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Experimental evaluation of factors affecting performance of concentrating photovoltaic/thermal system integrated with phase‐change materials(PV/T‐CPCM)

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Energy Storage and Saving 2024年第1期3卷 30-41页

作者： Zhaoyang Luan Lanlan Zhang Xiangfei Kong Han Li Man Fan School of Energy and Environmental Engineering Hebei University of TechnologyTianjin300401China School of Mechanical Engineering Beijing Institute of TechnologyBeijing100081China

The photovoltaic/thermal(PV/T)system is a promising option for countering energy *** improve the performance of PV/T systems,compound parabolic concentrators(CPCs)and phase-change materials(PCMs)were jointly applied to construct a concentrating photovoltaic/thermal system integrated with phase-change materials(PV/T-CPCM).An open-air environment is used to analyze the effects of different parameters and the intermittent operation strategy on the system *** results indicate that the short-circuit current and open-circuit voltage are positively correlated with the solar irradiance,but the open-circuit voltage is negatively correlated with the temperature of the PV *** the solar irradiance is 500 W⋅m^(−2) and the temperature of the PV modules is 27.5℃,the short-circuit current and open-circuit voltage are 1.0 A and 44.5 V,*** solar irradiance results in higher thermal power,whereas the thermal efficiency is under lower solar irradiance(136.2-167.1 W⋅m^(−2) is twice under higher solar irradiance(272.3-455.7 W⋅m^(−2))).In addition,a higher mass flow rate corresponds to a better cooling effect and greater pump energy *** the mass flow rate increases from 0.01 to 0.02 kg⋅s^(-1),the temperature difference between the inlet and outlet decreases by 1.8℃,and the primary energy-saving efficiency decreases by 0.53%.The intermittent operation of a water pump can reduce the energy consumption of the system,and the combination of liquid cooling with PCMs provides better thermal regulation and energy-saving effects under various conditions.

关键词： Compound parabolic concentrator Factor analysis Open-air experiment phase-change materials Photovoltaic/thermal system

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Bioinspired solar anti-icing/de-icing surfaces based on phase-change materials

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Science China materials 2022年第5期65卷 1369-1376页

作者： Siyu Sheng Zhicheng Zhu Zhanhui Wang Tongtong Hao Zhiyuan He Jianjun Wang Key Laboratory of Green Printing Institute of ChemistryChinese Academy of SciencesBeijing 100190China School of Future Technology University of Chinese Academy of SciencesBeijing 100049China Zhong Neng Power-Tech Development CO. LTD.Beijing 100037China

Solar anti-icing/de-icing is an environmentally friendly way to convert light energy into heat with the purpose of melting/removing ice. However, the inherent intermittency of solar irradiation limits the application of solar-thermal energy-conversion technologies, when continuous de-icing is required. Herein, we investigate a solar phase-change material(SPCM) that consists of expanded graphite(EG)/paraffin/polydimethylsiloxane(PDMS), which can not only perform the solar-thermal conversion but also release/store thermal energy. Under sunlight, the SPCM effectively collects and converts the light energy into thermal energy for later antiicing/de-icing. To prepare for a no-light period, e.g., in the evening, the converted thermal energy can be stored in the SPCM using a phase transition. In this way, the energy can be released when needed to keep the temperature of a surface from freezing. The SPCM surface shows excellent anti-icing/de-icing properties such as a long droplet freeze-delay time(td> 2 h), even at an ultra-low temperature(-40℃), using only the light of one sun. This freeze-delay time is much longer than that for a surface without PCM. The tested SPCM surfaces show a high de-icing rate(2.21 kg m^(-2)h^(-1)) under real-life conditions. In addition, the SPCM shows a high de-icing rate and excellent durability. This study provides a promising route for the utilization of solar energy in anti-icing/de-icing applications.

