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Towards high-performance and robust anion exchange membranes(AEMs)for water electrolysis:Super-acid-catalyzed synthesis of AEMs

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Journal of Energy Chemistry 2024年第6期93卷 478-510,I0012页

作者： Geun Woong Ryoo Sun Hwa Park Ki Chang Kwon Jong Hun Kang Ho Won Jang Min Sang Kwon Department of Materials Science and Engineering Research Institute of Advanced Materials(RIAM)Seoul National UniversitySeoul 08826Republic of Korea Interdisciplinary Materials Measurement Institute Korea Research Institute of Standards and Science(KRISS)Daejeon 34113Republic of Korea Department of Chemical and Biological Engineering and Institute of Chemical ProcessSeoul National UniversitySeoul 08826Republic of Korea Department of Applied Measurement Science University of Science and TechnologyDaejeon 34113Republic of Korea

The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil *** various hydrogen production technologies,anion exchange membrane water electrolyzer(AEMWE)has emerged as a next-generation technology known for its high hydrogen production efficiency and its ability to use non-metal ***,this technology faces significant challenges,particularly in terms of the membrane durability and low ionic *** address these challenges,research efforts have focused on developing membranes with a new backbone structure and anion exchange groups to enhance durability and ionic ***,the super-acid-catalyzed condensation(SACC)synthesis method stands out due to its user convenience,the ability to create high molecular weight(MW)polymers,and the use of oxygen-tolerant organic *** the synthesis of anion exchange membranes(AEMs)using the SACC method began in 2015,and despite growing interest in this synthesis approach,there remains a scarcity of review papers focusing on AEMs synthesized using the SACC *** review covers the basics of SACC synthesis,presents various polymers synthesized using this method,and summarizes the development of these polymers,particularly their building blocks including aryl,ketone,and anion exchange *** systematically describe the effects of changes in the molecular structure of each polymer component,conducted by various research groups,on the mechanical properties,conductivity,and operational stability of the *** review will provide insights into the development of AEMs with superior performance and operational stability suitable for water electrolysis applications.

关键词： Green hydrogen production water electrolysis Anion exchange membrane water electrolyzer(AEMWE) Anion exchange membranes(AEMs) Super-acid-catalyzed condensation(SACC)

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Shining Light on Anion-Mixed Nanocatalysts for Efficient water electrolysis: Fundamentals, Progress, and Perspectives

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Nano-Micro Letters 2022年第3期14卷 79-119页

作者： Yaoda Liu Paranthaman Vijayakumar Qianyi Liu Thangavel Sakthivel Fuyi Chen Zhengfei Dai State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China State Key Laboratory of Solidification Processing Northwestern Polytechnical UniversityXi’an 710072People’s Republic of China

Hydrogen with high energy density and zero carbon emission is widely acknowledged as the most promising candidate toward world’s carbon neutrality and future sustainable ***-splitting is a constructive technology for unpolluted and high-purity H2 production,and a series of non-precious electrocatalysts have been developed over the past *** further improve the catalytic activities,metal doping is always adopted to modulate the 3d-electronic configuration and electron-donating/accepting(e-DA)properties,while for anion doping,the electronegativity variations among different non-metal elements would also bring some potential in the modulations of e-DA and metal valence for tuning the *** this review,we summarize the recent developments of the many different anion-mixed transition metal compounds(e.g.,nitrides,halides,phosphides,chalcogenides,oxyhydroxides,and borides/borates)for efficient water electrolysis ***,we have introduced the general information of water-splitting and the description of anion-mixed electrocatalysts and highlighted their complementary functions of mixed ***,some latest advances of anion-mixed compounds are also categorized for hydrogen and oxygen evolution *** rationales behind their enhanced electrochemical performances are *** but not least,the challenges and future perspectives are briefly proposed for the anion-mixed water dissociation catalysts.

关键词： Multianions Electrocatalysts water electrolysis Hydrogen energy Oxygen evolution

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Covalently Bonded Ni Sites in Black Phosphorene with Electron Redistribution for Efficient Metal‑Lightweighted water electrolysis

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Nano-Micro Letters 2024年第6期16卷 233-245页

作者： Wenfang Zhai Ya Chen Yaoda Liu Yuanyuan Ma Paranthaman Vijayakumar Yuanbin Qin Yongquan Qu Zhengfei Dai State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China School of Chemistry and Chemical Engineering Northwestern Polytechnical UniversityXi’an 710072People’s Republic of China SSN Research Centre SSN College of EngineeringChennaiTamil Nadu 603110India

