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Hydrocarbon expulsion model and resource potential evaluation of high-maturity marine source rocks in deep basins:Example from the Ediacaran microbial dolomite in the Sichuan Basin,China

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Petroleum Science 2022年第6期19卷 2618-2630页

作者： Wen-Yang Wang Xiong-Qi Pang Ya-Ping Wang Zhang-Xin Chen Chang-Rong Li Xin-Hua Ma State Key Laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China State Key Laboratory of Petroleum resources and Prospecting China University of Petroleum(Beijing)Beijing 102249China College of Geosciences China University of Petroleum(Beijing)Beijing 102249China Research Institute of Exploration and Development Petro China Southwest Oil&Gas Field CompanyChengduSichuan 610041China Chemical and Petroleum Engineering Schulich School of EngineeringUniversity of CalgaryCalgary T2N 1N4Canada School of Earth and Space Sciences Peking UniversityBeijing 100871China Research Institute of Petroleum Exploration and Development(RIPED) Petro ChinaBeijing 100083China

Hydrocarbon expulsion features and resource potential evaluation of source rocks are crucial for the petroleum exploration.High-maturity marine source rocks have not exhibited a hydrocarbon expulsion mode owing to the lack of low-maturity source rocks in deep petroliferous basins.We considered the Ediacaran microbial dolomite in the Sichuan Basin,the largest high-maturity marine gas layer in China,to exhibit a method that quantitatively characterizes the hydrocarbon expulsion of high-maturity marine source rocks.The experiment of fluid inclusion,rock pyrolysis,and vitrinite reflectance(Ro)of 119 microbial dolomite core samples obtained from the Dengying Formation were performed.A hydrocarbon expulsion model of high-maturity source rock was established,and its resource potential was evaluated.The results showed that the Ediacaran microbial dolomite in the Sichuan Basin is a good source rock showing vast resource potential.The hydrocarbon expulsion threshold is determined to be vitrinite reflectance at 0.92%.The hydrocarbon expulsion intensities in the geologic history is high with maximum of 1.6×10^(7)t/km^(2).The Ediacaran microbial dolomite expelled approximately 1.008×10^(12)t of hydrocarbons,and the recoverable resource was 1.5×10^(12)m^(3).The region can be categorized into areasⅠ,Ⅱ,Ⅲ,andⅣ,in decreasing order of hydrocarbon expulsion intensity.Areas with a higher hydrocarbon expulsion intensity have a lower drilling risk and should be prioritized for exploration in the orderⅠ>Ⅱ>Ⅲ>Ⅳ.Two areas,northern and central parts of Ediacaran in the Sichuan Basin,were selected as prospects which had the drilling priority in the future gas exploration.The production data of 55 drilled wells verified the high reliability of this method.This model in this study does not require low-maturity samples and can be used for evaluating high-maturity marine source rocks,which has broad applicability in deep basins worldwide.

关键词： Deep petroliferous basin Overmatured source rocks Hydrocarbon expulsion model resource evaluation Sichuan basin

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The key parameter of shale oil resource evaluation: Oil content

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Petroleum Science 2022年第4期19卷 1443-1459页

作者： Min Wang Ming Li Jin-Bu Li Liang Xu Jin-Xu Zhang State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing102206China SINOPEC Key Laboratory of Petroleum Accumulation Mechanisms WuxiJiangsu 214126China Shandong Provincial Key Laboratory of Deep Oil and Gas QingdaoShandong 266580China School of Geoscience China University of Petroleum(East China)QingdaoShandong 266580China

The United States has become the world's largest oil producer of shale oil. China has abundant shale oil resources, but its resource potential has not yet been exploited. The core of the evaluation is the selection of parameters and their reliability. By combining the parameters of the shale oil resource evaluation, we investigated the key parameters in the evaluation model and reviewed the research results. The adsorption and retention of heavy hydrocarbons, loss of light hydrocarbons, and original oil saturation are key in the evaluation of shale oil resources. The adsorption and retention of heavy hydrocarbons can be determined by the pyrolysis, FID curve, and hydrocarbon generation kinetics of shale before and after extraction. The loss of light hydrocarbons mainly occurs in coring(change in temperature and pressure),sample treatment, which can be evaluated using the GC spectrum, rock pyrolysis, crude oil volume coefficient, mass balance, component hydrocarbon generation kinetics, and other methods. The original oil saturation evaluation includes indirect, direct, logging, and simulation methods. The most reliable parameters can be obtained by using the sealed or pressure-maintained coring immediately after thawing(without crushing), and the recovery of light hydrocarbon loss is critical for the resource evaluation of medium to high mature shale. Therefore, the experimental determination of shale oil content and the study of the influencing factors of the parameters should be strengthened.

