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An Electrochemical Cleaning Technique for Removal of surface contamination before Texturization of Silicon Solar Cells

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Semiconductor Photonics and Technology 2010年第1期16卷 13-17页

作者： ZHANG Jianxin LIU Yuling TAN Baimei NIU Xinhuan GAO Baohong School of Information and Communication Engineering Tianjin Polytechnic University Tianjin 300160 CHN Institute of Microelectronics Hebei University of Technology Tianjin 300130 CHN

In order to decrease the consumption of reagents and silicon during removal of surface contamination before silicon texturing in solar cell manufacturing industry, a new low-cost surface treatment approach of electrochemical cleaning technique(ECT) is reported. In this technique, a powerful oxidizing electrolyte was obtained from the electrochemical reaction on Boron-doped Diamond(BDD) electrodes, and applied during removal of surface contaminations on silicon wafer surfaces. The slightly polished monocrystalline silicon surfaces after cleaning were compared with the ones of primal silicon wafers. The measurement results show that ECT is quite efficient in removing NaCl and organic contaminants. After cleaning, the contrast test was conducted for the textured silicon wafers with/without pre-treatment(polish) separately. The results show that the size of pyramids on the surface without traditional polishing process is homogeneous and smaller than 4μm, and the average surface reflectance is much lower in the wavelength range from 400nm to 800nm. Therefore, the new technique can save silicon material, and effectively avoid optical losses for improving photoconversion effect of solar cells.

关键词： electrochemical cleaning surface contamination solar cell texturization Boron-doped Diamond(BDD) electrodes

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Dust Deposition’s Effect on Solar Photovoltaic Module Performance:An Experimental Study in India’s Tropical Region

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Journal of Renewable Materials 2022年第8期10卷 2133-2153页

作者： K.R.Chairma Lakshmi Geetha Ramadas Department of Electrical and Electronics Engineering R.M.K.Engineering CollegeChennaiIndia

A solar PV panel works with maximum efficiency only when it is operated around its optimum operating point or maximum power point.Unfortunately,the performance of the solar cell is affected by several factors like sun direction,solar irradiance,dust accumulation,module temperature,as well as the load on the system.Dust deposition is one of the most prominent factors that influence the performance of solar panels.Because the solar panel is exposed to the atmosphere,dust will accumulate on its surface,reducing the quantity of sunlight reaching the solar cell and diminishing output.In the proposed work,a detailed investigation of the performance of solar PV modules is carried out under the tropical climatic condition of Chennai,India,where the presence of dust particles is very high.The data corresponding to four different dust samples of various densities at four solar irradiation levels of 220,525,702,and 905 W/m^(2)are collected,and performance analysis is carried out.Based on the analysis carried out,the maximum power loss is found to be 73.51%,66.29%,65.46%,and 61.42%,for coal,sand,brick powder,and chalk dust respectively.Hence,it can be said that coal dust contributes to the maximum power loss among all four dust samples.Due to heat dissipation produced by dust deposition,the performance of solar PV modules is degraded as the temperature rose.

关键词： Solar photovoltaic power generation system dust effect electrical efficiency loss dust samples surface contamination

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Investigation of natural contamination layer growth on optical substrates

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Chinese Physics C 2018年第11期42卷 107-119页

作者：蒋励黄秋实 Igor V. Kozhevnikov 姚逸云冯江涛冯宇飞马彬焦宏飞陈鸿张众王占山 Key Laboratory of Advanced Micro-Structured Materials MOE Institute of Precision Optical Engineering School of Physics Science and Engineering Tongji University Shanghai 200092 China Shubnikov Institute of Crystallography of Federal Scientific Research Centre "Crystallography and Photonics" of the Russian Academy of Sciences Leninskiy pr. 59 Moscow 119333 Russia

The surface contamination layer on mirrors can cause significant degradation of the optical performance, which is widely observed in applications, particularly in the fabrication of X-ray focusing telescopes. In this paper, we study the natural contamination layer arising from adsorption precipitation of hydrocarbons or other organic and water molecules in the absence of any external factor. Temporal evolution of the layer formed on super-smooth fused silica, borosilicate glass, and silicon substrates is studied by X-ray reflectometry, atomic force microscopy, and transmission electron microscopy for a one-year period after surface cleaning. The general characteristics of adhesion layer growth are established and discussed. The reconstructed dielectric constant profiles demonstrate that an increase in the adhesion layer thickness, deposited mass and density over time obeys power laws with extremely small exponents. Therefore, the adhesion layer growth is rapid immediately after surface cleaning, with a - 1 nm thick layer formed within the first day on all three substrates studied, while the layer density is low （- 1 g/cm^3）. The layer growth on the fused silica and silicon substrates became very slow in the succeeding days, with only a 1.4-1.5 nm thick layer and 1.2-1.3 g/cm^3 density after one year of storage in air. At the same time, the adhesion layer growth on the glass substrate showed unexpected acceleration about two months after cleaning, so that the layer thickness reached - 2.2 nm after one year of storage. The reason for this effect, which is connected with leaching of the glass, is discussed briefly.

关键词： X-ray telescope surface contamination surface dynamics X-ray reflectometry inverse problem

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