science and TechnologyXi’an710054China State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430064China

Due to the presence of ice and unfrozen water in pores of frozen rock,the rock fracture behaviors are susceptible to *** this study,the potential thawing-induced softening effects on the fracture behaviors of frozen rock is evaluated by testing the tension fracture toughness(KIC)of frozen rock at different temperatures(i.e.-20℃,-1.℃,-1.℃,-1.℃,-8℃,-6℃,-4℃,-2℃,and 0℃).Acoustic emission(AE)and digital image correlation(DIC)methods are utilized to analyze the microcrack propagation during *** melting of pore ice is measured using nuclear magnetic resonance(NMR)*** results indicate that:(1.The KIC of frozen rock decreases moderately between-20℃ and-4℃,and rapidly between-4℃ and 0℃.(2)At-20℃ to-4℃,the fracturing process,deduced from the DIC results at the notch tip,exhibits three stages:elastic deformation,microcrack propagation and microcrack ***,at-4℃e0℃,only the latter two stages are observed.(3)At-4℃e0℃,the AE activities during fracturing are less than that at-20℃ to-4℃,while more small events are reported.(4)The NMR results demonstrate a reverse variation trend in pore ice content with increasing temperature,that is,a moderate decrease is followed by a sharp decrease and-4℃ is exactly the critical ***,we interpret the thawing-induced softening effect by linking the evolution in microscopic structure of frozen rock with its macroscopic fracture behaviors as follow:from-20℃ to-4℃,the thickening of the unfrozen water film diminishes the cementation strength between ice and rock skeleton,leading to the decrease in fracture ***-4℃ to 0℃,the cementation effect of ice almost vanishes,and the filling effect of pore ice is reduced significantly,which facilitates microcrack propagation and thus the easier fracture of frozen rocks.

关键词： Frozen sandstone Different thawing temperature Fracture toughness Microcrack propagation process Unfrozen water content

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A novel dandelion-based bionic proppant and its transportation mechanism in different types of fractures

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Petroleum Science 2024年第4期21卷 2583-2599页

作者： Jun Li Ming-Yi Wu Xu Han Si-Yuan He Ze-Yu Lin State Key Laboratory of Oil and Gas Reservoir geology and Exploitation Southwest Petroleum University Sichuan Particles Energy and Technology Co. Ltd Chongqing Industry Polytechnic college Petroleum Systems Engineering Faculty of Engineering and Applied Science University of Regina

Low-permeability reservoirs are generally characterized by low porosity and low permeability. Obtaining high production using the traditional method is technologically challenging because it yields a low reservoir recovery factor. In recent years, hydraulic fracturing technology is widely applied for efficiently exploiting and developing low-permeability reservoirs using a low-viscosity fluid as a fracturing ***, the transportation of the proppant is inefficient in the low-viscosity fluid, and the proppant has a low piling-up height in fracture channels. These key challenges restrict the fluid(natural gas or oil) flow in fracture channels and their functional flow areas, reducing the profits of hydrocarbon *** study aimed to explore and develop a novel dandelion-bionic proppant by modifying the surface of the proppant and the fiber. Its structure was similar to that of dandelion seeds, and it had high transport and stacking efficiency in low-viscosity liquids compared with the traditional ***, the transportation efficiency of this newly developed proppant was investigated experimentally using six different types of fracture models(tortuous fracture model, rough fracture model,narrow fracture model, complex fracture model, large-scale single fracture model, and small-scale single fracture model). Experimental results indicated that, compared with the traditional proppant, the transportation efficiency and the packing area of the dandelion-based bionic proppant significantly improved in tap water or low-viscosity fluid. Compared with the traditional proppant, the dandelionbased bionic proppant had 0.1.4 times longer transportation length, 0.3-5 times higher piling-up height, and 2-1. times larger placement area. The newly developed proppant also had some other extraordinary features. The tortuosity of the fracture did not influence the transportation of the novel proppant. This proppant could easily enter the branch fracture and n

关键词： Dandelion-based bionic proppant Low-viscosity fracturing fluid Unconventional reservoir Volumetric fracturing stimulation

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Microstructure Features and the Macroscopic Acoustic Behavior of Gassy Silt in the Yellow River Delta

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Journal of Ocean University of China 2024年第2期23卷 371-382页

作者： LIU Tao GUO Zhenqi ZHANG Yan WU Chen LIU Lele DENG Shenggui Laboratory for Marine geology Pilot National Laboratory for Marine Science and TechnologyQingdao 266061China Shandong Provincial Key Laboratory of Marine Environment and Geological Engineering Ocean University of ChinaQingdao 266100China college of Civil Engineering Anhui Jianzhu UniversityHefei 230601China The Key Laboratory of Gas Hydrate Ministry of Natural ResourcesQingdao Institute of Marine GeologyQingdao 266071China college of Marine Geosciences Key Laboratory of Submarine Geosciences and ProspectingOcean University of ChinaQingdao 266100China

The morphological changes in isolated bubbles in gassy silt play a critical role in the microscopic structures between soil particles and bubbles and macroscopic physical *** on X-ray CT scanning experiments under various vertical loads(four levels),self-designed acoustic macro experiments,and a series of formula revisions to the macro-air-bearing silt sound-velocity prediction model,this paper discusses the macro-and micro-scale features of gassy silts from the Yellow River *** samples consisted of different proportions of silt from the Yellow River Delta and porous media,and they were used to form two types of aerosol silts with initial gas contents of 4.23%and 7.67%.The results show that the air bubble content and external load considerably affect the microstructural parameters and acoustic behavior of gassy silt in the Yellow River *** macroscopic sound velocity showed a linear positive correlation with vertical load and relation to microstructural parameters in varying manners and *** on the traditional Biot-Stoll acoustic model,the gas-phase medium coefficient was introduced for the proper calculation and prediction of the sound velocity of air-bearing *** errors of the overall prediction varied between 5.6%and 9.6%.

关键词： gassy silt vertical load microstructure parameters bubble vibration Biot-Stoll acoustic model

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