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Controlled Synthesis of Core-Shell Nickel Microspheres with Solid Core and Porous Shell by Precipitation and thermal decomposition Method

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Journal of Wuhan University of Technology(Materials Science) 2019年第4期34卷 824-829页

作者： LI Tao MA Guohua CHEN Jian GONG Yong School of Mechanical Engineering Chengdu UniversityChengdu 610106China College of Materials Science and Engineering Southwest University of Science and TechnologyMianyang 621010China Analysis and Testing Center Southwest University of Science and TechnologyMianyang 621010China Sichuan University of Science & Engineering Material Corrosion and Protection Key Laboratory of Sichuan ProvinceZigong 643000China

Nickel oxalate micro-spheres with core-shell structure of solid core and radiate shell were synthesized by precipitation method in a mixed water solution, with oxalic acid and nickel acetate as raw materials, through dropping ammonium hydroxide to adjust the solution pH value to about 8.0. Nickel microspheres with core-shell structure of solid core and porous shell were prepared by decomposing of nickel oxalate microspheres precursor at about 340 ℃ in argon atmosphere. The analyses of infrared spectroscopy(IR)indicates that the composition of the powders is nickel oxalate. The analyses of atomic absorption spectrometry(AAS) and organic elemental analysis(OEA) indicate that the molar ratio of(C2O4)^2-/Ni^2+ is about 1.02, close to the theoretical value of 1.0. The results of the thermo-gravimetric and differential thermal gravity analyses(TG-DTG) indicate that the molar ratio of(C2O4)^2-/Ni^2+ is about 1.06, also close to the theoretical value of *** analysis of X-ray diffraction(XRD) indicates that the composition of black powders as-prepared is nickel,which has a face-centered cubic crystal structure with average crystal grain size about 16.87 nm. The images of scanning electron microscopy(SEM) indicate that the morphology of nickel oxalate microspheres is a coreshell structure with solid core and radiate shell. The diameter of nickel oxalate microspheres is about 3 μm, and the shell consists of a large number of thin nanorods. The images of SEM also indicate that the morphology of nickel microspheres is a core-shell structure with solid core and porous shell. The diameter of nickel microspheres is about 2 μm, and the shell consists of a large number of nickel grains, surface holes and through holes. The diameter of nickel grains is about 50-100 nm, and the diameter of holes is about 50-200 nm.

关键词： nickel oxalate nickel core-shell porous precipitation thermal-decomposition

Spherical and Radiate Ni Particles Prepared by the Tartrate Precipitation and thermal decomposition Method

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Journal of Wuhan University of Technology(Materials Science) 2013年第5期28卷 857-861页

作者：李涛刘颖 MA Guohua HE Dengliang College of Materials Science and Engineering Sichuan University State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials College of Chemistry and Chemical Engineening Mianyang Normal University

Nickel tartrate precursor particles were synthesized by the liquid phase precipitation method in an ethanol-water-ammonia mixed solution, with tartaric acid and using nickel chlorate as raw materials, with the pH value controlled at 4.0, and the temperature controlled at 50 ℃. Nickel particles with complicated morphology were prepared by the decomposition of nickel taratrate precursor particles at temperatures of 360, 380 and 400 ℃, respectively. The study of infrared spectroscopy （IR） indicated that the product was pure nickel tartrate. The studies of the atomic absorption spectrometry （AAS） and organic elemental analysis （OEA） indicated that the molar ratio of Ni2＋ to （C4H4O6）2- is close to 1：1. The studies of the differential scanning calorimeter and thermo-gravimetric analysis （DSC-TG） indicated that the chemical formula Niz（C4H4O6） 2.5H2O was confirmed. The studies of X-ray diffractions （XRD） indicated that the silvery white metal powders were pure Ni, with a face-centered cubic crystal structure. The images of scanning electron microscopy （SEM） showed that the morphology of metal Ni particles was obvious spherical and radiate. The diameter of nickel tartrate particles was about 60 μm, which consisted of many nanolathes; and the diameter of metal Ni particles was about 30 μm, which consisted of many lathes about 0.5 μm in thickness.

关键词： inorganic materials nickel spherical radiate precipitation thermal-decomposition optical spectroscopy thermal analysis scanning electron microscopy

Assessment of electrostatic discharge sensitivity of nitrogen-rich heterocyclic energetic compounds and their salts as high energy-density dangerous compounds: A study of structural variables

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DEFENCE TECHNOLOGY 2024年第9期39卷 15-22页

作者： Keshavarz, Mohammad Hossein Bani, Sedigheh Heydari Bakhtiari, Reza Hosseini, Seyyed Hesamodin Malek Ashtar Univ Technol Fac Appl Sci Esfahan 177415875 Iran

Nitrogen-rich heterocyclic energetic compounds (NRHECs) and their salts have witnessed widespread synthesis in recent years. The substantial energy-density content within these compounds can lead to potentially dangerous explosive reactions when subjected to external stimuli such as electrical discharge. Therefore, developing a reliable model for predicting their electrostatic discharge sensitivity (ESD) becomes imperative. This study proposes a novel and straightforward model based on the presence of specific groups (-NH2 or -NH-, -N = N+ -O(- )and -NNO2, -ONO2 or -NO2) under certain conditions to assess the ESD of NRHECs and their salts, employing interpretable structural parameters. Utilizing a comprehensive dataset comprising 54 ESD measurements of NRHECs and their salts, divided into 49/5 training/test sets, the model achieves promising results. The Root Mean Square Error (RMSE), Mean Absolute Error (MAE), and Maximum Error for the training set are reported as 0.16 J, 0.12 J, and 0.5 J, respectively. Notably, the ratios RMSE(training)/RMSE(test), MAE(training)/MAE(test), and Max Error(training)/Max Error(test) are all greater than 1.0, indicating the robust predictive capabilities of the model. The presented model demonstrates its efficacy in providing a reliable assessment of ESD for the targeted NRHECs and their salts, without the need for intricate computer codes or expert involvement. (c) 2024 China Ordnance Society. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://***/ licenses/by-nc-nd/4.0/).

