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Multifunctional cellular carbon foams derived from chitosan toward self-cleaning, thermal insulation, and highly efficient microwave absorption properties

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Nano Research 2024年第3期17卷 927-938页

作者： Beibei Zhan Yanling Hao Xiaosi Qi Yunpeng Qu Junfei Ding Jing-liang Yang Xiu Gong Yanli Chen Qiong Peng Wei Zhong College of Physics Guizhou Province Key Laboratory for Photoelectrics Technology and ApplicationGuizhou UniversityGuiyang 550025China Minzu Normal University of Xingyi Xingyi 562400China National Laboratory of Solid State Microstructures and Jiangsu Provincial Laboratory for NanoTechnology Nanjing UniversityNanjing 210093China

To adapt the practical demand,designing and constructing the multifunctional microwave absorbers(MAs)is the key future direction of research and development.However,effective integrating the multiple functions into a single material remains a huge challenge.Herein,cellular carbon foams(CCFs)with different porous structures were elaborately designed and fabricated in high efficiency through a facile continuous freeze-drying and carbonization processes using a sustainable biomass chitosan as the precursor.The obtained results revealed that the thermal treated temperature and g-C_(3)N_(4) amount played a great impact on the carbonization degrees,pore sizes,and morphologies of CCFs,which led to their tunable electromagnetic(EM)parameters,improved conduction loss,and polarization loss abilities.Owing to the special cellular structure,the designed CCFs samples simultaneously displayed the strong absorption capabilities,broad absorption bandwidths,and thin matching thicknesses.Meanwhile,the as-prepared CCFs exhibited the strong hydrophobicity and good thermal insulation,endowing its attractive functions of self-cleaning and thermal insulation.Therefore,our findings not only presented a facile approach to produce different porous structures of CCFs,but also provided an effective strategy to develop multifunctional high-performance MAs on basis of three-dimensional CCFs.

关键词： multifunctional microwave absorbers carbon foams cellular structure self-cleaning thermal insulation

Superhydrophobic Fe-based amorphous coating fabricated by detonation spraying with excellent anti-corrosion and self-cleaning properties

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Rare Metals 2023年第2期42卷 629-644页

作者： Shuai Cui Hai-Min Zhai Wen-Sheng Li Wei Tong Xiao-Song Li An-Hui Cai Xiang-Juan Fan Xu-Qiang Li Dang-Sheng Xiong School of Materials Science and Engineering Nanjing University of Science and TechnologyNanjing210094China State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou University of TechnologyLanzhou730050China Hunan Provincial Key Laboratory of Electromagnetic Equipment Design and Manufacturing Hunan Institute of Science and TechnologyYueyang414000China

Amorphous alloys without crystalline defects(dislocation,crystal boundary)are ideal hydrophobic coating materials due to their low surface energy.This work used a synergistic method of detonation spraying and surface modification to obtain the superhydrophobic Febased amorphous coatings with high hardness and dense structure on the Q 235 substrate.The results showed that the water contact angles(WCA)of the superhydrophobic coating was 160°±3.6°,and water droplets could bounce off the superhydrophobic coating surface,illustrating the excellent self-cleaning performance of coating.Notably,the corrosion current density(i_(corr))of the superhydrophobic coating further decreased by 2 orders of magnitude down to8.008×10^(-8)A·cm^(-2)compared to the as-deposited coating with 5.473×10^(-6)A·cm^(-2);the corrosion potential(E_(corr))of the superhydrophobic coating shifted by 34 mV to the positive side compared with that of the as-deposited coating(-310 mV).Likewise,the impedance modulus|Z|values of the superhydrophobic coating increased by nearly2 orders of magnitude up to 1×10^(5.6)compared to the asdeposited coating with 1×10^(3.8).Even through lasting immersion in NaCl for 10 days,|Z|values of the superhydrophobic coating were still much higher than those of the as-deposited coating.The superhydrophobic Fe-based amorphous coatings could respond to their applications under extreme conditions due to their excellent hydrophobicity and self-cleaning properties,illustrating their promising future in aerospace,automotive,and machinery industries.

