检索结果-南通市图书馆

Photocatalytic thin film composite forward osmosis membrane for mitigating organic fouling in active layer facing draw solution mode

引用

Chinese Chemical Letters 2023年第6期34卷 230-235页

作者： Yang Hu Pin Zhao Hao Liu Xiawen Yi Weilong Song Xinhua Wang Jiangsu Key Laboratory of Anaerobic Biotechnology School of Environmental and Civil EngineeringJiangnan UniversityWuxi 214122China Jiangsu Collaborative Innovation Center of Technology and Material of water Treatment Suzhou University of Science and TechnologySuzhou 215009China

As a high-flux operation mode of thin film composite-forward osmosis(TFC-FO)membrane,active layer facing draw solution(AL-DS)mode suffers from the severe membrane fouling tendency,which is not addressed well.Here,we introduced a photocatalyst(Anatase titanium dioxide,A-TiO_(2))onto the support layer of TFC-FO membrane via the bonding of polydopamine(PDA)and polytetrafluoroethylene(PTFE),and prepared two photocatalytic membranes,A-TiO_(2)/PDA@TFC and A-TiO_(2)/PTFE@TFC.Compared with the pristine TFC-FO membrane,both A-Ti O_(2)/PDA@TFC and A-TiO_(2)/PTFE@TFC had an improved water permeability(10.5 L m^(-2)h^(-1)and 9.5 L m^(-2)h^(-1),respectively)and reduced reverse Na Cl flux salt(0.8 g m^(-2)h^(-1)and 0.7 g m^(-2)h^(-1),respectively)in the AL-DS mode using 1 mol/L Na Cl as draw solution and pure water as feed solution.Moreover,in the 16 h fouling experiment using 200 ppm bovine serum albumin(BSA)solution as a representative pollutant,the flux decline rate of both photocatalytic membranes was dramatically alleviated from 39.7%and 21.7%in the darkness to 8.5%and 9.7%under UV irradiation,respectively,indicating a significant anti-fouling capacity of photocatalytic effect.In all,the presence of A-TiO_(2)endowed membrane with high permeability,high rejection efficiency and excellent anti-fouling capacity under UV spotlight.As bonding agent,PTFE provided the modified membrane with a high photocatalytic effect and high self-cleaning capacity,while PDA increased the membrane permeability and protected membrane against photocatalytic damage.This work provides a simple and feasible method to improve the anti-fouling capacity of TFC-FO membrane in AL-DS mode.

关键词： Forward osmosis Photocatalysis Membrane orientation Membrane fouling water permeation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Altering membrane structure to enhance water permeability and performance of anion exchange membrane fuel cell

引用

Science China(Technological Sciences) 2021年第2期64卷 414-422页

作者： YANG Yue GAO XueQiang SONG Wei YU HongMei LI WenBin QI ManMan HUANG He WANG PengHao FAN ZhiXuan SHAO ZhiGang Fuel Cell System and Engineering Laboratory Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of Chinese Academy of Sciences Beijing 100049China School of Automotive Studies Tongji UniversityShanghai 201804China

water management has been proven significant for enhancing both performance and durability of anion exchange membrane fuel cell. Besides searching new material, decreasing membrane thickness and modifying operation parameters, a simple and universal method of altering membrane structure is proposed in this work. Composite membranes made by unique processing method that includes both casting and electrospinning processes were compared with traditional casting membrane, all with the same thickness of 40 μm. Comparing to traditional casting membrane, the composite membrane put at proper position shows a higher water permeability, thus even more than 50% enhancement of the peak performance.

关键词： AEMFC water management membrane structure electrospinning water permeation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Theoretical study on Janus graphene oxide membrane for water transport

引用

Frontiers of Chemical Science and Engineering 2021年第4期15卷 913-921页

作者： Quan Liu Mingqiang Chen Yangyang Mao Gongping Liu Analytical and Testing Center Anhui University of Science and TechnologyHuainan 232001China State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 211816China

Graphene oxide(GO)membranes have received considerable attention owing to their outstanding water-permeation properties;however,the effect of the membrane’s microstructures(such as the distribution of oxidized and pristine regions)on the transport mechanism remains unclear.In this study,we performed molecular simulations to explore the permeation of a water-ethanol mixture using a new type of Janus GO membranes with different orientations of oxidized and pristine surfaces.The results indicate that the oxidized upper surface endows the GO membrane with considerable water-capture capability and the in-built oxidized interlayer promotes the effective vertical diffusion of water molecules.Consequently,using the optimized Janus GO membrane,infinite water selectivity and outstanding water flux(-40.9 kg·m^(-2) h^(-1))were achieved.This study contributes to explaining the role of oxidized regions in water permeation via GO membranes and suggests that Janus GO membranes could be used as potential candidates for water-ethanol separation.

关键词： graphene oxide membrane molecular dynamics simulation water permeation water-ethanol separation oxidized and pristine regions

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：