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Recent progress in all-inorganic tin-based perovskite solar cells:a review

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Science China Chemistry 2024年第4期67卷 1117-1136页

作者： Minghao Wang Yu Shi School of Electronics and Information Engineering Wuxi UniversityWuxi 214105China Institute of Advanced Materials Nanjing Tech UniversityNanjing 211816China

Recently,power conversion efficiency(PCE)of organic-inorganic hybrid perovskite solar cells(PSCs)has been improved to26.1%.However,the toxicity issue of lead still hinders the large-scale commercial production and application of lead(Pb)-based halide ***,environmentally friendly tin(Sn)-based perovskites have recently shown excellent *** them,the all-inorganic Sn-based perovskites,including CsSnX_(3) and Cs_(2)SnX_(6),have better stability,more suitable bandgap,and higher charge mobility,which have attracted more attention from researchers than organic-inorganic Sn-based hybrid ***,we review recent research progress on all-inorganic Sn-based perovskite materials and corresponding solar cell ***,we also summarize the current challenges and future research directions for this type of PSCs.

关键词： solar cells perovskite all-inorganic CsSnX_(3) Cs_(2)SnX_(6)

One‑Step Gas-Solid‑Phase Diffusion‑Induced Elemental Reaction for Bandgap‑Tunable Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI Thin Film solar cells

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Nano-Micro Letters 2023年第4期15卷 261-271页

作者： Erchuang Fan Manying Liu Kangni Yang Siyu Jiang Bingxin Li Dandan Zhao Yanru Guo Yange Zhang Peng Zhang Chuantian Zuo Liming Ding Zhi Zheng Key Laboratory of Micro‑Nano Materials for Energy Storage and Conversion of Henan Province College of Chemical and Materials EngineeringInstitute of Surface Micro and Nano MaterialsXuchang UniversityXuchang 461000People’s Republic of China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001People’s Republic of China Center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190People’s Republic of China

Lead-free inorganic copper-silver-bismuth-halide materials have attracted more and more attention due to their environmental friendliness,high element abundance,and low ***,we developed a strategy of one-step gas-solid-phase diffusioninduced reaction to fabricate a series of bandgap-tunable Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI bilayer films due to the atomic diffusion effect for the first *** designing and regulating the sputtered Cu/Ag/Bi metal film thickness,the bandgap of Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI could be reduced from 2.06 to 1.78 *** cells with the structure of FTO/TiO_(2)/Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI/carbon were constructed,yielding a champion power conversion efficiency of 2.76%,which is the highest reported for this class of materials owing to the bandgap reduction and the peculiar bilayer *** current work provides a practical path for developing the next generation of efficient,stable,and environmentally friendly photovoltaic materials.

关键词： Cu_(a)Agm_(1)Bim_(2)I_(n)/CuI Elemental reaction Bandgap tuning solar cells Gas-solid phase

Novel broad spectral response perovskite solar cells:A review of the current status and advanced strategies for breaking the theoretical limit efficiency

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Journal of Materials Science & Technology 2023年第9期140卷 33-57页

作者： Bin Liu Yuqi Wang Yanjie Wu Biao Dong Hongwei Song State Key Laboratory on Integrated Optoelectronics College of Electronic Science and EngineeringJilin UniversityChangchun 130012China

Perovskite solar cells(PSCs)have revolutionized photovoltaic *** power conversion efficiency(PCE)of PSCs has now reached 25.7%,which is comparable to current state-of-the-art silicon-based ***,PSCs can only utilize light of 300-850 nm,resulting in wasted near-infrared(NIR)light,which occupies 45%-50%of entire solar spectrum,which is one of the main reasons limiting the development of *** strategies to broaden NIR spectroscopy to break the theoretical limit efficiency of PSCs have recently attracted extensive *** review firstly outlines theoretical basis for improving the NIR spectroscopy,then systematically summarizes some key strategies and research progress to improve NIR spectroscopy of *** firstly provided a comprehensive overview of historical research experiments on narrow-gap perovskite absorber layers,rare earth up-conversion,tandem devices,and integrated perovskite/organic solar cells and given constructive suggestions for exceeding limit efficiency of ***,based on the development status of PSCs with NIR utilization,the current issues,solutions and future development directions of important aspects to improve NIR utilization of PSCs are systematically *** review lays the foundation for the efficiency of PSCs beyond the Shockley-Queisser limit,and provides a certain development prospect.

