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Analyses of the NAC Transcription Factor Gene Family in Gossypium raimondii Ulbr.:Chromosomal Location,structure,Phylogeny,and Expression Patterns

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Journal of Integrative Plant Biology 2013年第7期55卷 663-676页

作者： Haihong Shang Wei Li Changsong Zou Youlu Yuan State Key Laboratory of Cotton Biology Institute of Cotton Researchthe Chinese Academy of Agricultural Sciences

NAC domain proteins are plant-specific transcription factors known to play diverse roles in various plant developmental processes. In the present study, we performed the first comprehensive study of the NAC gene family in Gossypium raimondii Ulbr., incorporating phylogenetic, chromosomal location, gene structure, conserved motif, and expression profiling analyses. We identified 145 NAC transcription factor （NAC-TF） genes that were phylogenetically clustered into 18 distinct subfamilies. Of these, 127 NAC-TF genes were distributed across the 13 chromosomes, 80 （55%） were preferentially retained duplicates located in both duplicated regions and six were located in triplicated chromosomal regions. The majority of NAC-TF genes showed temporal-, spatial-, and tissue-specific expression patterns based on tran- scriptomic and qRT-PCR analyses. However, the expression patterns of several duplicate genes were partially redundant, suggesting the occurrence of sub-functionalization during their evolution. Based on their genomic organization, we concluded that genomic duplications contributed significantly to the expansion of the NAC-TF gene family in G. raimondii. Comprehensive analysis of their expression profiles could provide novel insights into the functional divergence among members of the NAC gene family in G. raimondii.

关键词： Cotton expression patterns NAC phylogeny structure,

Synthesis of GoldMag particles with assembled structure and their applications in immunoassay

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Science China Chemistry 2006年第6期49卷 534-540页

作者： CUI Yali1, ZHANG Lianying1, SU Jing1, ZHANG Caifeng3, LI Qi2, CUI Ting3, JIN Boquan2 & CHEN Chao1,3 1. Biochip Research and Development Center, Northwest University (National Engineering Research Center for Miniaturized Detection System), Xi’an 710069, China 2. Department of Immunology, The Fourth Military Medical University, Xi’an 710032, China 3. Shaanxi Lifegen Co., Ltd., Xi’an 710069, China Biochip Research and Development Center Northwest University (National Engineering Research Center for Miniaturized Detection System) Xi’an China Shaanxi Lifegen Co. Ltd. Xi’an China Department of Immunology The Fourth Military Medical University Xi’an China

Micrometer-sized Fe3O4 particles and nano-sized gold particles were first synthesized by methods of self-aggregation of surface-chemically modified Fe3O4 nanoparticles and citrate reduction of the Au3+ to Au0, respectively. Interaction between these two types of particles resulted in the assembly of nano-sized gold particles on the surface of the micrometer-sized Fe3O4 particles, forming an assembled structure with the Fe3O4 core particles around which are attached nano-sized gold parti- cles. The Fe3O4/Au structure is named GoldMag particles with assembled structure. The synthetic process, structure, and magnetic property of the GoldMag particles were analyzed. GoldMag particles with assembled structure have an irregular shape, rough surface with a diameter of 2―3 μm. These particles exhibit the superparamagnetic property with saturated magnetization of 41 A·m2/kg. In a single step, antibodies could be readily immobilized onto the surface of the particles with a high binding capacity. The GoldMag particles can be used as a novel carrier in immunoassays. The maximum quantity of human IgG immobilized onto GoldMag particles was 330 μg/mg. In order to validate the quality of the GoldMag particles as immunoassay carriers, an immunoassay system was used. The relative amount of immobilized human IgG was measured by HRP-labeled anti human IgG. The coefficient of variation within parallel samples of each group was below 6% and the coefficient of variation of means between five groups carried out separately was below 7%. Based on the sandwich method, the Hepatitis B surface antigen (HBsAg) and interleukin-8 (IL-8) were also analyzed by qualitative and quantitative detection, respectively. The result indicated that the GoldMag particles with assembled structure were an ideal carrier in immunoassay.

