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Immobilization of antimony in soil and groundwater using ferro-magnesium bimetallic organic frameworks

Journal of Environmental Sciences 2023年第3期125卷 194-204页

作者： Le Yuan JianleWang Zuqi Zhong Jiguang Li Hong Deng School of Environment and Energy Guangdong Provincial Key Laboratory of Solid Wastes Pollution Control and Resource RecyclingSouth China University of TechnologyGuangzhou 510006China Guangxi Key Laboratory of Beibu Gulf Marine Biodiversity Conservation Beibu Gulf UniversityQinzhou 535000China Guangdong Engineering and Technology Research Center for Environmental Nanomaterials South China University of TechnologyGuangzhou 510006China

Sb(Ⅲ) is often detected in contaminated soil and groundwater. Hence, high-efficiency technology is needed. In this study, bimetallic organic frameworks were used for the first time to immobilize Sb(Ⅲ) from contaminated soil and groundwater. The materials were synthesized by the hydrothermal method. Both ends of the prepared material were hexagonal tip rods,and the length became shorter as the ratio of Fe/Mg decreased. The bimetallic organic framework with a Fe/Mg feeding ratio of 0.5 was the optimum material for Sb(Ⅲ) removal, which could effectively immobilize Sb(Ⅲ). The adsorption isotherm was fitted well with the Freundlich model, and the optimal adsorption capacity can reach 106.97 mg/g. The adsorption capacity of 84% can be completed in 10 min, which conformed to the pseudo-second-order kinetics. The Fe^(3+)could enhance the stability of the material, and the Mg^(2+)was conducive to freeing up adsorption sites for binding Sb(Ⅲ) and forming stable chemical adsorption. Ion exchange is the predominant mechanism to remove Sb(Ⅲ). After 14 days of remediation of Sb(Ⅲ) contaminated soil, the Toxicity Characteristic Leaching Procedure(TCLP)-leached concentrations of Sb(Ⅲ) were reduced by 86%, 91% and 94% when the material dosages were1%, 2% and 3%, respectively. Immobilization of Sb(Ⅲ) in soil resulted in a conversion of antimony speciation from more easily bioavailable species to less bioavailable species, further contributing to reduce the environmental risk of antimony. The results indicate that ferromagnesium bimetallic organic frameworks may serve as a kind of promising materials for the immobilization of Sb(Ⅲ) in contaminated soil and groundwater.

关键词： Antimony Ferro-magnesium bimetallic organic frameworks(MOFs) soil Groundwater

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Pronounced temporal changes in soil microbial community and nitrogen transformation caused by benzalkonium chloride

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Journal of Environmental Sciences 2023年第4期126卷 827-835页

作者： Rui Yang Shaohong Zhou Lilan Zhang Cunli Qin State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongqing 400044China Key Laboratory of Three Gorges Reservoir Region’s Eco-Environment Ministry of EducationChongqing UniversityChongqing 400045China

As one typical cationic disinfectant, quaternary ammonium compounds(QACs) were approved for surface disinfection in the coronavirus disease 2019 pandemic and then unintentionally or intentionally released into the surrounding environment. Concerningly, it is still unclear how the soil microbial community succession happens and the nitrogen(N)cycling processes alter when exposed to QACs. In this study, one common QAC(benzalkonium chloride(BAC) was selected as the target contaminant, and its effects on the temporal changes in soil microbial community structure and nitrogen transformation processes were determined by q PCR and 16S r RNA sequencing-based methods. The results showed that the aerobic microbial degradation of BAC in the two different soils followed first-order kinetics with a half-life(4.92 vs. 17.33 days) highly dependent on the properties of the soil. BAC activated the abundance of N fixation gene(nif H) and nitrification genes(AOA and AOB) in the soil and inhibited that of denitrification gene(nar G). BAC exposure resulted in the decrease of the alpha diversity of soil microbial community and the enrichment of Crenarchaeota and Proteobacteria. This study demonstrates that BAC degradation is accompanied by changes in soil microbial community structure and N transformation capacity.