关键词： bioinspired phase-change materials anti-icing/deicing solar energy multifunctional

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Hierarchical graphene foam-based phase change materials with enhanced thermal conductivity and shape stability for efficient solar-to-thermal energy conversion and storage

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Nano Research 2017年第3期10卷 802-813页

作者： Guoqiang Qi Jie Yang Ruiying Bao Dongyun Xia Min Cao Wei Yang Mingbo Yang Dacheng Wei State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science Fudan University Shanghai 200433 China College of Polymer Science and Engineering State Key Laboratory of Polymer Materials Engineering Sichuan University Chengdu 610065 China

Recently, graphene foam （GF） with a three-dimensional （3D） interconnected network produced by template-directed chemical vapor deposition （CVD） has been used to prepare composite phase-change materials （PCMs） with enhanced thermal conductivity. However, the pore size of GF is as large as hundreds of micrometers, resulting in a remarkable thermal resistance for heat transfer from the PCM inside the large pores to the GF strut walls. In this study, a novel 3D hierarchical GF （HGF） is obtained by filling the pores of GF with hollow graphene networks. The HGF is then used to prepare a paraffin wax （PW）-based composite PCM. The thermal conductivity of the PW/HGF composite PCM is 87% and 744% higher than that of the PW/GF composite PCM and pure PW, respectively. The PW/HGF composite PCM also exhibits better shape stability than the PW/GF composite PCM, negligible change in the phase-change temperature, a high thermal energy storage density that is 95% of pure PW, good thermal reliability, and chemical stability with cycling for 100 times. More importantly, PW/HGF composite PCM allows light-driven thermal energy storage with a high light-to- thermal energy conversion and storage efficiency, indicating its great potential for applications in solar-energy utilization and storage.

关键词： phase-change materials hierarchical graphene foam light-to-thermal energyconversion thermal conductivity solar energy

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Effect of Nanomaterials Addition to phase change materials on Heat Transfer in Solar Panels under Iraqi Atmospheric Conditions

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Frontiers in Heat and Mass Transfer 2023年第1期21卷 215-226页

作者： Majid Ahmed Mohammed Abdullah Talab Derea Mohammed Yaseen Lafta Obed Majeed Ali Omar Rafae Alomar Department of Power Mechanics Haweja Technical InstituteNorthern Technical UniversityKirkuk36001Iraq Department of Reconstruction and Projects Ministry of Higher Education and Scientific ResearchBaghdad10065Iraq Department of Physics College of EducationAl-Iraqia UniversityBaghdad10053Iraq Engineering Technical College of Mosul Northern Technical UniversityMosul41002Iraq

It is common knowledge that phase-change materials are used for the purpose of thermal storage because of the characteristics that are exclusive to these materials and not found in *** characteristics include a large capacity for absorbing heat and a large capacity for releasing heat when the phase changes;however,these materials have a low thermal *** paper presents the results of an experimental study that investigated the impact that nanoparticles of copper oxide had on reducing the temperature of solar *** phase change substance that was used was determined to be *** impact of adding nanoscale copper oxide at a concentration of 0.05%of the total mass of wax was investigated and compared to a reference solar panel that did not contain any nanoscale *** findings demonstrated that the incorporation of nanoscale copper oxide brought about a reduction of three℃ in the plate’s average temperature as well as a one percent improvement in its electrical *** cases where it seems that the use of nanoparticles might potentially enhance the performance of integrated solar energy systems that contain phase change.

关键词： Copper oxide nanoparticles nanoparticle beeswax thermal conductivity phase-change materials

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Fabrication and integration of photonic devices for phase-change memory and neuromorphic computing

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International Journal of Extreme Manufacturing 2024年第2期6卷 2-27页

作者： Wen Zhou Xueyang Shen Xiaolong Yang Jiangjing Wang Wei Zhang Center for Alloy Innovation and Design(CAID) State Key Laboratory for Mechanical Behavior of MaterialsXi’an Jiaotong UniversityXi’an 710049People’s Republic of China

In the past decade,there has been tremendous progress in integrating chalcogenide phase-change materials(PCMs)on the silicon photonic platform for non-volatile memory to neuromorphic in-memory computing *** particular,these non von Neumann computational elements and systems benefit from mass manufacturing of silicon photonic integrated circuits(PICs)on 8-inch wafers using a 130 nm complementary metal-oxide semiconductor *** manufacturing based on deep-ultraviolet lithography and electron-beam lithography enables rapid prototyping of PICs,which can be integrated with high-quality PCMs based on the wafer-scale sputtering technique as a back-end-of-line *** this article,we present an overview of recent advances in waveguide integrated PCM memory cells,functional devices,and neuromorphic systems,with an emphasis on fabrication and integration processes to attain state-of-the-art device *** a short overview of PCM based photonic devices,we discuss the materials properties of the functional layer as well as the progress on the light guiding layer,namely,the silicon and germanium waveguide ***,we discuss the cleanroom fabrication flow of waveguide devices integrated with thin films and nanowires,silicon waveguides and plasmonic microheaters for the electrothermal switching of PCMs and mixed-mode ***,the fabrication of photonic and photonic–electronic neuromorphic computing systems is *** systems consist of arrays of PCM memory elements for associative learning,matrix-vector multiplication,and pattern *** large-scale integration,the neuromorphic photonic computing paradigm holds the promise to outperform digital electronic accelerators by taking the advantages of ultra-high bandwidth,high speed,and energy-efficient operation in running machine learning algorithms.

