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rice husk Bio-Chars as Adsorbent for Methylene Blue and Ethinylestradiol from Water

Journal of Renewable Materials 2020年第3期8卷 275-287页

作者： Jonathan Lacuesta Iris Beatriz Vega Erramuspe Liji Sobhana Dennis Kronlund Jouko Peltonen Soledad Gutiérrez Pedro Fardim Department of Chemical Engineering University of the RepublicJulio Herrera y Reissig 565Montevideo11300Uruguay Laboratory of Fibre and Cellulose Technology Åbo Akademi UniversityPorthansgatan 3Turku/ÅboFI-20500Finland Laboratory of Physical Chemistry and Center of Excellence for Functional Materials Åbo Akademi UniversityPorthansgatan 3Turku/ÅboFI-20500Finland Department of Chemical Engineering KU LeuvenCelestijnenlaan 200FLeuvenB-3001Belgium

Biobased adsorbents are eco-friendly materials used for water and wastewater treatment and air *** research work explores the potential use of rice husk chars as a low-cost adsorbent for pollutants from water,such as methylene blue and *** husk chars are prepared by combustion of rice husks(RH-Char)or pre-treated rice husks(PT-Char).A third char(M-Char)supplied by a local company which uses rice husks as combustion material is also *** chars are characterized by field emission scanning electron microscopy(FE-SEM)in conjunction with energy dispersive X-ray spectroscopy(EDX),X-ray powder diffraction(XRD),and zeta-potential *** three bio-chars are tested as adsorbent for the removal of two wastewater contaminants:methylene blue(MB)and ethinylestradiol(EE2).According to the results,RH-Char and PT-Char present zeta-potential values near−52 mV,whereas M-Char shows a zeta-potential value of−32 *** RH-Char and PTChar are rich in amorphous SiO_(2) and M-Char has crystalline SiO_(2)(cristobalite).The bio-chars remove MB and EE2 efficiently showing the following results for the adsorption capacity of MB(inμmol g^(−1)):769.2(RH-Char),41.2(PT-Char),and 31.7(M-Char).The adsorption capacity values for EE2(inμmol g^(−1))are:33.1(RH-Char),19.1(PT-Char),and 16.9(M-Char).The information gathered in the present work evidences the potential of rice husks bio-chars for bio-remediation and may in future contribute to the conversion of a side-stream from the rice industry into value-added materials.

关键词： rice husk bio-char thermal treatment adsorption methylene blue ethinylestradiol

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Fabrication of PMMA nanocomposite biomaterials reinforced by cellulose nanocrystals extracted from rice husk for dental applications

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Friction 2024年第12期12卷 2808-2825页

作者： Ahmed FOULY Walid M.DAOUSH Hesham I.ELQADY Hany S.ABDO Mechanical Engineering Department College of EngineeringKing Saud UniversityRiyadh 11421Saudi Arabia The King Salman Center for Disability Research Riyadh 11421Saudi Arabia Department of Production Engineering and Mechanical Design Faculty of EngineeringMinia UniversityMinia 61519Egypt Department of Chemistry College of ScienceImam Mohammad Ibn Saud Islamic University(IMSIU)Riyadh 11623Saudi Arabia Faculty of Technology and Education Helwan UniversityCairo 11281Egypt Faculty of Engineering Aswan UniversityAswan 81528Egypt Center of Excellence for Research in Engineering Materials(CEREM) King Saud UniversityRiyadh 11421Saudi Arabia Mechanical Design and Materials Department Faculty of Energy EngineeringAswan UniversityAswan 81521Egypt

The primary objective of global studies is to develop the properties and durability of polymers for various *** it comes to dental disability,denture base materials must have sufficient mechanical and tribological performance in order to withstand the forces experienced in the *** work aims to investigate the effects of the addition of low content of cellulose nanocrystals(CNC)on the mechanical and tribological performance of the polymethyl methacrylate(PMMA)*** weight percent of CNC(0,0.2,0.4,0.6,and 0.8 wt%)were added to the PMMA matrix followed by ball milling to evenly distribute the nanoparticles reinforced phase in the matrix *** findings emphasize the significant impact of CNC integration on the performance of PMMA *** increasing the content of the CNC nanoparticles,the mechanical properties of PMMA were *** addition,the tribological outcomes demonstrated a significant reduction in the friction coefficient besides an enhancement in the wear resistance as the weight percentage of nanoparticles *** surface of the worn samples was investigated by utilizing SEM to identify the wear mechanisms corresponding to the different *** addition,a finite elment model(FEM)was developed to ascertain the thickness of the worn layer and the generated stressed on the surfaces of the nanocomposite throughout the friction process.