The metal-lightweighted electrocatalysts for water splitting are highly desired for sustainable and economic hydrogen energy deployments,but *** this work,a low-content Ni-functionalized approach triggers the high capability of black phosphorene(BP)with hydrogen and oxygen evolution reaction(HER/OER)*** a facile in situ electro-exfoliation route,the ionized Ni sites are covalently functionalized in BP nanosheets with electron redistribution and controllable metal *** is found that the as-fabricated Ni-BP electrocatalysts can drive the water splitting with much enhanced HER and OER *** 1.0 M KOH electrolyte,the optimized 1.5 wt%Nifunctionalized BP nanosheets have readily achieved low overpotentials of 136 mV for HER and 230 mV for OER at 10 mA cm^(−2).Moreover,the covalently bonding between Ni and P has also strengthened the catalytic stability of the Ni-functionalized BP electrocatalyst,stably delivering the overall water splitting for 50 h at 20 mA cm^(−2).Theoretical calculations have revealed that Ni–P covalent binding can regulate the electronic structure and optimize the reaction energy barrier to improve the catalytic activity *** work confirms that Ni-functionalized BP is a suitable candidate for electrocatalytic overall water splitting,and provides effective strategies for constructing metal-lightweighted economic electrocatalysts.

关键词： Black phosphorus water electrolysis Electrocatalyst Electron redistribution Covalent functionalization

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N‑Doped Graphene‑Decorated NiCo Alloy Coupled with Mesoporous NiCoMoO Nano‑sheet Heterojunction for Enhanced water electrolysis Activity at High Current Density

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Nano-Micro Letters 2021年第5期13卷 77-89页

作者： Guangfu Qian Jinli Chen Tianqi Yu Lin Luo Shibin Yin College of Chemistry and Chemical Engineering MOE Key Laboratory of New Processing Technology for Nonferrous Metals and MaterialsState Key Laboratory of Processing for Non‑Ferrous Metal and Featured MaterialsGuangxi University100 Daxue RoadNanning 530004P.R.China

Developing highly effective and stable non-noble metalbased bifunctional catalyst working at high current density is an urgent issue for water electrolysis(WE).Herein,we prepare the N-doped graphene-decorated NiCo alloy coupled with mesoporous NiCoMoO nano-sheet grown on 3D nickel foam(NiCo@C-NiCoMoO/NF)for water ***@C-NiCoMoO/NF exhibits outstanding activity with low overpotentials for hydrogen and oxygen evolution reaction(HER:39/266 mV;OER:260/390 mV)at±10 and±1000 mA cm^(−2).More importantly,in 6.0 M KOH solution at 60℃ for WE,it only requires 1.90 V to reach 1000 mA cm−2 and shows excellent stability for 43 h,exhibiting the potential for actual *** good performance can be assigned to N-doped graphene-decorated NiCo alloy and mesoporous NiCoMoO nano-sheet,which not only increase the intrinsic activity and expose abundant catalytic activity sites,but also enhance its chemical and mechanical *** work thus could provide a promising material for industrial hydrogen production.

关键词： N-doped graphene-decorated NiCo alloy Catalyst Mesoporous nano-sheet water electrolysis High current density

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Classification and technical target of water electrolysis for hydrogen production

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Journal of Energy Chemistry 2024年第8期95卷 554-576,I0012页

作者： Kahyun Ham Sooan Bae Jaeyoung Lee Ertl Center for Electrochemistry and Catalysis Gwangju Institute of Science and Technology(GIST)123 Cheomdangwagi-RoBuk-guGwangju 61005South Korea Department of Heterogeneous Reactions Max Planck Institute for Chemical Energy ConversionStiftstr.34-36Mülheim an der RuhrGermany School of Earth Sciences and Environmental Engineering GIST123 CheomdangwagiroBuk-guGwangju 61005South Korea International Future Research Center of Chemical Energy Storage and Conversion Processes GIST123 CheomdangwagiroBuk-guGwangju 61005South Korea eSuS Co. Ltd.#408S6 BuildingSchool of Environment and Energy EngineeringGIST123 CheomdangwagiroBuk-guGwangju 61005South Korea

Continuous efforts are underway to reduce carbon emissions worldwide in response to global climate *** electrolysis technology,in conjunction with renewable energy,is considered the most feasible hydrogen production technology based on the viable possibility of large-scale hydrogen production and the zero-carbon-emission nature of the ***,for hydrogen produced via water electrolysis systems to be utilized in various fields in practice,the unit cost of hydrogen production must be reduced to$1/kg H_(2).To achieve this unit cost,technical targets for water electrolysis have been suggested regarding components in the *** this paper,the types of water electrolysis systems and the limitations of water electrolysis system components are *** suggest guideline with recent trend for achieving this technical target and insights for the potential utilization of water electrolysis technology.