关键词： Shale oil Oil content Oil saturation Light hydrocarbon recovery resource evaluation

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Shale oil resource evaluation with an improved understanding of free hydrocarbons:Insights from three-step hydrocarbon thermal desorption

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Geoscience Frontiers 2023年第6期14卷 464-477页

作者： Gang Yan Yao-Hui Xu Wang-Lin Xu Bin Bai Ying Bai Yun-Peng Fan Shan-Shan Li Ming Zhong Yan Liu Zhi-Yao Xu Cooperative Innovation Center of Unconventional Oil and Gas Yangtze University(Ministry of Education&Hubei Province)Wuhan 430100China Hubei Key Laboratory of Petroleum Geochemistry and Environment Yangtze UniversityWuhan 430100China Research Institute of Petroleum Exploration and Development PetroChinaBeijing 100083China School of Energy and resources China University of GeosciencesBeijing 100083China Suzhou Grand Energy Technology Co.Ltd Suzhou 215129China

The pyrolysis parameter S1,which indicates the amount of free hydrocarbons present in shale,is often underestimated due to hydrocarbon loss during sample handling and measurement processes.To remedy this issue,we strongly recommend an immediate three-step hydrocarbon thermal desorption(HTD)approach to be conducted on oil shale at the drilling site.This approach measures S_(g),S_(O),and S_(1)^(*),which refer to gaseous,light,and free hydrocarbons,respectively.The new shale oil content value,calculated from the total of these three parameters,is far more precise and reliable than traditional pyrolysis S1.Moreover,we thoroughly investigated the components and microscopic occurrence features of hydrocarbons thermally desorbed at three temperature stages using gas chromatography(GC)and X-ray microcomputed tomography(CT).For example,we selected Chang 7_(3)mud shale.Our experimental results irrefutably indicate that the ultimate shale oil content of poor resource rocks is significantly impacted by evaporative loss,with this effect being greater when the total organic carbon(TOC)is lower.Additionally,C_(1-5)and C_(1-7)hydrocarbons constitute almost all of S_(g)and S_(O),respectively.S_(g)and S_(O)are predominantly composed of C_(1-3)gaseous hydrocarbons,with a maximum proportion of 42.93%.In contrast,S_(1)^(*)contains a substantial amount of C_(16-31)hydrocarbons.A three-dimensional reconstruction model of an X-ray micro-CT scan shows that while the amount of shale organic matter greatly decreases from the frozen state to 300℃,the pore volume significantly increases,particularly between 90 and 300℃.The increased pore volume is mainly due to macropores and fractures.It is imperative to note that the shale oil triple-division boundaries must be adjusted based on more accurate oil content,although this would not affect the resource zones to which the samples already belong(ineffective,low-efficient,and enriched resources).In conclusion,we strongly advise conducting an immediate well-site analysis or utilizing preservation p

关键词： Shale oil Hydrocarbon thermal desorption resource evaluation Component Microscopic occurrence feature

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Reduction of global natural gas hydrate(NGH)resource estimation and implications for the NGH development in the South China Sea

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Petroleum Science 2022年第1期19卷 3-12页

作者： Xiong-Qi Pang Cheng-Zao Jia Zhang-Xing Chen He-Sheng Shi Zhuo-Heng Chen Tao Hu Tong Wang Zhi Xu Xiao-Han Liu Xing-Wen Zhang En-Ze Wang Zhuo-Ya Wu Bo Pang State Key Laboratory of Petroleum resources and Prospecting Beijing102249China College of Geosciences China University of Petroleum(Beijing)Beijing102249China China National Petroleum Corporation Beijing100007China Chemical and Petroleum Engineering Schulich School of EngineeringUniversity of CalgaryCalgaryT2N 1N4Canada Shenzhen Branch of China National Offshore Oil Corporation Ltd. GuangzhouGuangdong 510240China Geological Survey of Canada Natural Resources CanadaCalgaryT2L 2A7Canada School of Earth&Space Sciences Peking UniversityBeijing100871China