关键词： GoldMag particles with assembled structure, synthesis, carrier, immunoassay.

The atomic structure and the properties of Ununbium (Z=112) and Mercury (Z=80)

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Science China(Physics,Mechanics & Astronomy) 2007年第6期50卷 707-715页

作者： S.FRITZSCHE B.FRICKE Institut fr Physik Universita..t Kassel 34132Germany

A super heavy element Uub (z = 112) has been studied theoretically in conjunction with rela-tivistic effects and the effects of electron correlations.The atomic structure and the oscillator strengths of low-lying levels have been calculated,and the ground states have also been determined for the singly and doubly charged ions. The influence of relativity and correlation effects to the atomic properties of such a super heavy element has been investigated in detail. The results have been compared with the properties of an element Hg. Two energy levels at wave numbers 64470 and 94392 are suggested to be of good candidates for experimental observations.

关键词： super heavy element, atomic structure, relativistic effects, electron correlation effects, MCDF method A super heavy element Uub (Z = 112) has been studied theoretically in conjunction with rela-tivistic effects and the effects of electron correlations. The atomic structure and the oscillator strengths of low-lying levels have been calculated, and the ground states have also been determined for the singly and doubly charged ions. The influence of relativity and correlation effects to the atomic properties of such a super heavy element has been investigated in detail. The results have been compared with the properties of an element Hg. Two energy levels at wave numbers 64470 and 94392 are suggested to be of good candidates for experimental observations.……

Lithospheric composition and structure beneath the northern margin of the Qinling orogenic belt——On deep-seated xenoliths in Minggang region of Henan Province

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Science China Earth Sciences 2004年第1期47卷 13-22页

作者： LU Fengxiang WANG Chunyang ZHENG Jianping Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China

Swarms of mafic-intermediate volcaniclastic bodies occur in the Minggang region of Henan Province, a tectonic boundary between the North Qinling and the North China Block, and emplaced at (178.31±3.77) Ma. These volcanic rocks are subalkaline basaltic andesites and contain abundance of lower crust and mantle xenoliths. Thus this area is an ideal place to reveal the lithospheric composition and structure beneath the northern margin of the Qinling orogenic belt. Geochemical data indicate that these mafic granulites, eclogites and metagabbros have trace elemental and Pb isotopic characteristics very similar to those rocks from the South Qinling Block, representing the lower part of lower crust of the South Qinling which subducted beneath the North China Block. Talcic peridotites represent the overlying mantle wedge materials of the North China Block, which underwent the metasomatism of the acidic melt/fluid released from the underlying lower crust of the South Qinling Block. Deep tectonic model proposed in this paper is that after the Late Paleozoic South Qinling lithosphere subducted northward and decoupled, the upper part of the lithosphere emplaced under the North Qinling and the lower part continuously subducted northward under the North China Block. In Early Mesozoic, the North Qinling Block obducted northward and the North China Block inserted into the Qinling orogenic belt in a crocodile-mouth shape.

关键词： lithosphere structure, deep-seated xenolith, decoupling and subduction.

Syntheses and Br…π supramolecular interactions in the crystal structure of ipriflavone bromides

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Science China Chemistry 2005年第4期48卷 315-325页

作者： ZHANG Zunting WANG Xiaobing School of Chemistry and Materials Science Shaanxi Normal UniversityXi'an 710062China School of Chemistry and Materials ScienceShaanxi Normal UniversityXi'an 710062China