关键词： water electrolysis Hydrogen production Technical target Electrochemistry

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Novel Au nanoparticles-inlaid titanium paper for PEM water electrolysis with enhanced interfacial electrical conductivity

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International Journal of Minerals,Metallurgy and Materials 2022年第5期29卷 1090-1098页

作者： Yue Liu Shaobo Huang Shanlong Peng Heng Zhang Lifan Wang Xindong Wang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China Department of Energy Storage Science and Engineering School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China School of Physics and Engineering Henan University of Science and TechnologyLuoyang 471023China

Proton-exchange membrane water electrolysis(PEM WE)is a particularly promising technology for renewable hydrogen ***,the excessive passivation of the gas diffusion layer(GDL)will seriously affect the high surface-contact resistance and result in energy ***,a mechanism for improving the conductivity and interface stability of the GDL is an urgent *** this work,we have prepared a hydrophilic and corrosion resistant conductive composite protective *** polydopamine(PDA)film on the Ti surface,which was obtained via the solution oxidation method,ensured that neither micropores nor pinholes existed in the final hybrid ***-situ reduced gold nanoparticles(AuNPs)improved the conductivity to achieve the desired interfacial contact resistance and further enhanced the corrosion *** surface composition of the treated samples was investigated using scanning electron microscopy(SEM),transmis-sion electron microscopy(TEM),X-ray diffraction(XRD),and Fourier transform infrared spectroscopy(FTIR).The results indicated that the optimized reaction conditions included a pH value of 3 of HAuCl_(4) solution with PDA deposition(48 h)on papers and revealed the lowest con-tact resistance(0.5 mΩ·cm^(2))and corrosion resistance(0.001μA·cm^(−2))in a 0.5 M H_(2)SO_(4)+2 ppm F−solution(1.7 V ***)among all the modified specimens,where RHE represents reversible hydrogen *** findings indicated that the Au-PDA coating is very appropriate for the modification of Ti GDLs in PEM WE systems.

关键词： water electrolysis proton-exchange membrane hydrogen energy titanium paper diffusion layer Au nanoparticles inlaid titanium gold–polydopamine nanocomposite

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Electronic Coupling of Single Atom and FePS_3 Boosts water electrolysis

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Energy & Environmental Materials 2022年第3期5卷 899-905页

作者： Chongyang Tang Dong He Nan Zhang Xianyin Song Shuangfeng Jia Zunjian Ke Jiangchao Liu Jianbo Wang Changzhong Jiang Ziyu Wang Xiaoqing Huang Xiangheng Xiao School of Physics and Technology Wuhan UniversityWuhan 430072China The Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi 214122China Institute of Technological Sciences Wuhan UniversityWuhan 430072China State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China

Engineering the electronic structure of surface active sites at the atomic level can be an efficient way to modulate the reactivity of ***,we report the rational tuning of surface electronic structure of FePS_(3) nanosheets(NSs)by anchoring atomically dispersed metal *** calculations predict that the strong electronic coupling effect in single-atom Ni-FePS_(3) facilitates electron aggregation from Fe atom to the nearby Ni-S bond and enhances the electron-transfer of Ni and S sites,which balances the oxygen species adsorption capacity,reinforces water adsorption and dissociation process to accelerate corresponding oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).The optimal Ni-FePS_(3)NSs/C exhibits outstanding electrochemical water-splitting activities,delivering an overpotential of 287 mV at the current density of 10 mA cm^(-2) and a Tafel slope of 41.1 mV dec^(-1) for OER;as well as an overpotential decrease of 219 mV for HER compared with pure FePS_(3)NSs/*** concept of electronic coupling interaction between the substrate and implanted single active species offers an additional method for catalyst design and beyond.

关键词： electronic coupling iron thiophosphates nanosheet single atom water electrolysis

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Bifunctional PdPt bimetallenes for formate oxidation-boosted water electrolysis

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Carbon Energy 2023年第12期5卷 175-186页

作者： Xi-Lai Liu Yu-Chuan Jiang Jiang-Tao Huang Wei Zhong Bin He Pu-Jun Jin Yu Chen Key Laboratory of Macromolecular Science of Shaanxi Province Key Laboratory of Applied Surface and Colloid Chemistry(Ministry of Education)Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi'anShaanxiPR China College of New Materials and New Energies Shenzhen Technology UniversityShenzhenGuangdongPR China