There have been at least 29 groups of estimates on the global natural gas hydrate(NGH)resource since1973,varying greatly with up to 10,000 times and showing a decreasing trend with time.For the South China Sea(SCS),35 groups of estimations were conducted on NGH resource potential since 2000,while these estimates kept almost the same with time,varying between 60 and 90 billion tons of oil equivalent(toe).What are the key factors controlling the variation trend?What are the implications of these variations for the NGH development in the world and the SCS?By analyzing the investigation characteristics of NGH resources in the world,this study divided the evaluation process into six stages and confirmed four essential factors for controlling the variations of estimates.Results indicated that the reduction trend reflects an improved understanding of the NGH formation mechanism and advancement in the resource evaluation methods,and promoted more objective evaluation results.Furthermore,the analysis process and improved evaluation method was applied to evaluate the NGH resources in the SCS,showing the similar decreasing trend of NGH resources with time.By utilizing the decreasing trend model,the predicted recoverable resources in the world and the SCS are(205-500)×10^(12)m^(3)and(0.8-6.5)×10^(12)m^(3),respectively,accounting for 20%of the total conventional oil and gas resources.Recoverable NGH resource in the SCS is only about 4%-6%of the previous estimates of 60-90 billion toe.If extracted completely,it only can support the sustainable development of China for 7 years at the current annual consumption level of oil and gas.NGH cannot be the main energy resource in future due to its low resource potential and lack of advantages in recovery.

关键词： Natural gas hydrate resource evaluation South China Sea Global NGH resource Reduction trend in NGH resource

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A Detail Investigation on the Antarctic Wind Energy

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中国海洋工程:英文版 2023年第4期37卷 698-708页

作者： WANG Kai-shan WU Di ZHENG Chong-wei TAO Gui-sheng LI Wei GAO Yuan-bo YU Yue WU Kai Dalian Naval Academy Dalian 116018China Marine resources and Environment Research Group on the Maritime Silk Road Dalian 116018China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai 519082China

The scientific development of wind energy based on local conditions is conducive to the urgent energy demand and environmental protection of Antarctic region.In this study,the ERA5 reanalysis data are used to evaluate the wind energy resources in the Antarctic region.A series of key indicators,such as wind power density,effective wind speed occurrence,energy level occurrence and stability,are comprehensively considered by using climate statistical analysis methods to analyze the temporal and spatial distribution characteristics of Antarctic wind energy resources.The results show that the Antarctic region contains abundant wind energy resources,which benefits the construction of scientific research stations.The superior areas are the Southern Ocean and the coast of the East Antarctica,followed by the Transantarctic Mountains,the coast of the Bellingshausen Sea and Amundsen Sea.These areas have advantages in terms of wind power density(500-2500 W/m2),effective wind speed occurrence(80%-90%),energy level occur-rence(60%-90%)and stability(Cv:0.6-1,Mv:1.2-1.8,Sv:0.8-1.2).The Antarctic’s wind energy resources in wind power density,effective wind speed occurrence and energy level occurrence in autumn and winter are better than those in summer,while the coefficient of variation in summer is worse than that in autumn and winter.

关键词： Antarctic wind energy resource evaluation temporal and spatial characteristics

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evaluation of natural gas hydrate resources in the South China Sea by combining volumetric and trend-analysis methods

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Petroleum Science 2022年第1期19卷 37-47页

作者： Xing-Wen Zhang Tao Hu Xiong-Qi Pang Yao Hu Tong Wang En-Ze Wang Zhi Xu Xiao-Han Liu Zhuo-Ya Wu Laboratory of Petroleum resources and Prospecting China University of Petroleum(Beijing)Beijing 102249China College of Geosciences China University of Petroleum(Beijing)Beijing 102249China CNOOC International Limited Beijing 100029China School of Earth&Space Sciences Peking UniversityBeijing 100871China Research Institute of Petroleum Exploration and Development PetroChina Company LimitedBeijing 100083China

