检索结果-南通市图书馆

Synergistic nano-tribological interaction between zinc dialkyldithiophosphate(ZDDP)and methyl oleate for biodiesel-fueled engines

引用

Friction 2021年第3期9卷 612-626页

作者： Siti Hartini HAMDAN Chiew Tin LEE Mei Bao LEE William Woei Fong CHONG Cheng Tung CHONG Suhaila Mohd SANIP Bio-Engineering Technology Department University Kuala Lumpur Malaysian Institute of Chemical&Bioengineering Technology(UniKL MICET)Alor Gajah 78000Malaysia School of Mechanical Engineering Faculty of EngineeringUniversiti Teknologi Malaysia(UTM)Johor Bahru 81310Malaysia Automotive Development Centre(ADC) Universiti Teknologi Malaysia(UTM)Johor Bahru 81310Malaysia China-UK Low Carbon College Shanghai Jiao Tong UniversityShanghai 201306China Faculty of Engineering and Physical Sciences University of Southampton Malaysia(UoSM)Iskandar Puteri 79200Malaysia

In biodiesel-fueled compression-ignition(CI)engines,dilution by unburned biodiesel has been found to have adverse effects on the boundary lubrication properties of additives in fully formulated engine *** dilution of engine lubricants could be even more pronounced for CI engines running on higher blend concentrations of *** the nanoscopic nature of the interaction,this study seeks to determine the nano-tribological properties of an engine lubricant additive(e.g.,zinc dialkyldithiophosphate(ZDDP))when diluted with a fatty acid methyl ester(e.g.,methyl oleate).Using lateral force microscopy(LFM)together with a fluid imaging technique,the lowest nanoscopic friction forces and coefficient of friction values(0.068-0.085)were measured for ZDDP when diluted with 70 vol%of methyl *** values are also observed to be lower than those measured for neat ZDDP and neat methyl oleate,respectively,under similar ***,interpreting the data with the Eyring thermal activation energy approach,it could then be elucidated that the lower frictional losses observed for the contact lubricated with this volumetric mixture are a result of the lower potential energy barrier and activation energy required to initiate *** energy values are approximated to be 2.6%and 28.9%(respectively)lower than that of the contact lubricated with neat *** was also found that the mixture,at this volumetric concentration,possesses the highest possible pressure activation energy(load-carrying capacity)along with the lowest possible shear activation energy(shearing),potentially indicating optimum tribological conditions for boundary ***,the findings of this study suggest that an optimum concentration threshold exists in which a synergistic nano-tribological interaction between additives and fatty acid methyl esters can be attained,potentially reducing boundary frictional losses of lubricated *** findings could prove to be ess

关键词： boundary lubrication lateral force microscopy thermal activation energy methyl ester boundary additives

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

thermally-enhanced photo-electric response of an organic semiconductor with low exciton binding energy for simultaneous and distinguishable detection of light and temperature

引用

Science China Chemistry 2022年第1期65卷 145-152页

作者： Yongxu Hu Li Yu Yinan Huang Zhongwu Wang Shuguang Wang Xiaosong Chen Deyang Ji Huanli Dong Jie Li Yajing Sun Liqiang Li Wenping Hu Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of ChemistryInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityFuzhou 350207China Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China

Simultaneous and distinguishable detection of external stimuli such as light and temperature is of great interest for a variety of scientific and industrial ***,an organic semiconductor with low exciton binding energy,low thermal activation energy and good charge transporting property produces thermally enhanced photo-electric response in organic phototransistors(OPTs),which thus provides an ideal and effective way to realize the simultaneous and distinguishable detection of temperature and ***,there is no report on such a kind of organic semiconductor until ***,we designed and synthesized a narrow band gap organic small molecule semiconductor 2,5-bis(2-butyloctyl)-3,6-bis(5-(4-(diphenylamino)phenyl)thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione(DPP-T-TPA)with low exciton binding energy(about 37 meV)and small activation energy(about 61 meV)for distinct thermal-dependence of charge carrier and *** low exciton binding energy enables the semiconductor to exhibit strong thermal dependence of exciton dissociation,which contributes to the thermally-enhanced photo-electric ***,the low thermal activation energy produces the weak thermal dependence of charge transport,which avoids the disturbance of thermally-modulated charge transport on photo-electric *** from these two features,phototransistors based on DPP-T-TPA show great potential in simultaneous and distinguishable detection of light and temperature,which represents a novel and efficient way for bifunctional detection.

关键词： phototransistor thermally activated photo-electric response exciton binding energy thermal activation energy

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Dielectric relaxation of interfacial polarizable molecules in chitosan ice-hydrogel materials

引用

Journal of Materiomics 2018年第1期4卷 35-43页

作者： Y.Q.Li C.X.Zhang P.Jia Y.Zhang L.Lin Z.B.Yan X.H.Zhou J.-M.Liu Laboratory of Solid State Microstructures and Innovative Center of Advanced Microstructures Nanjing UniversityNanjing 210093China Institute for Advanced Materials Hubei Normal UniversityHuangshi 435002China

The functionalities of hydrogel-based smart materials are highly related to the electrostatic interactions and molecular polarization associated with the polymer networks and encapsulated water droplets,and therefore the dielectric responses of the polarizable molecules in the polymer,water,and polymer-water interfaces are particularly attractive,where the properties of polymer-water interfacial molecules remain *** from extensive dielectric relaxation spectroscopy studies on polymer hydrogel solutions,in this work we investigate the dielectric response of chitosan hydrogels below the water solidifying point(ice-hydrogels)so that the contribution of chitosan-water interfacial molecules can be *** is revealed that the chitosan-water interfacial polarizable molecules have slow dielectric relaxation but large polarization compared with the chitosan chains and water molecules,and the dielectric relaxations beyond~10^(4)Hz are substantially *** thermal activation energy of the dielectric relaxation for these interfacial polarizable molecules can be as large as 0.93 eV,i.e.89.73 kJ/*** present work provides a platform for characterizing the polymer-water electrostatic interactions and interfacial polarizable molecules,informative to understand the microstructure-property relationships of chitosan-based hydrogel materials.

关键词： Chitosan hydrogels Dielectric relaxation Polymer-water interfacial polarizable molecules thermal activation energy

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：