关键词： Fe-based amorphous coating Detonation spraying Superhydrophobic Corrosion resistance self-cleaning

self-cleaning of superhydrophobic nanostructured surfaces at low humidity enhanced by vertical electric field

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Nano Research 2022年第5期15卷 4732-4738页

作者： Yijie Liu Yujun Guo Xueqin Zhang Guoqiang Gao Chaoqun Shi Guizao Huang Pengli Li Qi Kang Xingyi Huang Guangning Wu College of Electrical Engineering Southwest Jiaotong UniversityChengdu 611756China Department of Polymer Science and Engineering Shanghai Key Laboratory of Electrical Insulation and Thermal AgeingState Key laboratory of Metal Matrix CompositesShanghai Jiaotong UniversityShanghai 200240China

self-cleaning is the key factor that makes superhydrophobic nanostructured materials have wide applications.The self-cleaning effect,however,strongly depends on formations and movement of water droplets on superhydrophobic nanostructured surfaces,which is greatly restricted at low humidity(self-cleaning method at low humidity in which the pollution is electro-aggregated and driven in the electric field to achieve the aggregation and cleaning large areas.The cleaning efficiency of this method is much higher than that of water droplet roll-off,and will not produce"pollution bands".A simplified numerical model describing pollution movements is presented.Simulation results are consistent with experimental results.The proposed method realizes the self-cleaning of superhydrophobic nanostructured surfaces above dew point curve for the first time,which extends applications of superhydrophobic nanostructured materials in low humidity,and is expected to solve self-cleaning problems of outdoor objects in low humidity areas(<5.0 g·kg^(-1)).

关键词： self-cleaning electric field low humidity electro-aggregation superhydrophobic nanostructured surface

Flexible, self-cleaning, and high-performance ceramic nanofiber-based moist-electric generator enabled by interfacial engineering

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Science China(Technological Sciences) 2022年第2期65卷 450-457页

作者： WANG LiMing FENG LanLan SUN Zhao Yang HE XinYang WANG RongWu QIN XiaoHong YU JianYong Key Laboratory of Textile Science&Technology Ministry of EducationCollege of TextilesDonghua UniversityShanghai 201620China Innovation Center for Textile Science and Technology Donghua UniversityShanghai 201620China

Due to their long-term stability, even under extreme conditions, oxide ceramics have attracted significant attention in emerging fields like moist-electric generation. However, the inherent brittleness and low voltage output of oxide ceramic-based moistelectric generators(MEGs) limit their applications in wearable electronics. Herein, a facile strategy involving the combination of sol-gel electrospinning and calcination is used to fabricate flexible and freestanding Ti O_(2)/Zr O_(2)(TZ) composite nanofiber-based MEGs. The excellent flexibility of the TZ nanofiber membranes can be attributed to the suppression of their crystal structure transformation, dispersion of stress concentration, and reduction of crack propagation via interfacial engineering. The porous structure of the electrospun nanofiber membrane features an abundance of charged narrow channels for the diffusion of water molecules and generates a streaming potential. The optimal voltage output reached ~0.8 V, which is the highest value reported for an oxide ceramic-based MEG. Furthermore, the as-fabricated nanofiber-based MEG exhibits good self-cleaning capability to degrade organic pollutants under ultraviolet irradiation. By integrating mechanical flexibility, high performance, and a selfcleaning effect, this work presents a new idea for exploring diverse, efficient, and wearable oxide ceramic-based MEGs.

关键词： moist-electric generation ceramic nanofiber electrospinning flexible self-cleaning

Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic self-cleaning and antifouling functionalities

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Frontiers of Chemical Science and Engineering 2023年第10期17卷 1450-1459页

作者： Nee Nee Tan Qi Hwa Ng Siti Kartini Enche Ab Rahim Abdul Latif Ahmad Peng Yong Hoo Thiam Leng Chew Faculty of Chemical Engineering&Technology Universiti Malaysia Perlis(UniMAP)Perlis 02600Malaysia Centre of Excellent for Frontier Materials Research Universiti Malaysia Perlis(UniMAP)Perlis 02600Malaysia School of Chemical Engineering Engineering CampusUniversiti Sains MalaysiaPenang 14300Malaysia Department of Chemical Engineering Faculty of EngineeringUniversiti Teknologi PETRONASPerak 32610Malaysia CO_(2) Research Centre(CO2RES) Institute of Contaminant ManagementUniversiti Teknologi PETRONASPerak 32610Malaysia