Natural gas hydrate(NGH),considered as a type of premium energy alternative to conventional hydrocarbons,has been broadly studied.The estimate of the total NGH resources in the world has decreased by more than 90%since the first evaluation in 1973.Geographic and geophysical conditions of the South China Sea(SCS)are favorable for the formation of NGH,which has been proved by drilling results up to date.The recoverability of the NGH in the SCS has been confirmed by the production tests using both vertical and horizontal wells.Since 2001,35 estimates of NGH resources in the SCS have been made,with relatively stable results varying between 600 and 900×109 ton oil equivalent.In these estimations,the volumetric method was commonly adopted,but the geological conditions,the migration-accumulation mechanisms of NGH,and the practical recoverability were not considered.These estimates cannot be regarded as evaluated resources according to the international resource evaluation standards,but are at most about prospective gas content of NGH,thus inefficient for guiding explorations and developments.To solve these problems,this study divides the past NGH surveys in the SCS into seven stages,acquires key geological parameters of every stage based on previous studies and analogy with other areas,evaluates the NGH resources of these seven stages by using the volumetric method,then adopts a new trend-analysis method to simulate the downward trend of these estimates,and finally predicts the NGH resources in the SCS at 2025 and 2030.The downward trend is because of the continuous improvement of NGH understanding over time,which is consistent with the trend of global NGH estimates.At the present stage(from 2019 to 2021),the average technically recoverable resource(ATRR)is 7.0×10^(12)m^(3),and the estimates of 2025 and 2030 ATRR are 6.46×10^(12)m^(3) and 4.01×10^(12)m^(3)respectively,with a difference of less than 40%.Therefore,it can be inferred that the ATRR of NGH in the SCS is between 4.0 and 6.5×10^(12)m^(3),with an average of 5.2

关键词： resource evaluation Natural gas hydrates The South China Sea Volumetric method Trend-analysis method

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Deep bedrock geothermal resources in the Maichen Sag,Beibuwan Basin and their potential for exploitation and utilization

能源地球科学(英文)

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能源地球科学(英文) 2023年第4期4卷 188-197页

作者： Yan Zeng Ying Zhang Exploration and Production Research Institute SINOPECBeijing100083China

The Maichen Sag in the south-central part of the Beibuwan Basin is abundant in geothermal resources that have not been widely exploited and utilized due to inadequate research on it.This study evaluated the geothermal resources in the Maichen Sag based on the regional geological setting and geothermal conditions.Grid units for assessment and a geological model for areas with geothermal resources were established using spatial analysis techniques.The spatial distribution models of the physical and thermophysical properties of the geothermal reservoirs were also built using the Kriging interpolation method.Based on the terrestrial heat flow distribution in the target areas,the spatial distribution of the geo-temperature field through the inversion under the constraints of the temperature data from boreholes were predicted.Factors such as deep geo-temperature,thermophysical properties of rocks,and terrestrial heat flow values,were integrated into this quantitative evaluation of geothermal resources through the geological modeling-based volume method and the geothermal reservoir engineering-based numerical simulation method.The results show that the Maichen Sag has favorable heat source conditions with intersected,deep-rooted faults and widely developed Upper Paleozoic fissured granite geothermal reservoirs.The northern outer slope zone at a burial depth of 3‒5 km on the tectonic plane of the basement in the sag is suggested to be a potential target area,where,as calculated using the volume method,is likely to be the home to the total geothermal resources of 80.4×10^(9)GJ(i.e.,2.75×10^(9)tonnes of coal equivalent(tce))in the bedrock geothermal reservoirs at a burial depth of 3‒6 km.The geotemperature of 172‒201℃at a formation depth of 5 km in the sag also indicates that the deep geothermal resources are of high value for exploitation.

关键词： Maichen sag Geothermal resource resource evaluation Parameter estimation for geothermal resource exploitation Numerical simulation

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Formation characteristics and resource potential of Jurassic tight oil in Sichuan Basin

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Petroleum Research 2017年第4期2卷 301-314页

作者： Denghua Li Jianzhong Li Bin Zhang Jiajing Yang Shaoyong Wang Strategic Research Center of Oil and Gas resources Ministry of Land and ResourcesBeijing 100034China PetroChina Research Institute of Petroleum Exploration and Development Beijing 100083China Institute of Exploration and Development PetroChina Southwest Oil and Gas Field CompanyChengdu 610041China

