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zirconium Aided Epitaxial Growth of InxSey on InP(111) Substrates Cheng

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Chinese Physics Letters 2020年第8期37卷 118-122页

作者： Cheng Zheng Dapeng Zhao Xinqiang Cai Wantong Huang Fanqi Meng Qinghua Zhang Lin Tang Xiaopeng Hu Lin Gu Shuai-Hua Ji Xi Chen State Key Laboratory of Low Dimensional Quantum Physics Department of PhysicsTsinghua UniversityBeijing 100084China Beijing Academy of Quantum Information Sciences Beijing 100193China Laboratory for Advanced Materials&Electron Microscopy Beijing National Laboratory for Condensed Matter PhysicsInstitute of PhysicsChinese Academy of SciencesBeijing 100190China RIKEN Center for Emergent Matter Science(CEMS) Wako 351-0198Japan

Layered material indium selenide(InxSey)is a promising candidate for building next-generation electronic and photonic *** report a zirconium aided MBE growth of this van der Waals *** co-depositing zirconium and selenium onto an indium phosphide substrate with a substrate temperature of 400℃at a constant zirconium flux rate of 0.01 ML/min,the polymorphic Inx Sey layer emerges on top of the insulating ZrSe2 *** archetypes,such as InSe,α-In2Se3 and α-In2Se3,are found in the InxSey layers.A negative magnetoresistance of 40%at 2 K under 9 T magnetic field is *** an InxSeyZrSe2 heterostructure with good lattice-matching may serve as a candidate for device applications.

关键词： material. zirconium matching

zirconium-mediated Selective Synthesis of 1,4-Dialkyl（aryl）-hexa-substituted Benzenes from Two Silyl-substituted Alkynes and One Internal Alkyne

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Chemical Research in Chinese Universities 2016年第3期32卷 366-372页

作者： LI Junqiu ZHANG Jiqian QU Hongmei LIU Jun LI Juan ZHOU Lishan Key Laboratory of Systems Bioengineering Ministry of Education Department of Pharmaceutical Engineering School of Chemical Engineering and Technology Tianjin University Tianjin 300072 P. R. China Nantong Dongchang Chemical Industrial Co. Ltd. Nantong 226407 P. R. China CNOOC Tianjin Chemical Research and Design Institute Tianjin 300131 P. R. China

Based on the formation of 2,5-bis（trimethylsilyl）-zirconacyclopentadienes from two silylalkynes with CpEZrBu2 and the Cu-mediated formation of 1,4-disilylbenzene via the cycloaddition of zirconacyclopentadienes to disubstituted alkynes, a selective synthesis of 1,4-dialkyl（aryl）-hexa-substituted benzenes was achieved followed by iodination and coupling reaction. The coupling reactions were carried out with either organolithium reagent or orga- nozinc reagent（Negishi coupling）, depending on the electrophilic species.

关键词： zirconium Hexa-substituted benzene Iodination Coupling reaction

zirconium metal-organic framework nanocrystal as microwave sensitizer for enhancement of tumor therapy

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Chinese Chemical Letters 2019年第2期30卷 481-484页

作者： Yuanwen Zou Wei Zhang Hongqiao Zhou Changhui Fu Longfei Tan Zhongbing Huang Xiangling Ren Jun Ren Xudong Chen Xianwei Meng College of Materials Science and Engineering Sichuan University Second Clinical Medical College of Jinan University Shenzhen People's Hospital Laboratory of Controllable Preparation and Application of Nanomaterials CAS Key Laboratory of Cryogenics Technical Institute of Physics and Chemistry Chinese Academy of Sciences (CAS)

Although surgical resection and chemotherapy were widely applied in tumor therapy, the dysfunction of normal cells resulted in the side effects (such as anorexia, nausea). MW thermal therapy is a non-invasive anticancer strategy under the help of MW sensitizer, with the safety and higher efficacy. zirconium metal-organic framework nanocubes (ZrMOF NCs) modified with polyethylene glycol, were prepared via one pot method and carbodiimide technique, resulting in their large specific surface area and *** results showed that non-ion-loaded ZrMOF NCs in 0.9% NaCl solution exhibited better heating effect,higher than that in pure water, due to the robust collision among the ions under MW irradiation. The in vivo experiments confirmed that ZrMOF-PEG NCs + MW group exhibited the higher temperature in the tumor region than that of only MW treatment, suggesting a better MW thermal therapeutic anticancer efficacy. This work provides a new preparation strategy of biosafety nanomaterial as MW sensitizer for enhancing MW thermal anticancer therapy.

