检索结果-南通市图书馆

Highly efficient and green synthesis of 14-aryl(alkyl)-14H-dibenzo[a,j]xanthene and 1,8-dioxooctahydroxanthene derivatives catalyzed by reusable zirconyl triflate[ZrO(OTf)_2]under solvent-free conditions

引用

Chinese Chemical Letters 2011年第1期22卷 9-12页

作者： Iraj Mohammadpoor-Baltork Majid Moghadam Valiollah Mirkhani Shahram Tangestaninejad Hamid Reza Tavakoli Department of Chemistry Catalysis DivisionUniversity of IsfahanIsfahan 81746-73441Iran

An efficient, convenient and green method has been introduced for the preparation of 14-aryl（alkyl）-14H-dibenzo[a,j]xanthene and 1,8-dioxooctahydroxanthene derivatives by the reaction of aldehydes with 2-naphthol and 5,5-dimethyl-1,3-cyclohexanedione, respectively, in the presence of ZrO（OTf）2 as a reusable catalyst under solvent-free conditions. In addition, very short reaction times, excellent yields, straightforward procedure, and relatively non-toxicity of the catalyst are other noteworthy advantages of the present method.

关键词： Xanthenes Zirconyl triflate Aldehydes 2-Naphthol reusable catalyst

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Simple and Efficient Method for Deprotection of Tetrahydropyranyl Ethers by Using Silica Supported Sodium Hydrogen Sulphate

引用

Chinese Journal of Chemistry 2012年第5期30卷 1189-1191页

作者： Kumar K. Ravi Satyanarayana P. V. V. Reddy B. Srinivasa RA Chem Pharma Limited Research and Development Division Prasanth Nagar Hyderabad 500072 AP India Department of Chemistry Aeharya Nagarjuna University Nagarjuna Nagar Guntur 522510 AP India

Tetrahydropyranyl （THP） ethers have been efficiently and simply deprotected by using Silica supported sodium hydrogen sulphate （NaHSO4-SiO2） in methanol at room temperature to regenerate the parent alcohols in hig... 详细信息

关键词： THP ethers deprotection NaHSO4-SiO2 methanol reusable catalyst

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

An Efficient Procedure for Esterification of Aryloxyacetic Acid and Arylthioacetic Acid Catalyzed by Silica Sulfuric Acid

引用

有机化学 2004年第z1期24卷 85-页

作者： LI,Hong-Ya LI,Ji-Tai LI,Hui-Zhang College of Chemistry and Environment Science Hebei University Baoding 071002 College of Chemistry and Environment Science Hebei University Baoding 071002 College of Chemistry and Environment Science Hebei University Baoding 071002

　　Aryloxyacetate and arylthioacetate are wildly used in herbicides, plant regulator and insecticides. Recently, Wille et al. have reported that methyl aryloxyacetate is an efficient agent to prevent and treat allergic contact dermatitis.[1] The most popular synthesis is by heating sodium phenoxide (mercaptide) with ethyl chloroacetate in DMF,[2] or by the esterification of acid with alcohol using concentrated H2SO4 as catalyst.[3] In this paper, synthesis of aryloxyacetate and aryl thioacetate from aryloxyacetic acid and arylthioacetic acid respectively in ether catalyzed by silica sulfuric acid in 83%～94% yields is described. The catalyst is reused for 3 times without significant loss of activity (Entry 4). Compared with common procedures, the present procedure possesses the advantages of the operational simplicity, short reaction time,less-corrosion, high yield and reusable catalyst.……

关键词： allergic contact dermatitis silica sulfuric acid ethyl chloroacetate reusable catalyst reaction time used in

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：