Small-molecule electrooxidation-boosted water electrolysis(WE)is an energy-saving method for hydrogen(H2)***,PdPt bimetallenes(PdPt BMLs)are obtained through the simple galvanic replacement *** BMLs reveal 2.93-fold enhancement in intrinsic electroactivity and 4.53-fold enhancement in mass electroactivity for the formate oxidation reaction(FOR)with respect to Pd metallenes(Pd MLs)at 0.50 V potential due to the synergistic ***,the introduction of Pt atoms also considerably increases the electroactivity of PdPt BMLs for hydrogen evolution reaction(HER)with respect to Pd MLs in an alkaline medium,which even exceeds that with the use of commercial Pt *** by the outstanding FOR and HER electroactivity of bifunctional PdPt BMLs,a two-electrode FOR-boosted WE system(FOR-WE)is constructed by using PdPt BMLs as the cathode and the *** FOR-WE system only requires an operational voltage of 0.31 V to achieve H2 production,which is 1.48 V lower than that(ca.1.79 V)with the use of the traditional WE system.

关键词： electrocatalyst formate oxidation reaction hydrogen evolution reaction metallene water electrolysis

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Efficient synthesis of IrPtPdNi/GO nanocatalysts for superior performance in water electrolysis

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Nano Research 2024年第11期17卷 10208-10215页

作者： Sanha Jang Young Hwa Yun Jin Gyu Lee Kyung Hee Oh Shin Wook Kang Jung-Il Yang MinJoong Kim Changsoo Lee Ji Chan Park Clean Fuel Research Laboratory Korea Institute of Energy Research Daejeon 34129 Korea Hydrogen Research Department Korea Institute of Energy Research Daejeon 34129 Korea Energy Engineering University of Science and Technology Daejeon 34113 Korea

Traditional iridium (Ir) oxide catalysts have faced significant limitations in water electrolysis, particularly under acidic conditions where instability and degradation severely restrict the efficiency of the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). To overcome these challenges, this study successfully synthesized highly dispersed IrPtPdNi alloy nanoparticles on a graphene oxide support using a vertically moving reactor, demonstrating exceptional performance in water electrolysis. These nanoparticles, synthesized via a fast-moving bed pyrolysis method, combine iridium, platinum, palladium, and nickel. They exhibit lower overpotentials in OER and comparable performance in HER to commercial catalysts, while also offering enhanced stability. These results surpass the limitations of traditional catalysts, marking significant progress toward more efficient and sustainable hydrogen production technologies. This advancement is expected to contribute significantly to the development of sustainable energy systems by innovatively enhancing the performance of catalysts in the electrochemical water-splitting process.

关键词： multicomponent nanoparticles rapid synthesis water electrolysis alloy iridium cat

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Optimization of electrocatalytic properties of NiMoCo foam electrode for water electrolysis by post-treatment processing

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Rare Metals 2015年第11期34卷 802-807页

作者： Jian-Wei Wang Yue-Fa Wang Jing-Guo Zhang Yan-Lin Yu Ge-Ge Zhou Lei Cheng Lin-Shan Wang Z.Zak Fang State Key Laboratory of Nonferrous Metals and Processes General Research Institute for Nonferrous Metals GRIPM Advanced Materials Co. Ltd General Research Institute for Nonferrous Metals Department of Metallurgical Engineering University of UtahSalt Lake City

Hydrogen is a potential alternative to fossil fuels in coping with the increased global energy demand,and water electrolysis is an attractive approach for H2production. Nickel–molybdenum–cobalt（Ni Mo Co） foam electrodes used for water electrolysis were prepared by the electrodeposition method, and the influence of heat treatments on the surface structure of Ni Mo Co foam electrodes,mechanical properties, and electrochemical performance of the synthesized electrodes was investigated in order to optimize the post-treatment processes. The residual carbon in the surface of the electrode was removed by decarbonization in the atmospheric condition. The carbon content decreases to lower than 200 ×10-6when the temperature exceeds 500 °C. Next, the material is reduced in hydrogen atmosphere from 500 to 1100 °C to remove the surface oxides. As the temperature increases, the surface molybdenum content increases significantly between 500 and 800 °C, the surface grains become coarser, and the tensile strength and elongation increase as well. The lowest polarization overpotential is obtained at 800 °C. Below 800 °C, the electrode is only partially reduced and some black oxide zones are observed on the electrode surface,which leads to the higher polarization overpotential. Thesamples heat-treated at the temperatures of higher than 800 °C show better strength and toughness as well as brighter appearance. However, the surface particle coarsening leads to a decrease in the specific surface area and a higher overpotential.

关键词： water electrolysis Foam electrode Ni Mo Co Post-tr

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