关键词： polymethyl methacrylate nanocomposite cellulose nanocrystals denture materials rice husk polymethyl methacrylate(PMMA) wear resistance

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Mechanical properties of a clay soil reinforced with rice husk under drained and undrained conditions

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Journal of Rock Mechanics and Geotechnical Engineering 2023年第10期15卷 2676-2686页

作者： Claudia Regina Bernardi Baldin Maiky Yamato Kawanami Weiner Gustavo Silva Costa Vitor Reinaldo Bordignon Cristhyano Cavali da Luz Ronaldo Luis dos Santos Izzo Federal University of Technology-Paraná CuritibaBrazil

Fiber-reinforced soils have been increasingly used in geotechnical *** the years,research has sought to understand and investigate the influences of fibers as reinforcement in soilefiber *** study assessed the behavior of clayey soil in the city of Curitiba(Paraná,Brazil),adding rice husk fiber(RHF),an industrial waste from Cooperativa Agroindustrial in Alegrete(Rio Grande do Sul,Brazil).To evaluate the effect of the presence of natural RHF on the mechanical behavior of compacted soil,aspects such as the influence of fiber content and the drained and undrained behaviors of the soil were evaluated through unconfined triaxial compression *** following tests were realized:soil granulometry,specific mass of solids and Atterberg *** were produced in quadruplicate for the soil and mixtures using the RHF contents of 0.5%,0.75%,1%and 1.5%to determine the unconfined compressive strength(UCS).Triaxial tests were realized on a pure soil specimen and the specimens with 1%RHF under confining pressures of 50 kPa,100 kPa,200 kPa and 400 *** interactions at the interface between husk surface and soil were analyzed using scanning electron microscopy(SEM).In UCS tests,specimens with RHF percentages of 1%and 1.5%presented the highest results,with an increment of 36%compared to the soil without *** results of the consolidated drained triaxial compression tests show that in terms of effective stress,there was a small difference in the strength of the compacted pure soil and soil with the addition of *** the undrained tests,the strength increased with the inclusion of husk,with a reduction of 50%in cohesion and an increment of 22%in friction angle for specimens containing RHF compared to the soil without RHF additions.

关键词： Clay soil rice husk Soil reinforcemen

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Biorefinery of rice husk to Obtain Functionalized Bioactive Compounds

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Journal of Renewable Materials 2019年第4期7卷 313-324页

作者： M.Lopretti N.Lecot A.Rodriguez G.Lluberas F.Orozco L.Bolaños G.Montes De Oca H.Cerecetto J.Vega-Baudrit Laboratorio de Técnicas Nucleares Aplicadas a Bioquímica y Biotecnología Centro de Investigaciones Nucleares-Facultad de CienciasMataojo 2055Montevideo CP 11400Uruguay Área de Radiofarmacia Centro de Investigaciones Nucleares-Facultad de CienciasMataojo 2055Montevideo CP 11400Uruguay Química Bioanalítica Instituto Polo Tecnológico de Pando-Facultad de QuímicaUdelaRBy Pass de Pando y Ruta 8Pando-Canelones CP 91000Uruguay Laboratorio de Nacional de Nanotecnología-CeNAT-CONARE Costa Rica 1174-1200San JoséCP 10109Costa Rica Laboratorio de Polímeros POLIUNA-Escuela de Química Universidad NacionalHerediaSan JoséCP 86-3000Costa Rica

The biomass industrialization valorisation of grains and cereals is considered an opportunity for the countries where agro-industrial activity is one of its main economic activities,rendering new higher-value products with a concomitant solution to waste accumulation *** that end,in this work we describe and characterise bioactive compounds generation from rice husk by semisolid fermentation,obtained from 500 g of the material at room temperature and 60%humidity with mixed cultures of Phanerochaete chrysosporium and Gloeophyllum *** extract was evaluated in different situations:murine mammary tumour cells(4T1),normal cells(NIH 3T3)and in Lactobacillus acidophilus,and Trichoderma *** results exhibited that the extract inhibited 4T1 cells at concentrations higher than 20μg/mL,but did not inhibit normal cells,and displayed germicide activity after 3 days *** propose that these functionalized compounds have a potential application in industry/agriculture/medicine obtained from rice husk waste.