关键词： Organic materials Up-conversion materials Perovskite solar cells Tandem cells Integrated perovskite/organic heterojunction solar cells

Multidentate anchoring through additive engineering for highly efficient Sb_(2)S_(3)planar thin film solar cells

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Journal of Materials Science & Technology 2021年第30期89卷 36-44页

作者： Jian Han Xingyu Pu Hui Zhou Qi Cao Shuangjie Wang Jiabao Yang Junsong Zhao Xuanhua Li State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072China Northwestern Polytechnical University-Queen Marry University of London(NPU-QMUL)Joint Research Institute of Advanced Materials and Structures(JRI-AMAS)Xi’an 710072China

Sb_(2)S_(3)is a promising candidate for the flexible solar cells or the top subcells in tandem solar cells due to its wide-bandgap,less toxic,acceptable cost and progressive power conversion efficiency(PCE).However,the poor quality and high trap states of Sb_(2)S_(3)films limit the device performance further ***,we adopt a multidentate ionic liquid,tetramethylammonium hexafluorophosphate([TMA][PF_(6)])as a novel additive to address this *** octahedral[PF_(6)]~-contains six different oriented fluorine atoms with the lone pair electrons,which could coordinate with Sb atoms due to the multidentate ***,the high-quality Sb_(2)S_(3)film with low trap states has been ***,the Fermi level of the Sb_(2)S_(3)film has been upshifted,thereby showing an effective charge *** a result,all photovoltaic parameters of the optimized Sb_(2)S_(3)devices are obviously enhanced,boosting the final PCE from 4.43(control device)to 6.83%.Our study about the multidentate anchoring is manifested to be an effective method to enhance the Sb_(2)S_(3)device performance.

关键词： Sb_(2)S_(3) solar cells Additive engineering Multidentate anchoring Passivation

Acetylacetone-TiO_(2) Promoted Large Area Compatible Cascade Electron Transport Bilayer for Efficient Perovskite solar cells

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Energy & Environmental Materials 2024年第2期7卷 221-228页

作者： Hyong Joon Lee Jin Kyoung Park Jin Hyuck Heo Sang Hyuk Im Department of Chemical and Biological Engineering Korea University145 Anam-ro Seongbuk-guSeoul 17104Korea

In designing efficient perovskite solar cells(PSCs),the selection of suitable electron transport layers(ETLs)is critical to the final device performance as they determine the driving force for selective charge ***_(2)nanoparticles(NPs)based ETLs have been a popular choice for PSCs due to superior electron mobility,but their relatively deep-lying conduction band energy levels(ECB)result in substantial potential ***,TiO_(2)NPs establish favorable band alignment owing to shallower ECB,but their low intrinsic mobility and abundant surface trap sites impede the final *** this reason,constructing a cascaded bilayer ETL is highly desirable for efficient PSCs,as it can rearrange energy levels and exploit on advantages of an individual *** this study,we prepare SnO_(2)NPs and acetylacetone-modified TiO_(2)(Acac-TiO_(2))NPs and implement them as bilayer SnO_(2)/Acac-TiO_(2)(BST)ETL,to assemble cascaded energy band ***_(2)contributes to rapid charge carrier transport from high electron mobility while Acac-TiO_(2)minimizes band-offset and effectively suppresses interfacial ***,the optimized BST ETL generates synergistic influence and delivers power conversion efficiency(PCE)as high as 23.14%with open-circuit voltage(V_(oc))reaching 1.14 ***,the BST ETL is transferred to a large scale and the corresponding mini module demonstrates peak performance of 18.39%PCE from 25 cm^(2)aperture ***,the BST-based mini module exhibit excellent stability,maintaining 83.1%of its initial efficiency after 1000 h under simultaneous 1 Sun light-soaking and damp heat(85℃/RH 85%)environment.