关键词： Benzalkonium chloride soil Degradation kinetics Microbial community structure Nitrogen cycling

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Nationwide distribution of polycyclic aromatic hydrocarbons in soil of China and the association with bacterial community

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Journal of Environmental Sciences 2023年第6期128卷 1-11页

作者： Qiuyue Zhang Meng Gao Xinhui Sun Yu Wang Chaolei Yuan Hongwen Sun MOE Key Laboratory of Pollution Processes and Environmental Criteria College of Environmental Science and EngineeringNankai UniversityTianjin 300350China School of Agriculture Sun Yat-sen UniversityShenzhen 518107China

soil contamination by polycyclic aromatic hydrocarbons(PAHs)has raised great environmental concerns.However,the information on national wide distribution of PAHs in soil as well as their effect on soil bacterial community are limited.In this study,16 PAHs weremeasured in 94 soil samples collected across China.The total concentration of 16 PAHs(PAHs)in soil ranged from 74.0 to 17,657 ng/g(dry weight basis),with a median value of 200 ng/g.Pyrene was themajor soil PAH,with amedian concentration of 71.3 ng/g.soil samples from Northeast China had a higher median concentration ofPAHs(1,961 ng/g)than those from other regions.Petroleum emission and wood/grass/coal combustion were potential sources for soil PAHs based on diagnostic ratios and positive matrix factors analysis.A nonnegligible ecological risk(hazard quotients>1)was found in over 20%of soil samples analyzed and the highestmedian total HQs value(8.53)was found in soils from Northeast China.The effect of PAHs on bacterial abundance,α-diversity,andβ-diversity was limited in the soils surveyed.Nevertheless,the relative abundance of some members in genera Gaiella,Nocardioides,and Clostridium was significantly correlated with the concentrations of some PAHs.Especially,the bacterium Gaiella Occulta showed potential in indicating soil contamination by PAH,which is worth further exploration.

关键词： PAHs soil Source analysis Bacterial community

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Core-shell design of UiO66-Fe_(3)O_(4) configured with EDTA-assisted washing for rapid adsorption and simple recovery of heavy metal pollutants from soil

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Journal of Environmental Sciences 2024年第5期139卷 556-568页

作者： Xi Wang Asif Hussain Qingqing Li Mingyu Ma Juan Wu Mingqiang Deng Jie Yang Dengxin Li Department of Environmental Science and Engineering Donghua UniversityShanghai 201620China Department of Environmental Science Federal Urdu University of ArtsScience and Technology75300 KarachiPakistan Shanghai Academy of Environmental Sciences Shanghai 200233China

The coupling of washing with adsorption process can be adopted for the treatment of soils contaminated with heavy metals pollution.However,the complex environment of soil and the competitive behavior of leaching chemicals considerably restrain adsorption capacity of adsorbent material during washing process,which demands a higher resistance of the adsorbents to interference.In this study,we synthesized strongly magnetic,high specific surface area(573.49 m^(2)/g)UiO66 composites(i.e.,UiO66-Fe_(3)O_(4))using hydrothermal process.The UiO66-Fe_(3)O_(4) was applied as an adsorbent during the ethylene diamine tetraacetic acid(EDTA)-assisted washing process of contaminated soil.The incorporation of UiO66-Fe_(3)O_(4)results in rapid heavy metal removal and recovery from the soil under low concentrations of washing agent(0.001 mol/L)with reduced residual heavy metal mobility of soil after remediation.Furthermore,UiO66-Fe_(3)O_(4)can quickly recollect by an external magnet,which offers a simple and inexpensive recovery method for heavy metals from contaminated soil.Overall,UiO66-Fe_(3)O_(4)configuration with EDTA-assisted washing process showed opportunities for heavy metals contaminated sites.

关键词： UiO66 composites Metal-EDTA complexes EDTA-assisted washing Heavy metals recovery soil

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The co-transport of Cd(Ⅱ) and nZnO in saturated soil packed column:effects of ionic strength and pH

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Acta Geochimica 2024年第1期43卷 97-109页

作者： Min Liao Guo Bin Yixin Luo Yuhao Zhang Kangyou Hu Xiongxiong Lu Xiaomei Xie College of Environmental and Resource Science Zhejiang UniversityYuhangtang Road No.866Hangzhou 310058China Zhejiang Provincial Key Laboratory of Subtropical soil and Plant Nutrition Yuhangtang Road No.866Hangzhou 310058China National Demonstration Center for Experimental Environmental and Resources Education(Zhejiang University) Yuhangtang Road No.866Hangzhou 310058China