关键词： Biorefinery rice husk bioactive compounds valorisation of biomass veratryl alcohol

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Influence of La_2O_3 on preparation and performance of porous cordierite from rice husk

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Journal of Rare Earths 2010年第4期28卷 614-617页

作者：郭伟陆洪彬冯春霞 Department of Materials Engineering Yancheng Institute of Technology

A porous cordierite was synthesized at 1350 ℃ using rice husk as silica source and pore forming agent, and La2O3 as fluxing agent. The crystal phases of the cordierite were analyzed by X-ray diffraction (XRD) and their microstructures were observed by scanning electronic microscopy (SEM). The flexural strength, porosity and thermal expansion coefficient of the porous cordierite samples were inves- tigated in detail. Results showed that when 5 wt.% La2O3 was added, the flexural strength, porosity and thermal...

关键词： porous ceramic cordierite rice husk lanthana

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Production of chitosan-based composite film reinforced with lignin-rich lignocellulose nanofibers from rice husk

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Journal of Bioresources and Bioproducts 2024年第2期9卷 174-184页

作者： Hye Jee Kang Yeon Ju Lee Jin Kyoung Lee Irnia Nurika Sri Suhartini Deokyeong Choe Dong Hyun Kim Hoon Choi Natasha P.Murphy Ho Yong Kim Young Hoon Jung School of Food Science and Biotechnology Kyungpook National UniversityDaegu 41566Republic of Korea CPR S&T Co. Ltd.Gunpo 15880Republic of Korea Department of Agroindustrial Technology Faculty of Agricultural TechnologyUniversitas BrawijayaMalang 65145Indonesia Renewable Resources and Enabling Sciences Center National Renewable Energy LaboratoryGoldenCO 80401United States Center for Bio-based Chemistry Korea Research Institute of Chemical TechnologyUlsan 44429Republic of Korea

Lignocellulosic nanofibers(LCNFs),implying lignin-containing cellulose fibers,maintain the prop-erties of both lignin and cellulose,which are hydrophobic and hydrophilic,*** pres-ence of hydrophobic lignin in LCNFs is expected to be an economical and attractive option that can improve the thermal and mechanical properties of ***,this study was conducted to produce lignin-rich LCNFs from sugar-rich waste obtained from rice husks after acidic *** LCNFs were produced from the lignin-rich solid fractions obtained after pretreatment and enzymatic hydrolysis,which were then incorporated as an additive into a chitosan-based *** variations in lignin content in the range of approximately 50.6%-66.8%in differently obtained LCNFs gave significantly different optical strengths and mechanical *** controllable processes may allow for customized film ***,the glucose-rich liquid fractions obtained after pretreatment and enzymatic hydrolysis were used as a substrate for ethanol fermentation to achieve total utilization of rice husk biomass *** conclusion,the lignin-rich biomass fraction holds promise as a suitable material for chitosan-LCNF film and has the potential to increase the economic feasibility of the biomaterial industry.

关键词： rice husk Lignocellulose nanofiber Lignin-based material Chitosan film Upcycling

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Pyrolysis of rice husk and sawdust for liquid fuel

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Journal of Environmental Sciences 2006年第2期18卷 392-396页

作者： ZHU Xi-feng ZHENG Ji-lu GUO Qing-xiang ZHU Qing-shi Biomass Clean Energy Laboratory University of Science and Technology of China Hefei-230026 China

The paper is focused on studying how to convert rice husk and sawdust into liquid fuel. rice husk, sawdust and their mixture were pyrolyzed at the temperature between 420℃ and 540℃, and the main product of liquid fuel was obtained. The experimental result showed that the yield of liquid fuel heavily depended on the kind of feedstock and pyrolysis temperature. In the experiments, the maximum liquid yields for rice husk, sawdust and their mixture were 56% at 465 ℃, 61% at 490℃ and 60% at 475℃ respectively. Analysis with GC-MS and other apparatus indicated that the liquid fuel is a complicated organic compound with low caloric value and can be directly used as fuel oil without any up-grading. As a crude oil, the liquid fuel can be refined to be vehicle oil.