关键词： Microwave thermal therapy zirconium metal-organic framework nanocubes Microwave sensitizer Tumor therapy Biosafety

Enhanced Mechanical Properties of Pure zirconium via Friction Stir Processing

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Acta Metallurgica Sinica(English Letters) 2020年第1期33卷 147-153页

作者： Wen Wang Peng Han Jie Yuan Pai Peng Qiang Liu Fei Qiang Ke Qiao Kuai-She Wang School of Metallurgical Engineering Xi’an University of Architecture and TechnologyXi’an 710055China National and Local Joint Engineering Research Center for Functional Materials Processing Xi’an 710055China

Friction stir processing(FSP), as a new kind of severe plastic deformation technique, can refine and homogenize the microstructure of metallic material. In this study, the effect of FSP on the microstructure and mechanical properties of pure Zr was investigated using electron backscatter diffraction analysis, microhardness and room-temperature tensile testing. The fine-grained(FG) structure with an average grain size of ~ 5.3 μm was obtained in the processed zone, where the average microhardness was ~ 198 HV, 1.6 times higher than that of base metal. Furthermore, tensile property of FG pure Zr exhibited obvious anisotropy owing to strong texture. Both grain size and texture had a significant effect on strength and ductility of FG pure Zr. High yield strength(248 MPa) and ultimate tensile strength(483 MPa), as well as good uniform elongation(10%) were achieved, which demonstrated that FSP was an effective method to fabricate bulk FG pure Zr with high strength and good ductility.

关键词： Friction stir processing Pure zirconium Grain size Texture Mechanical property

Effects of yttrium and zirconium additions on inclusions and mechanical properties of a reduced activation ferritic/martensitic steel

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Journal of Iron and Steel Research International 2020年第2期27卷 197-207页

作者： Dong-ping Zhan Guo-xing Qiu Chang-sheng Li Min Qi Zhou-hua Jiang Hui-shu Zhang School of Metallurgy Northeastern UniversityShenyang 110819LiaoningChina State Key Laboratory of Rolling and Automation.Northeastern University Shenyang 110819LiaoningChina School of Metallurgy Engineering Liaoning Institute of Science and TechnologyBenxi 117004.LiaoningChina

The effects of two alloying elements,i.e.,yttrium(Y)and zirconium(Zr),on the inclusion,microstructure,tensile property and impact toughness of reduced activation ferritic/martensitic(RAFM)steel are *** size and number of particles were determined by optical microscopy,and the particle types were examined by scanning electron *** size of?20% and?85% of the inclusions lied in the range of 0.5-1.0μm and 0.5-3.0μm,*** Y-and Y-Zr-containing specimens,the density of the fine inclusions,with a size less than 0.5μm,was found to be 1.06×10^17 and 9.82×10^16 m^-*** specimens were normalized at 1323 K for 30 min and tempered at 923 and 1023 K for 90 min,resulting in the formation of tempered martensite with M23C6 carbides and MX ***-containing RAFM steel tempered at 923 K formed M23C6 carbides and nano-sized carbides with Zr,conferring superior strength balance and impact *** yield strength of alloy reached 695 MPa,and a low ductile-brittle transition temperature of 238 K was maintained.

关键词： 9Cr oxide-dispersion-strengthened steel Inclusion Mechanical property DBTT Yttrium zirconium

Enhanced phosphate removal using zirconium hydroxide encapsulated in quaternized cellulose

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Journal of Environmental Sciences 2020年第3期32卷 102-112页

作者： Shuoxun Dong Qinghua Ji Yili Wang Huijuan Liu Jiuhui Qu Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100084China College of Environmental Science and Engineering Beijing Key Lab for Source Control Technology of Water PollutionBeijing Forestry UniversityBeijing 100083China

zirconium-based materials are efficient adsorbent for aqueous phosphate ***,current zirconium-based materials still show unsatisfied performance on adsorption capacity and ***,we demonstrate a zirconium hydroxide encapsulated in quaternized cellulose(QC-Zr) for the selective phosphate *** hydroxide nanoparticles were simultaneously generated in situ with the QC framework and firmly anchored in the three-dimensional(3D) cross-linked cellulose *** maximum P adsorption capacity of QC-Zr was 83.6 mg P/***,the QC-Zr shows high P adsorption performance in a wide pH range,generally due to the electrostatic effects of quaternized *** enhanced adsorption of P was also achieved in the presence of competing anions(including Cl^-,NO3^-,SO4^2-,SO4^4-) and humic acid(HA) even at a molar ratio up to 20 *** column adsorption capacity of QC-Zr reached 4000 bed volumes(BV) at EBCT=0.5 min as the P concentration decreased from 2.5 to 0.5 mg/*** study revealed that both-N^+(CH3)3 groups and zirconium hydroxide were involved in phosphate adsorption via electrostatic interactions between -N^+(CH3)3 and phosphate,and the formation of zirconium hydrogen phosphate(Zr(HPO4)x).The 31 P nuclear magnetic resonance(NMR) study implied that P surface-precipitated and inner-sphere complexed with zirconium hydroxide at a ratio of 3:1.