关键词： Electrostatic discharge sensitivity Heterocyclic energetic compounds containing azole compound Interpretable structural parameter Safety ELECTRIC SPARK SENSITIVITY thermal-decomposition IMPACT SENSITIVITY NITRAMINES PERFORMANCE EXPLOSIVES PREDICTION

A review of recent advances of kesterite thin films based on magnesium, iron and nickel for photovoltaic application: insights into synthesis, characterization and optoelectronic properties

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CLEAN ENERGY 2024年第2期8卷 217-238页

作者： Perez, Nelson Mauricio Espinel Lopez, Enrique Vera Cuaspud, Jairo Alberto Gomez Castello, Juan Bautista Carda Univ Pedag & Tecnol Colombia Grp Invest Integridad & Evaluac Mat GIEM Inst Invest & Innovac Ciencia & Tecnol Mat INCITEM Ave Cent Norte 39-115 Tunja Boyaca Colombia Ctr Minero Serv Nacl Aprendizaje Sena Vereda Morca Sect Bata Sogamoso Boyaca Colombia Univ Jaume 1 Grp Quim Inorgan & Organ Campus Riu Sec Castellon De La Plana Castellon De La Spain

This review emphasizes the recent advancements and prospects of thin-film kesterite-based photovoltaic (PV) applications using magnesium, iron and nickel. The quest for novel materials employed in solar cells has resulted in incorporating these elements into the composition of kesterite as substitutes or modifiers (dopants) for zinc. This integration has induced notable repercussions on the structural, optoelectronics and morphological properties, which are reviewed. The first section of this paper offers a comprehensive review of the general characteristics of kesterite minerals. These crucial materials exhibit a high absorption coefficient (104 cm-1) and an optical band gap of 1.0-1.8 eV. Moreover, they are free of critical raw materials, non-toxic and sustainable. The second section depicts the substitution or modification of zinc by magnesium in kesterite. Additionally, this paper provides a comprehensive review of the quaternary and pentanary systems Cu2MgSn(S,Se)4 and Cu2Zn1-xMgxSnS4, highlighting their advantages and drawbacks. In the last section, a review of the quaternary or pentanary systems is conducted, namely Cu2ZnxFe1-xSnS4 and Cu2ZnxNi1-xSnS4, along with their effects on optoelectronic properties. In conclusion, various methods for obtaining modified or substituted kesterite materials using magnesium, iron and nickel have demonstrated sustainability, scalability for industrial production and potential candidacy as substitutes for conventional PV materials. The prospects for pentanary materials (Cu2Zn1-xMgxSnS4, Cu2Zn1-xFexSnS4 and Cu2Zn1-xNixSnS4) are to overcome the efficiency record of kesterite reported in 2014, which was 12.6 % for Cu2ZnSn(S,Se)4, and to enhance its optoelectronic properties through synthesis conditions that comply with the principles of green chemistry. Recent advancements and prospects for thin-film kesterite-based materials for photovoltaic applications are reviewed in which magnesium, iron and nickel are used as substitutes o

关键词： kesterite thin film magnesium iron nickel substitutes or modifiers novel materials sustainability SOLAR-CELL TECHNOLOGIES HYDROthermal SYNTHESIS thermal-decomposition ELECTRICAL-PROPERTIES OPTICAL-PROPERTIES CU2ZNSNS4 CU2FESNS4 EFFICIENCY NANOPARTICLES FABRICATION

Synthesis, Characterization and Thermodecomposition Kinetics of Dy-Complex with Furfural and DL-α-Alanine

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Journal of Rare Earths 2004年第S1期22卷 54-56页

作者：刘德军刘峙嵘毕彩丰 Radioactive Chemical Department of China Institute of Atomic Energy Beijing 102413 China Department of Applied Chemistry of East China Institute of Technology Fuzhou 344000 China Department of (Applied) Chemistry of Jinan University Jinan 250022 China

A new schiff base complex derived from furfural-DL-α-alanine and Dy(NO_3)·6H_2O was synthesized. It was characterized by elemental analysis, infrared spectra, ultraviolet spectra, molar conductivity measurements and thermogravimetric analysis. The stoichiometry was deduced to be [Dy(C_8H_8NO_3)(H_2O)(NO_3)](H_2O)(NO_3). Its thermal decomposition reaction kinetics was studied by thermogravimetry.

关键词： schiffbase ligand complex thermal-decomposition reaction kinetics

A Facile Synthesis of 9-Amino-1,2,3,4- Tetrahydroacridine from Isatin

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Journal of Beijing Institute of Technology 2002年第4期11卷 375-377页

作者：李加荣周馨我陈鹏郭永建北京理工大学化工与材料学院北京100081

Tacrine(9-amino-1,2,3,4-tetrahydroacridine) was synthesized using isatin as the raw material through isatin 3-oxime and 2-aminobenzonitrile with a yield of 68.1%. Sodium methoxide was used as the catalyst in the thermal decomposition of isatin 3-oxime, and tetramethylene sulfone was used as the solvent. The structure of tacrine was determined by IR, 1H NMR, MS and elemental analysis.

关键词： synthesis Alzheimer’s disease thermal-decomposition condensation