检索结果-南通市图书馆

Shape Controllable Preparation of Submicronic Cadmium Tetrazole-Based Metal-Organic Frameworks via Solvothermal or Microwave-Assisted Methods and Their Photocatalytic Studies

引用

Chinese Journal of Chemistry 2017年第2期35卷 209-216页

作者： Arti Chouhan Guillaume Pilet Stephane Daniele Ashutosh Pandey Department of Chemistry MNNIT Allahabad Allahabad 211004 India LMI UMR CNRS 5615 University Claude Bernard-Lyon 1 69622 Villeurbanne cedex France IRCELYON UMR CNRS 5256 University Claude Bernard-Lyon 1 69626 Villeurbanne cedex France

The paper describes the experiments conducted to create shape controllable preparations of submicronic cad- mium tetrazole-based MOFs. In order to prepare the submicron sized blocks and tubes of bis[5-（2-pyridyltetrazo- lato）]diaquacadmium（II） [（2-PTZ）2Cd（H20）2] MOFs both solvothermal and microwave augmented reaction proce- dures have been followed. Cadmium nitrate tetrahydrate, cyanopyridine and sodium azide were used as reactants in both the conditions without any surfactants or modulators. Subsequently, IR spectroscopy and single-crystal X-ray crystallographic studies were performed on the prepared MOFs. Examinations using scanning electron microscopy and X-ray powder diffraction of the products made by the microwave method showed formation of bundles of reg- ular submicrotubes, as opposed to the submicron-sized irregular blocks of the Cd-MOF obtained through the sol- vothermal method. The fluorescence peak of the sub-microtube MOF was found at 460 nm while the irregu- lar-blocks emitted at 442 nm indicating a red shift for the former. In addition, the relative intensity of the peak at 460 nm was higher in the former, indicating a decrease in the crystallite size. Band gaps of the MOFs calculated by using the Tauc plots were 2.87 and 2.73 eV, respectively. Their photocatalytic performances using methylene blue under UV-vis irradiation have been investigated.

关键词： cadmium microwave synthesis solvothermal synthesis submicrotube photocatalysis

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：