Membrane technology is ideal for removing aqueous humic acid,but humic acid deposits cause membrane fouling,a significant challenge that limits its application.Herein,this work proposed an alternative approach to the controllably magnetically induced magnetohybrid polyoxometalate(magneto-HPOM)nanocomposite migration toward the polyethersulfone(PES)membrane surface under a magnetic field to enhance the self-cleaning and antifouling functionalities of the membrane.Before incorporating magneto-HPOM nanocomposite into the PES casting solution,functionalized magnetite nanoparticles(F-MNP)were first coated with HPOM photocatalyst to fabricate a magneto-HPOM-PES membrane.It was shown that the apparent impacts of this novel magneto-HPOM-PES membrane on the hydrophilic behavior and photocatalytic properties of the magneto-HPOM nanocomposite improve the hydrophilicity,separation performance,antifouling and self-cleaning properties of the membrane compared with neat PES membrane.Furthermore,after exposure to ultraviolet light,the magneto-HPOM-PES membrane can be recovered after three cycles with a flux recovery ratio of 107.95%,100.06%,and 95.56%,which is attributed to the temporal super hydrophilicity effect.Meanwhile,the magneto-HPOM-PES membrane could efficiently maintain 100%humic acid rejection for the first and second cycles and 99.81%for the third cycle.This study revealed a novel approach to fabricating membranes with high antifouling and self-cleaning properties for water treatment.

关键词： magneto-hybrid polyoxometalate nanocomposite composite membrane antifouling self-cleaning magnetic and photocatalytic responsiveness

A TiO_(2)nanotubes film with excellent antireflective and near-perfect self-cleaning performances

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Journal of Materials Science & Technology 2021年第29期88卷 11-20页

作者： Kaibin Li Ming Li Chang Xu Zengyan Du Jiawang Chen Fengxia Zou Chongwen Zou Sichao Xu Guanghai Li Key Laboratory of Materials Physics Anhui Key Laboratory of Nanomaterials and NanotechnologyInstitute of Solid State PhysicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei230031China University of Science and Technology of China Hefei230026China National Synchrotron Radiation Laboratory University of Science and Technology of ChinaHefei230026China

SiO_(2)/TiO_(2)composite films have been frequently used to realize the functions of self-cleaning and antireflection.Increasing the TiO_(2)volume ratio in SiO_(2)/TiO_(2)composite film is beneficial to enhance the self-cleaning effect,while high TiO_(2)content leads to a strong Rayleigh scattering and depresses the antireflective performance,resulting in a bottleneck problem for the dual-functional application.Here,we have achieved a high-quality TiO_(2)nanotubes film with excellent antireflective and near-perfect selfcleaning performances.Ultrasound assisted pickling method has been developed to effectively prepare the well-dispersed protonated titanate nanotubes colloid.After spin-coating and annealing treatment,glass substrate coated with double-side TiO_(2)nanotubes film has a peak transmittance of 99.2%and average transmittance of 97.4%at 400-800 nm.Ultra-high porosity of TiO_(2)nanotubes film(80%)and ultra-fine size of TiO_(2)nanotubes(8.6 nm in outer diameter)lead to excellent antireflective performance.With high UV absorptivity(80%at 254 nm)and formal quantum efficiency of stearic acid(10.9×10^(-3)),TiO_(2)nanotubes film shows near-perfect self-cleaning performance.A persistent anti-fogging ability is also presented.This study demonstrates the feasibility to fabricate pure TiO_(2)antireflective coating for glass substrate,extends application field of the classic TiO_(2)nanotubes,and sheds lights on the practical applications of high-powered TiO_(2)nanotube-based multi-functional films.

关键词： TiO_(2)nanotubes Antireflective self-cleaning Anti-fogging Multi-functional films

A visibly transparent radiative cooling film with self-cleaning function produced by solution processing

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Journal of Materials Science & Technology 2021年第31期90卷 76-84页

作者： Guoliang Chen Yaming Wang Jun Qiu Jianyun Cao Yongchun Zou Shuqi Wang Jiahu Ouyang Dechang Jia Yu Zhou Institute for Advanced Ceramics Harbin Institute of TechnologyHarbin 150080China Key Laboratory of Advanced Structure-Function Integrated Materials and Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China School of Energy Science and Engineering Harbin Institute of TechnologyHarbin 150001China Key Laboratory of Aerospace Thermophysics Ministry of Industry and Information TechnologyHarbin Institute of TechnologyHarbin 150001China Department of Materials and National Graphene Institute University of ManchesterManchesterM139PLU.K.