Two novel compounds,3,8-dibromo-2-methoxyl-7-isopropoxyisoflavanone (1) and 3,6-dibromo-2-methoxyl-7-isopropoxyisoflavanone (2),are synthesized via bromination reaction of their precursor ipriflavone in methanol.The mixture of 1 and 2 co-crystallizes in ethanol and forms two different crystal shapes,the shape of 1 being block and 2 prism,they can be separated manually.1 and 2 are characterized by IR,1H NMR and single crystal X-ray diffraction.The mechanism of bromination reaction is also discussed.1 crystallizes in the monoclinic space group P 21/n with cell parameters a = 1.3569(3) nm,b = 0.6706(2) nm,c = 2.0704(4) nm,?= 97.50(2)°,V = 1.8678(6) nm3,Z = 4,Dc = 1.672 Mg/m3,R = 0.0455,wR = 0.0779,F(000) = 936.2 crystallizes in the monoclinic space group P 21/c with cell parameters a =1.3854(17) nm,b = 1.1215(14) nm,c = 1.3038(17) nm,? = 103.71(2)°,V = 1.968(4) nm3,Z = 4,Dc = 1.587 Mg/m3,R = 0.0306,wR = 0.0619,F(000) = 936.The Br…p interactions,hydrogen bonds,aromatic hy-drogen bonds and aromatic stacking interactions exist in the crystal structures of 1 and 2,which lead them into supramolecular compounds with a three-dimensional network structure,respec-tively.1 and 2 are the isoflavanone derivatives halogenated at C3 and this kind of isoflavanone halides has not been reported yet.

关键词： ipriflavone, bromine, electrophilic addition, crystal structure, isoflavanone, supramolecular interaction.

Valence electron structure of cementite phase and its interface and the tempering phenomenon

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Science China(Technological Sciences) 2002年第3期45卷 282-290页

作者：李志林刘志林刘伟东 Beijing University of Chemical Technology Beijing 100029 China Department of Materials Science and Engineering Liaoning Institute of Technology Jinzhou 121001 China

Tempering is an important phenomenon in ferrous alloys. Most steels, especially alloy-ing steels, are used after quenching and tempering. To design the composition of quenching andtempering steels, control the tempering process more effectively, improve the properties aftertempering and realize the potentials of steels, the essence of tempering process and the proper-ties of tempering products have to be understood. In this paper, the phase structure factors andinterface conjunction factors of common alloying elements in cementite and its interface are calcu-lated out. The relationships between these valence electron structure parameters and (i) thephenomena of martensite decomposition, (ii) transformation, gathering and growth of the carbidesand (iii) the mechanical properties of tempering products are built up. The nature of the effect ofalloying elements on tempering process and properties of tempering products is uncovered on thelevel of valence electron structure. One new theoretical foundation for alloy design is provided.

关键词： valence electron structure, tempering, cementite, interface, mechanical property.

Synthesis and crystal structure of complex of Ce(NO_3)_3 with N-(3-methyl-pyridin-2-yl)-formimidoyl-(3-methyl-pyridin-2-yl) hydrazone

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Science China Chemistry 2004年第3期47卷 251-256页

作者： JIANG Yinzhi1,2 & HU Weixiao1 1. Department of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310032, China 2. Department of Applied Chemistry, Zhejiang Institute of Science and Technology, Hangzhou 310033, China Department of Pharmaceutical Science Zhejiang University of Technology Hangzhou China Department of Applied Chemistry Zhejiang Institute of Science and Technology Hangzhou China

The reaction of 3,6-di-(3-methyl-pyridin-2-yl)-s-tetrazine (DMPTZ, II) with CeIII salt [Ce(NO3)3·6H2O] generates a new ligand, N-(3-methyl-pyridin-2-yl)-formimidoyl-(3-methyl- pyridin-2-yl) hydrazone (L), and forms a new complex: a mononuclear complex [Ce(L)(NO3)2 (H2O)3]·NO3 (III). Crystal data for III: space group P-1, with a = 0.7133(4) nm, b = 1.1139(2) nm, c = 1.4572(3) nm, a = 102.13(2)? b = 99.81(3)? g = 91.10(3)? Z = 2, V = 1113.6(7) nm3, m = 2.123 mm-1 and F(000) = 630. L acts as a tri-dentate chelating ligand in III. There are 10 coor-dination sites around Ce3+ of III, which are respectively occupied by seven oxygen atoms (four from two nitrate anions and three from three H2O molecules) and three nitrogen atoms (all from L). The cerium atom and three chelating nitrogen atoms are coplanar. The mechanism of the metal assisted decomposition is discussed briefly.