The rapid development and widespread use of ZnO nanoparticles(nZnO) in various industries have raised concerns about their potential environmental impact.Therefore,understanding the fate and role of nZnO in the natural environment is crucial for mitigating their hazardous effects on the environment and human safety.The purpose of the present study was to provide scientific support for understanding and eliminating the joint risk of nanoparticle and heavy metal pollution in the soil environment by revealing the co-transport characteristics of Cd(Ⅱ) and ZnO nanoparticles(nZnO) in soil under different ionic strength(IS) and pH.The impacts of different IS and pH on the co-transport of Cd(Ⅱ) and nZnO in a20 cm long with an inner diameter of 2.5 cm acrylic column packed with 10 cm high soil samples were investigated in the present study.In the above system,a500 μg L^(-1) Cd(Ⅱ) loaded nZnO suspension pulse with varying IS or pH was introduced into the soil column for leaching over 5 PVs,followed up by 5 PVs background solutions without nZnO.The IS was 1,10,or 50 mM NaCl,with pH6,or the pH was 6,7 or 8 with 1 mM NaCl.Meanwhile,Sedimentation experiments for nZnO,adsorption of Cd(Ⅱ) on soil,and nZnO,DLVO theory calculation for the same background condition were conducted.The presence of nZnO significantly increased the mobility of Cd(Ⅱ) as a result of its strong adsorption capacity for nZnO-associated Cd(Ⅱ).However,with the increase of IS,the co-transport of nZnO and Cd(Ⅱ) was decreased and the retention of nZnO in the soil column due to more nZnO attended to aggregate and sediment during the transport and the decrease in the adsorption capacity of nZnO for Cd(Ⅱ) by competition of Na^(+).When pH was 6,7,and 8,the co-transport of nZnO and Cd(Ⅱ) increased with higher pH due to the lower electrostatic attraction between nZnO and soil under higher pH.Meanwhile,the DLVO theory was fitted to describe the above co-transport process of nZnO and Cd(Ⅱ).More attention should be paid to the presence of nZnO on the migration of Cd(Ⅱ) i

关键词： ZnO Nanoparticles Cadimium soil Co-transport

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A Generic Model to Estimate Wheat LAI over Growing Season Regardless of the soil-Type Background

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Plant Phenomics 2023年第2期5卷 333-352页

作者： Qiaomin Chen Bangyou Zheng Karine Chenu Scott C.Chapman School of Agriculture and Food Sciences The University of QueenslandSt LuciaQLDAustralia Agriculture and Food CSIROQueensland Bioscience PrecinctSt LuciaQLDAustralia The University of Queensland Queensland Alliance for Agriculture and Food InnovationToowoombaQLDAustralia

It is valuable to develop a generic model that can accurately estimate the leaf area index(LAI)of wheat from unmanned aerial vehicle-based multispectral data for diverse soil backgrounds without any ground calibration.To achieve this objective,2 strategies were investigated to improve our existing random forest regression(RFR)model,which was trained with simulations from a radiative transfer model(PROSAIL).The 2 strategies consisted of(a)broadening the reflectance domain of soil background to generate training data and(b)finding an appropriate set of indicators(band reflectance and/or vegetation indices)as inputs of the RFR model.The RFR models were tested in diverse soils representing varying soil types in Australia.Simulation analysis indicated that adopting both strategies resulted in a generic model that can provide accurate estimation for wheat LAI and is resistant to changes in soil background.From validation on 2 years of field trials,this model achieved high prediction accuracy for LAI over the entire crop cycle(LAI up to 7 m^(2)m^(−2))(root mean square error(RMSE):0.23 to 0.89 m^(2)m^(−2)),including for sparse canopy(LAI less than 0.3 m^(2)m^(−2))grown on different soil types(RMSE:0.02 to 0.25 m^(2)m^(−2)).The model reliably captured the seasonal pattern of LAI dynamics for different treatments in terms of genotypes,plant densities,and water–nitrogen managements(correlation coefficient:0.82 to 0.98).With appropriate adaptations,this framework can be adjusted to any type of sensors to estimate various traits for various species(including but not limited to LAI of wheat)in associated disciplines,e.g.,crop breeding,precision agriculture,etc.

关键词： soil Wheat breeding

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Natural siderite derivatives activated peroxydisulfate toward oxidation of organic contaminant: A green soil remediation strategy

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Journal of Environmental Sciences 2023年第5期127卷 615-627页

作者： Chengwei Zhong Yinying Jiang Quanfeng Liu Xiaoshuang Sun Jiang Yu Department of Environmental Science and Engineering College of Architecture and EnvironmentSichuan UniversityChengdu 610065China Yibin Institute of Industrial Technology Sichuan UniversityYibin 644000China Institute of New Energy and Low Carbon Technology Sichuan UniversityChengdu 610065China

Natural siderite(FeCO_(3)),simulated synthetic siderite and nZVI/FeCO_(3) composite were used as green and easily available iron-based catalysts in peroxydisulfate activation for remediating 2-chlorophenol as the target contaminant and this technique can effectively degrade organic pollutants in the soil.The key reaction parameters such as catalysts dosage,oxidant concentration and pH,were investigated to evaluate the catalytic performance of different materials in catalytic systems.The buffering property of natural soil conduced satisfactory degradation performance in a wide pH range(3-10).Both the main non-radical of ^(1)O_(2) and free radicals of SO_(4)^(-) and OH·were evidenced by quenching experiment and electron paramagnetic resonance.The reduction of nZVI on FFC surface not only has the advantage for electronic transfer to promote the circulation of Fe(Ⅲ)to Fe(Ⅱ),but also can directly dechlorinate.Furthermore,the intermediates were comprehensively analyzed by GC-MS and a potential removal mechanism of three oxidant system for 2-CP soil degradation was obtained.Briefly,this research provides a new perspective for organic contaminate soil treatment using natural siderite or simulated synthetic siderite as efficient and environmental catalytic material.