关键词： Adsorption Phosphate removal zirconium hydroxide aerogel Quaternized cellulose

Effect of precipitation pH and coexisting magnesium ion on phosphate adsorption onto hydrous zirconium oxide

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Journal of Environmental Sciences 2019年第2期31卷 167-187页

作者： Jianwei Lin Xingxing Wang Yanhui Zhan College of Marine Ecology and Environment Shanghai Ocean University

To understand the effect of precipitation pH and coexisting Mg^(2+) on phosphate adsorption onto zirconium oxide(ZrO_2), ZrO_2 particles precipitated at pH 5.3, 7.1 and 10.5, i.e., ZrO_2(5.3), ZrO_2(7.1)and ZrO_2(10.5), respectively were prepared and characterized, then their adsorption performance and mechanism in the absence and presence of Mg^(2+) were comparatively investigated in this study. The results showed that the Elovich, pseudo-second-order and Langmuir isotherm models correlated with the experimental data well. The adsorption mechanism involved the complexation between phosphate and zirconium. Coexisting Mg^(2+) slightly inhibited the adsorption of phosphate on ZrO_2(5.3), including the adsorption capacity and rate, but coexisting Mg^(2+) greatly increased the adsorption capacity and rate for ZrO_2(7.1)and ZrO_2(10.5). The enhanced adsorption of phosphate on ZrO_2(7.1) and ZrO_2(10.5) in the presence of Mg^(2+) was mainly due to the formation of Mg^(2+)-HPO_4^(2-) ion pair(MgHPO_4~0) in the solution and then the adsorption of MgHPO_4~0 on the adsorbent surface, forming the phosphatebridged ternary complex Zr(OPO_3H)Mg. In the absence of Mg^(2+) , the maximum phosphate adsorption capacity at pH 7 calculated from the Langmuir isotherm model decreased in the order of ZrO 2(7.1)(67.3 mg/g) > ZrO_2(5.3)(53.6 mg/g) ≈ ZrO_2(10.5)(53.1 mg/g), but it followed the order of Zr O2(7.1)(97.0 mg/g) > ZrO_2(10.5)(79.7 mg/g) > ZrO_2(5.3)(51.3 mg/g) in the presence of Mg^(2+) . The results of this work suggest that ZrO_2(7.1) is more suitable for use as an adsorbent for the effective removal of phosphate from municipal wastewater than ZrO_2(5.3) and ZrO_2(10.5),because Mg^(2+) is generally present in this wastewater.

关键词： Hydrous zirconium oxide Different precipitation pH values Adsorption Phosphate Magnesium ion Effect

Equilibrium and kinetic data of adsorption and separation for zirconium and hafnium onto MIBK extraction resin

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Transactions of Nonferrous Metals Society of China 2010年第8期20卷 1527-1533页

作者：徐志高吴延科张建东张力王力军 Division of Mineral Resources Metallurgy and MaterialsGeneral Research Institute for Nonferrous Metals

The equilibrium and kinetics of methyl isobutyl ketone(MIBK) extraction resin for adsorption and separation of zirconium and hafnium were studied under the different conditions of acidity,initial total concentrations of zirconium and hafnium and *** equilibrium data of both zirconium and hafnium are found to follow the Freundlich adsorption isotherm,and the Freundlich isotherm constants(KF) are 3.53 and 0.64 mg/g,*** equilibrium data of zirconium also fit the Langmuir adsorption isotherm,and the saturation adsorption capacity(Qmax) and the Langmuir isotherm constant(KL)are 75.93 mg/g and-0.012 7 L/g,*** obtained kinetic data of both zirconium and hafnium are found to fit the HO pseudo-second-order kinetic model,and the rate constants of pseudo-second-order equation(k2) are-0.019 and 0.41 g/(mg·min),*** tests show that the MIBK extraction resin could be used as efficient adsorbent material for separating hafnium from zirconium.

关键词： equilibrium kinetics adsorption methyl isobutyl ketone extraction resin zirconium hafnium separation

Intensification of zirconium and hafnium separation through the hollow fiber renewal liquid membrane technique using synergistic mixture of TBP and Cyanex-272 as extractant

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Chinese Journal of Chemical Engineering 2019年第8期27卷 1817-1827页

作者： A.Yadollahi M.Torab-Mostaedi K.Saberyan A.Charkhi F.Zahakifar Materials and Nuclear Fuel Research School Nuclear Science and Technology Research Institute

The novel synergistic mixture of TBP and Cyanex-272 is used as the extractant in the hollow fiber renewal liquid membrane(HFRLM) technique for Zr/Hf *** effects of the chemical and operational parameters such as HNO3 concentration in the donor phase,NH4 F concentration in the acceptor phase,Cyanex-272 and TBP concentration in the liquid membrane phase,the lumen and shell side flow rates,and aqueous/organic volume ratio on the mass transfer and separation performance of HFRLM method were *** obtained results reveal the intensification potential of proposed HFRLM technique for selective extraction of Zr over Hf with separation factor higher than *** HFRLM method provides two times higher mass transfer flux in comparison with hollow fiber supported liquid membrane(HFSLM).Also,the HFRLM method shows satisfactory stability for 700 min of continuous *** Zr ion transport through the LM phase follows the coupled co-transport mechanism and the diffusion in the renewal layer is recognized as the rate-controlling step in the HFRLM ***,the Zr mass transfer coefficient and molar flux in the HFRLM method are calculated in the range of 1×10^-8 to 8.4×10^-7 m·s^-1 and 4.9×10^-6 to 20.1×10^-6 mol·m^-2·s^-1,respectively.

关键词： zirconium Hafnium Synergistic separation Hollow fiber renewal liquid membrane (HFRLM)