关键词： acetylacetone large area perovskite solar cells TiO_(2)

Dimethylamine oxalate manipulating CsPbI_(3) perovskite film crystallization process for high efficiency carbon electrode based perovskite solar cells

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Journal of Energy Chemistry 2024年第6期93卷 221-228,I0006页

作者： Wenran Wang Xin Peng Jianxin Zhang Jiage Lin Rong Huang Guizhi Zhang Huishi Guo Zhenxiao Pan Xinhua Zhong Huashang Rao Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and EnergySouth China Agricultural UniversityGuangzhou 510642GuangdongChina College of Chemistry and Civil Engineering Shaoguan UniversityShaoguan 512005GuangdongChina Guangdong Provincial Key Laboratory of Utilization and Conservation of Food and Medicinal Resources in Northern Region Shaoguan UniversityShaoguan 512005GuangdongChina

Crystallization process determines the quality of perovskite films and the performances of resultant perovskite solar cells(PSCs).Dimethylamine oxalate has been proven as a multifunctional modulator,and is explored as an efficient additive in manipulating the crystallization process of CsPbI_(3) perovskite *** one hand,oxalate serves as the precipitator that facilitates the nucleation process of *** larger size of intermediate is conductive to the larger size and smaller grain boundaries of resultant *** the other hand,in subsequent annealing process,the phase conversion and growth process of transient perovskite can be decelerated due to the strong interactions of oxalate with both dimethylamine cation(DMA^(+))and Pb^(2+).Due to the optimized crystallization kinetics,the morphology and quality of CsPbI_(3) perovskite films are comprehensively improved with lower defect concentrations,and charge recombination loss is effectively *** from the optimized crystal quality of perovskite films,the carbon electrode-based CsPbI_(3) PSCs exhibit a champion efficiency of 18.48%.This represents one of the highest levels among all hole transport layer-free inorganic perovskite solar cells.

关键词： solar cells Perovskite CsPbI_(3) Carbon electrodes Oxalate

Ligand engineering of perovskite quantum dots for efficient and stable solar cells

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Journal of Energy Chemistry 2022年第6期31卷 626-648,I0018页

作者： Shanshan Ding Mengmeng Hao Tongen Lin Yang Bai Lianzhou Wang School of Chemical Engineering and Australian Institute of Bioengineering and Nanotechnology The University of QueenslandBrisbaneQLD 4072Australia

Lead halide perovskite quantum dots(PQDs) have recently emerged as promising light absorbers for photovoltaic application due to their extraordinary optoelectronic properties. Surface ligands are of utmost importance for the colloidal stability and property tuning of PQDs, while their highly dynamic binding nature not only impedes further efficiency improvement of PQD-based solar cells but also induces intrinsic instability. Tremendous efforts have been made in ligand engineering with good hopes to solve such challenging issues in the past few years. In this review, we first present a fundamental understanding of the role of surface ligands in PQDs, followed by a brief discussion and classification of various ligands that have the potential for improving the electronic coupling and stability of PQD solids. We then provide a critical overview of recent advances in ligand engineering including the strategies of in-situ ligand engineering, postsynthesis/-deposition ligand-exchange, and interfacial engineering, and discuss their impacts on changing the efficiency and stability of perovskite QD solar cells(QDSCs). Finally, we give our perspectives on the future directions of ligand engineering towards more efficient and stable perovskite QDSCs.

关键词： Perovskite quantum dots Ligand engineering Defect passivation solar cells Stability

Boosting efficiency and stability of perovskite solar cells with nickel phthalocyanine as a low-cost hole transporting layer material

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Journal of Materials Science & Technology 2018年第9期34卷 1474-1480页

作者： Mustafa Haider Chao Zhen Tingting Wu Gang Liu Hui-Ming Cheng Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences 72 Wenhua Road Shenyang 110016 China University of Chinese Academy of Sciences 19(A) Yuquan Road Beijing 100049 China School of Materials Science and Engineering University of Science and Technology of China 72 Wenhua Road Shenyang 110016 China Low-Dimensional Material and Device Laboratory Tsinghua-Berkeley Shenzhen Institute Tsinghua University 1001 Xueyuan Road Shenzhen 518055China Center of Excellence in Environmental Studies King Abdulaziz University Jeddah 21589 Saudi Arabia

