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Stoichiometry of base cations and silicon during weathering of a deep soil profile derived from granite

Pedosphere 2023年第5期33卷 800-807页

作者： Yue ZHAO Jinling YANG Nan JIA Yufang SUN Zhe XU Ganlin ZHANG State Key Laboratory of soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China University of Chinese Academy of Sciences Beijing 100081China State Key Laboratory of Lake Science and Environment Nanjing Institute of Geography and LimnologyChinese Academy of SciencesNanjing 210008China soil&Environment Analysis Center Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China

Evaluation of the stoichiometry of base cations(BCs,including K^(+),Na^(+),Ca^(2+),and Mg^(2+))and silicon(Si)(BCs:Si)during soil mineral weathering is essential to accurately quantify soil acidification *** aim of this study was to explore the differences and influencing factors of BCs:Si values of different soil genetic horizons in a deep soil profile derived from granite with different extents of mineral *** type was typic acidi-udic *** samples were collected from Guangzhou,China,which is located in a subtropical *** ensure that the BCs and Si originated from the mineral weathering process,soil exchangeable BCs were washed with an elution *** BCs:Si values during weathering were obtained through a simulated acid rain leaching experiment using the batch *** showed that soil physical,chemical,and mineralogical properties varied from the surface horizon to saprolite in the soil *** BCs:Si values of soil genetic horizons during weathering were 0.3–*** BCs:Si value was 1.7 in the surface horizon(A),1.1–3.7 in the argillic horizon(Bt),and 0.3–0.4 in the cambic(Bw)and transition(BC)horizons,as well as in horizon C(saprolite).The general pattern of BCs:Si values in the different horizons was as follows:Bt>A>Bw,BC,and *** BCs:Si values were influenced by weathering intensity,they did not correlate with the chemical index of alteration(CIA).The release amounts of Si and BCs are the joined impact of soil mineral composition and physical and chemical properties.A comprehensive analysis showed that the BCs:Si values of the soil derived from granite in this study were a combined result of the following factors:soil clay,feldspar,kaolinite,organic matter,pH,and *** main controlling factors of BCs:Si in soils of different parent material types require extensive *** wide variance of BCs:Si values in the deep soil profile indicated that H+consumed by soil mineral weathering was very dissimilar i

关键词： mineral weathering soil acidification rate soil evolution soil genesis soil geochemistry weathered sequence

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