Daylighting structures,including solar cells and building windows,utilize sunlight whilst suffering from undesired solar heat and outdoor dust contamination.A radiative cooling system that is transparent to sunlight and has a superhydrophobic surface would cool and clean the daylighting structures in a sustainable manner.However,the majority of the current daytime radiative cooling systems were designed to fully reflect the incident sunlight to maximize the cooling power.In this work,we optimized both the sunlight transmission and infrared thermal irradiation by modeling the size-dependent scattering and absorption of light by SiO_(2)spheres embedded in a polymer matrix,we found that the use of nanospheres(20 nm)enabled both high sunlight transmittance(>90%)and infrared emissivity(-0.85).This theoretical prediction was confirmed by experimental measurements of a solution-processed nanocomposite film.When coated on a solar cell,the as-prepared film not only preserved the power conversion efficiency of the cell(14.71%,uncoated cell has an efficiency of 14.79%)but also radiatively cooled the cell by up to 5℃under direct sunlight.This reduction of the operating temperature of the solar cell further enhanced its electrical power output,evidenced by an increase in the equilibrium temperature of the LED load by about 14℃.The nanoscale textured surface formed by the nanospheres further led to superhydrophobicity and thus excellent self-cleaning performance(efficient removal of dust by wind and/or water droplets).

关键词： Nanocomposite film Radiative cooling Visibly transparent self-cleaning

self-cleaning and Oil/Water Separation of 3D Network Super-hydrophobic Bead-like Fluorinated Silica Pellets/Poly(aryl ether ketone)Composite Membrane Fabricated via a Facile One-step Electrospinning

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Chemical Research in Chinese Universities 2020年第6期36卷 1320-1325页

作者： CUI Zengduo WANG Yongpeng LIU Mengzhu ZHANG Haibo JIANG Zhenhua National&Local Joint Engineering Laboratory for Synthesis Technology of High Performance Polymer College of ChemistryJilin UniversityChangchun 130012P.R.China College of Materials Science and Engineering Jilin Institute of Chemical TechnologyJilin 132022P.R.China

Novel super-hydrophobic fluorinated silica pellets/poly(aryl ether ketone)composite membranes with controllable structure have been prepared through incorporating poly(aryl ether ketonc)s with(3-triluoromethyl)-phenyl side groups and fluorinated silica pellets(F-SiO2)by a facile one-step electrospinning.Under the condition of adding 50%(mass fraction)F-SiO2 in the composite membrane,the water contact angle(WCA)reached its maximum(157°±4.3°).The controllable micro/nano-structures grown on the electrospun fibers could be regulated by the F-SiO2 loading,which was illustrated by scanning clectron microscopy(SEM).Moreover,these super-hydrophobic mem-branes also demonstrated excellent durability,anti-fouling property and oil-water separation ability after 200 h of water flushing.These promising PAEK composite membranes with controllable structure have the potential values in large-scale application of filtration,oil-water separation and antifouling.

关键词： Poly(aryl ecther ketonc) Electrospinning Super-hydrophobic membrane self-cleaning

Superhydrophobic Micro/Nanostructured Copper Mesh with self-cleaning Property for E ective Oil/Water Separation

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Chinese Journal of Chemical Physics 2019年第5期32卷 635-642页

作者： Tai-heng Zhang Tao Yan Guo-qing Zhao Wenjihao Hu Fei-peng Jiao Department of Chemistry and Chemical Engineering Central South University Changsha 410083 China Department of Chemical and Material Engineering University of Alberta Edmonton T5K1B9 Canada

In this work, a simple method was carried out to successfully fabricate superoleophilic and superhydrophobic N-dodecyltrimethoxysilane@tungsten trioxide coated copper mesh. The as-fabricated copper mesh displayed prominent superoleophilicity and superhydrophobicity with a huge water contact angle about 154.39° and oil contact angle near 0° Moreover, the coated copper mesh showed high separation efficiency approximately 99.3%, and huge water flux about 9962.3 L·h^-1·m-2, which could be used to separate various organic solvents/ water mixtures. Furthermore, the coated copper mesh showed favorable stability that the separation efficiency remained above 90% after 10 separation cycles. Benefiting from the excellent photocatalytic degradation ability of tungsten trioxide, the coated copper mesh possessed the self-cleaning capacity. Therefore, the mesh contaminated with lubricating oil could regain superhydrophobic property, and this property of self-cleaning permitted that the fabricated copper mesh could be repeatedly used for oil and water separation.

关键词： Superhydrophobicity Micro/nanostructure Tungsten trioxide self-cleaning Oil/water separation