关键词： Natural siderite 2-chlorophenol soil Peroxydisulfate Reactive radicals

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Influence analysis of calculated horizontally layered soil parameters on grounding parameters

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High Voltage 2023年第2期8卷 421-430页

作者： Yihua Dan Junjun Yin Jian Yang Huizhang Yang Department of Electronic Engineering Tsinghua UniversityBeijingChina School of Computer&Communication Engineering University of Science and Technology BeijingBeijingChina

Calculated parameters(soil layer resistivity,soil layer thickness,and the number of soil layers)of horizontally layered soil are usually obtained based on the measured apparent resistivity under different measurement distances,which are significant for the design,operation,and maintenance of grounding grids.Most existing calculation methods of soil parameters are just trying to make the calculation results approach the measurement data,ignoring the relationship among measurement data,the calculated soil parameters,and grounding parameters,which would increase the workload of the measurement.To better balance the distance range of the measurement data and the influence of the calculated horizontally layered soil on grounding parameters,this paper systematically studies the relationship among measured apparent soil resistivity,calculated horizontally layered soil parameters,and grounding parameters.The basic theories of apparent resistivity measurement,soil parameter calculation,and grounding parameter calculation are given,the influence of soil layer thickness on the measured apparent resistivity is studied,and the influence of the calculated soil parameters on the grounding resistance of different grounding models is analysed.Based on different scales of grounding grids,the results give a corresponding reference distance range of measured apparent soil resistivity.Therefore,this paper can help decrease the workload of soil resistivity measurement during grounding parameters analysis,which has far-reaching engineering significance.

关键词： soil parameters apparent

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被高估的全球土壤异养呼吸

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Science Bulletin 2022年第3期67卷 223-225页

作者：何悦丁金枝 Sino-French Institute for Earth System Science College of Urban and Environmental SciencesPeking UniversityBeijing 100871China State Key Laboratory of Tibetan Plateau Earth System Resources and Environment(TPESRE)Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China

soil heterotrophic respiration(Rh)is the flux of CO2 that microbes and soil fauna release to the atmosphere by extracting the energy of organic molecules that they break down[1].Rh closes the terrestrial carbon cycle by recycling more than 70%of the annual total fixed carbon to the atmosphere per year so that it can be reused by plants for photosynthesis[2].Rh plays a key role in regulating the changes in atmospheric CO2 concentrations as well as the consequential climate feedbacks[3,4].However,global Rh estimates suffer from large uncertainty.The simulated global Rh value ranges from 30 to 64 Pg C a-1 by MsTMIP models[5],from 47 to 72 Pg C a-1 by Trendy models[6],and from 42 to 73 Pg C a-1 by CMIP5 models[1].High spatial heterogeneity and the close contingency of soil decomposition on environmental changes,such as temperature and soil moisture,may be a response to such great unpredictability[7].Rh is highly transient and variable at diurnal,seasonal and multiyear scales.Short-term observations and limited in situ measurements,as well as low representativeness in many key regions with high soil carbon stocks and difficult accessibilities,such as the northern circumpolar permafrost region and high-altitude Tibetan region,make Rh the most unpredictable process in land-carbon cycle models[8].Accurate estimates of Rh at regional and global scales are thus imperative to quantify the land carbon sink,to evaluate land-carbon cycle models and to define baselines for climate change mitigation efforts.

关键词： soil 土壤异养呼吸 estimates

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智慧6S路线图破译全国棕地土壤和地下水系统中重金属迁移潜势与风险

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Science Bulletin 2022年第13期67卷 1295-1299页

作者：仇浩楼紫阳顾雪元孙媛媛王军张卫曹心德 School of Environmental Science and Engineering Shanghai Jiao Tong University.Shanghai200240.China School of the Environment Nanjing University.Nanjing210023.China School of Earth Sciences and Engineering Nanjing University.Nanjing210023.China College of Resources and Environment Shandong Agricultural University.Taian271000.China School of Resource and Environmental Engineering East China University of Science and Technology.Shanghai200237.China

Rapid industrialization and economic development have left a great amount of industrial facilities,such as chemical,smelting and mining industries,throughout the country over the past few decades.As a result,a wide ra... 详细信息

关键词： groundwater soil nationwide

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