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Controllable Exciton Diffusion Length and Ultrafast Charge Generation in Ternary Organic Solar Cells

Chinese Journal of Chemistry 2024年第11期42卷 1275-1283页

作者： Sixuan Cheng Jiawei Qiao Peng Lu Wei Qin Xiaotao Hao School of Physics State Key Laboratory of Crystal MaterialsShandong UniversityJinanShandong250100 China School of Physics National Demonstration Center for Experimental Physics EducationShandong UniversityJinanShandong250100 China ARC Centre of Excellence in Exciton Science School of ChemistryThe University of MelbourneParkvilleVictoria3010 Australia

Charge generation,a critical process in the operation of organic solar cell(OSC),requires thorough investigation in an ultrafast *** work demonstrates that the utilization of alloy model for the non-fullerene acceptor(NFA)component can regulate the crystallization properties of active layer films,which in turn affects exciton diffusion and hole transfer(HT),ultimately influencing the charge generation *** incorporating BTP-eC7 as a third component,without expanding absorption range or changing molecular energy levels but regulating the ultrafast exciton diffusion and HT processes,the power conversion efficiency(PCE)of the optimized PM6:BTP-eC9:BTP-eC7 based ternary OSC is improved from 17.30%to 17.83%,primarily due to the enhancement of short-circuit current density(JSC).Additionally,the introduction of BTP-eC7 also reduces the trap state density in the photoactive layer which helps to reduce the loss of *** study introduces a novel approach for employing ternary alloy models by incorporating dual acceptors with similar structures,and elucidates the underlying mechanism of charge generation and JSC in ternary OSCs.

关键词： Organic photovoltaics Ternary strategy Exciton diffusion Hole transfer trap state Kinetics Alloys Photophysics

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Self-trapped exciton engineering for white-light emission in colloidal lead-free double perovskite nanocrystals

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Science Bulletin 2020年第13期65卷 1078-1084,M0003页

作者： Muyu Cong Bin Yang Feng Hong Tiancheng Zheng Youbao Sang Jingwei Guo Songqiu Yang Keli Han state Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of the Chinese Academy of Sciences Beijing 100039China Institute of Molecular Sciences and Engineering Shandong UniversityQingdao 266237China Key Laboratory of Chemical Lasers Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China

Intrinsic broadband photoluminescence(PL)of self-trapped excitons(STEs)are systematically studied in lead-free double perovskite nanocrystals(NCs).It is clarified that bandgap(direct/indirect)has important influence on the PL properties of STEs:indirect bandgap NCs exhibit strong exciton-phonon coupling which results in non-radiative STEs,while direct bandgap NCs exhibit moderate exciton-phonon coupling,inducing bright STE ***,by alloying K+and Li+ions in Cs2AgInCl6 NCs,the NCs exhibit broadband white-light ***-carrier dynamics study indicates that the efficient white-light emission originates from the further suppressed non-radiative processes of the STEs in the direct bandgap *** work may deepen the understanding of STEs and guide the design of highperformance lead-free perovskites.

关键词： Double perovskite Nanocrystal trap state Hot-carrier cooling Carrier-phonon coupling

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Atomic origin of the traps in memristive interface

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Nano Research 2017年第6期10卷 1924-1931页

作者： Ye Tian Lida Pan Chuan Fei Guo Qian Liu CAS Center of Excellence for Nanoscience CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology No. 11 Beiyitiao Zhongguancun Beijing 100190 China School of Communication and Electronics Engineering Hunan City University Yiyang 413000 China Department of Physics and Astronomy Vanderbilt University Nashville TN 37235 USA Institute of Physics Chinese Academy of Sciences Beijing 100190 China Photonics Research Group Department of Information Technology Ghent University-IMEC Ghent B-9000 Belgium Department of Materials Science and Engineering South University of Science and Technology of China Shenzhen 518055 China

In recent years, trap-related interfacial transport phenomena have received great attention owing to their potential applications in resistive switching devices and photo detectors. Not long ago, one new type of memristive interface that is composed of F-doped SnO2 and Bi2S3 nano-network layers has demonstrated a bivariate-continuous-tunable resistance with a swift response comparable to the one in neuron synapses and with a brain-like memorizing capability. However, the resistive mechanism is still not clearly understood because of lack of evidence, and the limited improvement in the development of the interfacial device. By combining I-V characterization, electron energy-loss spectroscopy, and first- principle calculation, we studied in detail the macro/micro features of the memristive interface using experimental and theoretical methods, and confirmed that its atomic origin is attributed to the traps induced by O-doping. This implies that impurity-doping might be an effective strategy for improving switching features and building new interfacial memristors.

关键词： memristance interface trap state first principle calculation

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Electron transfer kinetics in CdS/Pt heterojunction photocatalyst during water splitting

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Chinese Journal of Catalysis 2022年第10期43卷 2530-2538页

作者： Jianjun Zhang Gaoyuan Yang Bowen He Bei Cheng Youji Li Guijie Liang Linxi Wang Laboratory of Solar Fuel Faculty of Materials Science and ChemistryChina University of GeosciencesWuhan 430074HubeiChina Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053HubeiChina state Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina College of chemistry and Chemical engineering Jishou UniversityJishou 416000HunanChina

Noble metal cocatalysts have shown great potential in boosting the performance of CdS in photocatalytic water ***,the mechanism and kinetics of electron transfer in noble-metal-decorated CdS during practical hydrogen evolution is not clearly ***,Pt-nanoparticle-decorated CdS nanorods(CdS/Pt)are utilized as the model system to analyze the electron transfer kinetics in CdS/Pt *** femtosecond transient absorption spectroscopy,three dominating exciton quenching pathways are observed and assigned to the trapping of photogenerated electrons at shallow states,recombination of free electrons and trapped holes,and radiative recombination of locally photogenerated electron-hole *** introduction of Pt cocatalyst can release the electrons trapped at the shallow states and construct an ultrafast electron transfer tunnel at the CdS/Pt *** CdS/Pt is dispersed in acetonitrile,the lifetime and rate for interfacial electron transfer are respectively calculated to be~5.5 ps and~3.5×10^(10) s^(−1).The CdS/Pt is again dispersed in water to simulate photocatalytic water *** lifetime of the interfacial electron transfer decreases to~5.1 ps and the electron transfer rate increases to~4.9×10^(10) s^(−1),confirming that Pt nanoparticles serve as the main active sites of hydrogen *** work reveals the role of Pt cocatalysts in enhancing the photocatalytic performance of CdS from the perspective of electron transfer kinetics.

关键词： Femtosecond transient absorption spectroscopy Photocatalytic water splitting CdS Electron transfer kinetics trap state

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