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Experimental study on desorption of soluble matter as influenced by cations in static water

Water Science and Engineering 2014年第4期7卷 384-394页

作者： Wen-sheng XU Li CHEN Xiao-xia TONG Xiao-ping CHEN Ping-cang ZHANG Division of Soil and Water Conservation Changjiang River Scientific Research Institute State Key Laboratory of Water Resources and Hydropower Engineering Science Wuhan University

With variation of drainage basin environments, desorption of soluble matter has become one of the significant erosion processes in rivers. It has a considerable impact on flow and sediment transport, as well as processes of river bed deformation and landform evolution throughout a watershed. In this study, considering influences on sediment movement, especially on cohesive sediment transport, Ca^2＋ and H^＋ were chosen as characteristic ions of soluble matter, and the total desorption quantity of Ca^2＋ and pH value when the desorption equilibrium is reached were employed as two indexes representing the desorption of soluble matter. By means of an indoor experiment, desorption of soluble matter as influenced by cations in static water was investigated. The results show that the total desorption quantity of soluble matter increases with the initial cation concentration until a maximum desorption quantity value is obtained and maintained. The total desorption quantity of soluble matter depends on properties of the specific cations in static water, and the stronger the affinity is between the cation and sediment surface, the higher the total desorption quantity will be. Finally, a strong approximate linear relationship between desorption quantities for different kinds of soluble matters was obtained, which means that variation of pH values can accurately reflect the desorption results of soluble matter.

关键词： soluble matter desorption cation sediment static water indoor experiment

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