The efficiency of perovskite solar cells（PSCs） has increased from around 4% to over 22% following a few years of intensive investigation. For most PSCs, organic materials such as 2,2＇,7,7＇-tetrakis（N,Npdimethoxyphenylamino）-9,9＇-spirobifluorene（spiro-OMeTAD） are used as the hole transporting materials（HTMs）, which are thermally and chemically unstable and also expensive. Here, we explored nickel phthalocyanine（NiPc） as a stable and cost-effective HTM to replace the conventionally used spiroOMeTAD. Because of its high carrier mobility and proper band alignments, we achieved a PCE of 12.1% on NiPc based planar device with short-circuit current density（Jsc） of 17.64 mAcm（-2）, open circuit voltage（Voc） of 0.94 V, and fill factor（FF） of 73%, outperforming the planar device based on copper phthalocyanine（CuPc） that is an outstanding representative of metal phthalocyanines（MPcs） reported. Moreover,the device with NiPc shows much improved stability compared to that based on the conventional spiroOMeTAD as a result of NiPc＇s high stability. Photoluminescence（PL） and Impedance spectroscopy analysis results show that thermally deposited NiPc has good hole-extraction ability. Our results suggest that NiPc is a promising HTM for the large area, low cost and stable PSCs.

关键词： solar cells Perovskite Hole transfer material

High-Performance Perovskite solar cells with Zwitterion-Capped-ZnO Quantum Dots as Electron Transport Layer and NH_(4)X(X=F,Cl,Br)Assisted Interfacial Engineering

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Energy & Environmental Materials 2024年第5期7卷 321-331页

作者： Rashmi Runjhun Essa A.Alharbi Zygmunt Druzyński Anurag Krishna Ma■gorzata Wolska-Pietkiewicz ViktorŠkorjanc Thomas P.Baumeler George Kakavelakis Felix Eickemeyer Mounir Mensi Shaik M.Zakeeruddin Michael Graetzel Janusz Lewiński Institute of Physical Chemistry Polish Academy of Sciences Kasprzaka 44/5201-224 WarsawPoland Laboratory of Photonics and Interfaces Institute of Chemical Sciences and EngineeringSchool of Basic SciencesEcole Polytechnique Fédérale de LausanneCH-1015 LausanneSwitzerland Microelectronics and Semiconductors Institute King Abdulaziz City for Science and Technology(KACST)11442 RiyadhSaudi Arabia Faculty of Chemistry Warsaw University of TechnologyNoakowskiego 300-664 WarsawPoland Institute of Chemical Sciences and Engineering École Polytechnique Fédérale de LausanneValais WallisCH-1951 SionSwitzerland

The systematic advances in the power conversion efficiency(PCE)and stability of perovskite solar cells(PSCs)have been driven by the developments of perovskite materials,electron transport layer(ETL)materials,and interfacial passivation between the relevant *** zinc oxide(ZnO)is a promising ETL in thin film photovoltaics,it is still highly desirable to develop novel synthetic methods that allow both fine-tuning the versatility of ZnO nanomaterials and improving the ZnO/perovskite *** various inorganic and organic additives,zwitterions have been effectively utilized to passivate the perovskite *** this vein,we develop novel,well-characterized betaine-coated ZnO QDs and use them as an ETL in the planar n-i-p PSC architecture,combining the ZnO QDs-based ETL with the ZnO/perovskite interface passivation by a series of ammonium halides(NH_(4)X,where X=F,Cl,Br).The champion device with the NH4F passivation achieves one of the highest performances reported for ZnO-based PSCs,exhibiting a maximum PCE of~22%with a high fill factor of 80.3%and competitive stability,retaining~78%of its initial PCE under 1 Sun illumination with maximum power tracking for 250 h.

关键词： interface passivations perovskites quantum dots solar cells zinc oxide zwitterions