关键词： solid organic waste rice husk sawdust pyrolysis liquid fuel

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Pyrolysis of rice husk in a Fluidized Bed Reactor:Evaluate the Characteristics of Fractional Bio-Oil and Particulate Emission of Carbonaceous Aerosol(CA)

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Journal of Renewable Materials 2020年第3期8卷 329-346页

作者： Ning Li Weiming Yi Zhihe Li Lihong Wang Yongjun Li Xueyuan Bai Mei Jiang School of Agricultural Engineering and Food Science Shandong University of TechnologyZibo255000China Shandong Research Center of Engineering and Technology for Clean Energy Zibo255000China

Bio-oil production via pyrolysis is one of promising technologies for renewable energy production from ***,the complicated biooil is still a challenge for high-valued application and during biomass pyrolysis,the emission of non-cleaned aerosol,the potential emission,namely carbonaceous aerosol(CA)increased the difficulty of the commercial *** this study,rice husk pyrolysis was performed in a semi-continuous fluidized bed reactor coupled with fractional *** effects of pyrolysis and condensation temperature on the properties of bio-oil and emission of CAwere investigated *** indicated that the in-situ separation of vapors was accomplished via condensers of different temperatures(85℃and−10℃).The bio-oil with different physiochemical properties were obtained in the high content of phenols and lower acids of BO1 and high content of acids and better *** size distribution of CA was found primarily classified as sub-micrometer grade particles,which have a diameter of less than 1.1μ*** particular,CA existed in three representative forms:bead,granular aggregate,and *** results of light absorption of total organic carbon(TOC)and non-volatile organic carbon(NVOC)indicated that the absorption per mass increased in the single temperature with the decrement of wavelength and it improved as the pyrolysis temperature increased at the specified *** absorption per mass was to maximum value(3.7 m^(2)/g)at 360 nm wavelength and 600℃.TOC demonstrated a strong light absorption and a wide spectral range dependence(AAE:5.08-10.05)which enhanced the light absorption in the ultra-violet and low-visible regions.

关键词： rice husk pyrolysis bio-oil aerosol size distribution light absorption

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Study of Kinetic Characteristics for Drying rice husk

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Journal of Harbin Institute of Technology(New Series) 2013年第3期20卷 56-62页

作者： Xu-Dong Chen Huai-Bin Wang Ming Xie School of Energy Science and Engineering Harbin Institute of Technology

rice husk (biomass fuel) samples have been dried in drying oven and a series of drying curve for illustrating moisture migration of rice husk have been obtained. It is first research for rice husk drying,and it can provide reference of fuel processing for different boilers which require rice husk with various water contents. In this paper,we apply Page equation to reflect the drying process and obtain drying characteristic curve,then analyze the drying law. Kinetic analysis of the results of moisture migration test has been done,after which, effective moisture diffusion coefficient,activation energy and drying kinetic equation of rice husk samples are obtained in test temperature range (80 - 130 ℃) . And these results show specific influence law of temperature for effective moisture diffusion coefficient.

关键词： rice husk drying characteristic curve effective moisture diffusion coefficient activation energy kinetic analysis

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Preparation and properties of low cost porous titanium by using rice husk as hold space

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Progress in Natural Science:Materials International 2017年第3期27卷 344-349页

作者： Xinsheng Wang Zhenlin Lu Lei Jia Feizhou Li School of Materials Science and Engineering Xi'an University of Technology Department of Mechanical Baoji University of Arts and Sciences

The present study demonstrates an effective low cost effective process for the production of porous titanium with 50-60 vol% porosity using 20 wt% rice husk(RH) with the hold spaces in the size ranges of 100-180,180-250,250-380,and 380-550 μ*** analysis of the samples revealed an interconnected pore microstructure consisting of a mixture of coarse channel pores,created during burnout of *** compressive strength of the developed samples was in the range of 17-70 MPa and depended strongly on their porosity and pore *** amounts of cleavage steps appeared on the brittle fracture surface after compression of the *** 3D morphology of porous titanium surface with rice husk sizes of 100-180μm and 380-550μm can be characterized by the micro-hole surface of pore size,and the size of the hole diameter and *** developed porous titanium is considered potentially useful in future medical or industrial application of biomass.

关键词： Porous Titanium rice husk Mechanical properties 3D morphology Biomass

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