关键词： rare earth, complex, crystal structure, synthesize, 3,6-bis (3-methyl-pyridin-2-yl)-s-tetrazine, N-(3-methyl-pyridin- 2-yl)-formimidoyl-(3-methyl-pyridin-2-yl) hydrazone.

Synthesis, crystal structure and magnetic properties of a novel manganese(II)-nitronyl nitroxide-azido(μ_(1,1) and μ_(1,3)) one-dimensional complex

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Science China Chemistry 2003年第6期46卷 533-541页

作者：王利亚刘志亮张晨曦刘占泉廖代正姜宗慧阎世平 Department of Chemistry Nankai UniversityTianjin 300071 China Department of ChemistryLuoyang Teachers CollegeLuoyang 471022 China Department of Chemistry Nankai UniversityTianjin 300071 China Department of Chemistry Nankai UniversityTianjin 300071 China State Key Laboratory of Coordination ChemistryNanjing UniversityNanjing 210093 China Department of Chemistry Nankai University.Tianjin 300071 China

A novel one-dimensional manganese(II) complex containing nitronyl nitroxide radical [Mn2(IM2-py)2(Ac)2(μ1,1-N3)(μ1,3-N3)·EtOH]n was synthesized and characterized structurally and magnetically. It crystallizes in the monoclinic space group p21/n. Each Mn(II) ion is six-coordinated in a distorted octahedral environment. The two N atoms of the nitronyl nitroxide radical and the two O atoms of acetate ligands are in the equatorial plane, whereas the two different azido bridging ligands are in trans axial position. Mn(II) ions are linked by nitrogen atom of μ1,1-azido and oxygen atoms of two carboxy groups to form a Mn-Mn unit. Mn-Mn units are linked by azido ligands through μ1,3 bridging style to form a one-dimensional chain. The compound is connected by the coordination bonds, π-π interactions and hydrogen bonds as a three-dimensional structure. Magnetic susceptibility data support that there are stronger antiferromagnetic interactions between the radical and Mn(II) ion, weak antiferromagnetic interactions between the Mn-R units, and very weak antiferromagnetic interactions between the R-Mn-Mn-R units.

关键词： nitroxide radical, manganese complex, azido, crystal structure, magnetism.

On the variation of water resource structure in the Lower Yellow River

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Science China(Technological Sciences) 2004年第Z1期47卷 127-141页

作者： NI Jinren1, WANG Yudong1, QIAN Zhenghan1, LI Tianhong1 & ZHAO Yean2 1. Department of Environmental Engineering, Peking University The Key Laboratory of Water and Sedi- ment Sciences, Ministry of Education, Beijing 100871, China 2. Institute of Hydraulic Research, Yellow River Conservancy Commission, Zhengzhou 450003, China Department of Environmental Engineering Peking University Beijing China The Key Laboratory of Water and Sediment Sciences Ministry of Education Beijing China Institute of Hydraulic Research YellowRiver Conservancy Commission Zhengzhou China

In view of river functions and the Minimum Water Demand for River Ecosystem (MWDRE), the water resources in the Lower Yellow River is further divided into three portions, i.e. water available for ecosystem (WE), water exploitable for socioeconomic purposes (WS) and excess flood water (WF). Corresponding conceptions and practical significances are expounded in details. The annual amount of the three portions of water resources from 1950 to 2001 is worked out on the basis of the daily hydrologic data, and the division of different portions is discussed. The results indicate that although the essential water demand for river functions is considered preferentially, the amount of the WE has decreased dramatically while its proportion increased gradually since the 1950s, and the shortage to the MWDRE increased markedly; both the amount and the proportion of the WS decreased notably. Since the 1990s, the actual water consumption for socioeconomic purposes in the lower reaches of the river basin has already exceeded the maximum amount of the WS and has to take over the WE which is already insufficient, hence not only the normal river functions are further disturbed and the river course shrinks greatly, but also the proportion and potential danger of the WF show no decreasing tendency in spite of the sharp decrease of upstream runoff.

关键词： the Yellow River, water resource structure, water available for ecosystem, water exploitable for socioeconomic purposes, excess flood water.