Through test analysis of large amount of cores,rock fragments and crude oil samples,and in combination with dynamic data of production from 456 oil wells,hydrocarbon generation potentials of four major source rocks and accumulation characteristics of three major pay layers in the Jurassic of Sichun Basin were well investigated.Results indicated that source rocks in the Lianggaoshan Formation,the Da'anzhai Member and the Dongyuemiao Member mainly generated oil,and those in the Zhenzhuchong Member dominantly generated gas;the organic-rich source rocks controlled distribution of sweet spots of tight oil,and most industrial oil wells were located at the area with high-quality source rocks(TOC>1.2%);and micron-sized pore throats were effective storage space,and fractures played a key role in initial high yield.Jurassic tight oil in the Sichuan Basin was characterized by light oil,high gas-oil ratio and abnormal high pressure,which were favorable for tight oil flow and output.Four methods(i.e.,small bin method,resource abundance analogy method,EUR analogy method and total organic carbon method)were used to estimate Jurassic oil in-place in the Sichuan Basin which ranged from 2×10^(9) to 3×10^(9) t.Through analysis of main controlling factors of resource enrichment,the grading criteria were established for the evaluation of oil in-place in the Sichuan Basin.Through the small bin method,the oil in-place of Type I,Type II and Type III was 1.611×10^(9)t,0.477×10^(9)t and 0.289×10^(9)t,respectively.It was predicted that the largest exploration potential of the Da'anzhai Member was in the Nanchong-Suining area and the east of Liangping area,the most favorable exploration area of the Lianggaoshan Formation was in the Guang'anNanchong-Suining-Yilong area,and the good exploration prospect of the Dongyuemiao Member was in the south of the Guang'an-Suining area.

关键词： Tight oil High-quality source rock Preservation condition Pore throat Sweet spot resource evaluation Jurassic Sichuan Baisn

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Research on evaluation and Development of Industrial Heritage Tourism resources in Textile Valley

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Asian Agricultural Research 2021年第10期13卷 1-4页

作者： Xiaomei LIU Hui WANG Weijun ZHAO Xiaomeng JI School of Tourism Taishan UniversityTaian 271000China College of Physical Education Taishan UniversityTaian 271000China Management College Ocean University of ChinaQingdao 266000China

This paper selects Qingdao Textile Valley as the research object,establishes the evaluation system of industrial heritage tourism resources,and analyzes the evaluation factors of industrial heritage tourism resources,such as resource element value,market location value,and environmental factors.Then this paper puts forward some effective suggestions to promote the development of industrial heritage tourism in Textile Valley.The results show that the measures put forward,such as fully tapping the value of resource elements,improving the surrounding traffic environment,perfecting tourism signs,perfecting local traffic routes,improving the complementarity of tourism resources,and expanding the tourist market,can scientifically and effectively protect urban industrial heritage,improve the development level of urban tourism,and speed up the transformation of new and old energy in Qingdao.

关键词： Textile Valley Industrial heritage tourism resource evaluation

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人口规模与交通环境影响的中国城市旅游资源—经济空间错位

旅游管理

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旅游管理 2021年第6期

作者：杨宇民焦胜廖婧茹刘奕村胡亮邓凌云郑华伍天亮

针对旅游发展“区域差异大，发展不平衡”带来的城市旅游发展潜力未能充分发掘和旅游供给分配效率低等问题，以中国地级行政区为主，与直辖市和省辖县一同作为研究区，利用12 135个旅游资源结合旅游经济、人口规模、交通环境大数据，通... 详细信息

针对旅游发展“区域差异大，发展不平衡”带来的城市旅游发展潜力未能充分发掘和旅游供给分配效率低等问题，以中国地级行政区为主，与直辖市和省辖县一同作为研究区，利用12 135个旅游资源结合旅游经济、人口规模、交通环境大数据，通过回归分析和空间分析法得出中国城市旅游资源—经济空间错位特征，以及基于人口规模—交通环境相对优势的强弱关系空间分布特征。其中资源—经济优势错位区中有34个规模优势型城市(SA型地区)和48个交通优势型城市(TA型地区)，分别呈现“南方优势化”和“省际边缘化”特征，资源—经济劣势错位区中有46个规模优势型城市(SI型地区)和75个交通优势型城市(TI型地区)，分别呈现“中部南部集中化”特征和“国界边缘化”特征。研究定量比对了旅游发展中城市与城市之间的差距，讨论各区域在旅游发展过程中可能面临的机遇和挑战，有利于充分发掘城市旅游发展潜力，从而实现全域旅游背景下旅游发展收益最大化的目标。

关键词：大数据资源评价资源诅咒人口规模交通环境空间错位旅游业　　big data resource evaluation resource curse population size traffic environment spatial dislocation tourism

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