关键词： nanofabrication silicon photonics phase-change materials non-volatile photonic memory neuromorphic photonic computing

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In situ characterization of vacancy ordering in Ge-Sb-Te phase-change memory alloys

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Fundamental Research 2024年第5期4卷 1235-1242页

作者： Ting-Ting Jiang Xu-Dong Wang Jiang-Jing Wang Han-Yi Zhang Lu Lu Chunlin Jia Matthias Wuttig Riccardo Mazzarello Wei Zhang En Ma Center for Alloy Innovation and Design(CAID) State Key Laboratory for Mechanical Behavior of MaterialsXi'an Jiaotong UniversityXi'an 710049China Institute of Physics IA RWTH Aachen UniversityAachen 52074Germany The School of Microelectronics State Key Laboratory for Mechanical Behavior of MaterialsXi'an JiaotongUniversityXi'an 710049China JARA-FIT and JARA-HPC RWTH Aachen UniversityAachen 52056Germany Peter Grünberg Institute(PGI 10) Forschungszentrum Jülich GmbHJülich 52425Germany Department of Physics Sapienza University of RomeRome 00185Italy

Tailoring the degree of structural disorder in Ge-Sb-Te alloys is important for the development of non-volatile phase-change memory and neuro-inspired *** crystallization from the amorphous phase,these alloys form a cubic rocksalt-like structure with a high content of intrinsic *** thermal annealing results in a gradual structural transition towards a layered structure and an insulator-to-metal *** this work,we elucidate the atomic-level details of the structural transition in crystalline GeSb_(2)Te_(4) by in situ high-resolution transmission electron microscopy experiments and ab initio density functional theory calculations,providing a comprehensive real-time and real-space view of the vacancy ordering *** also discuss the impact of vacancy ordering on altering the electronic and optical properties of GeSb_(2)Te_(4),which is relevant to multilevel storage *** phase evolution paths in Ge-Sb-Te alloys and Sb_(2)Te_(3)are illustrated using a summary diagram,which serves as a guide for designing phase-change memory devices.

关键词： phase-change materials Vacancy ordering Structural transition Metavalent bondingin situ TEM

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Electrically programmable phase-change photonic memory for optical neural networks with nanoseconds in situ training capability

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Advanced Photonics 2023年第4期5卷 42-50页

作者： Maoliang Wei Junying Li Zequn Chen Bo Tang Zhiqi Jia Peng Zhang Kunhao Lei Kai Xu Jianghong Wu Chuyu Zhong Hui Ma Yuting Ye Jialing Jian Chunlei Sun Ruonan Liu Ying Sun Wei.E.I.Sha Xiaoyong Hu Jianyi Yang Lan Li Hongtao Lin Zhejiang University College of Information Science and Electronic EngineeringState Key Laboratory of Modern Optical InstrumentationKey Laboratory of Micro-Nano Electronics and Smart System of Zhejiang ProvinceHangzhouChina Westlake University School of EngineeringKey Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang ProvinceHangzhouChina Institute of Advanced Technology Westlake Institute for Advanced StudyHangzhouChina Institute of Microelectronics of the Chinese Academy of Sciences BeijingChina Peking University School of PhysicsFrontiers Science Center for Nano-optoelectronicsState Key Laboratory for Mesoscopic PhysicsBeijingChina

Optical neural networks (ONNs), enabling low latency and high parallel data processing withoutelectromagnetic interference, have become a viable player for fast and energy-efficient processing andcalculation to meet the increasing demand for hash rate. Photonic memories employing nonvolatile phase-change materials could achieve zero static power consumption, low thermal cross talk, large-scale, andhigh-energy-efficient photonic neural networks. Nevertheless, the switching speed and dynamic energyconsumption of phase-change material-based photonic memories make them inapplicable for in situ ***, by integrating a patch of phase change thin film with a PIN-diode-embedded microring resonator,a bifunctional photonic memory enabling both 5-bit storage and nanoseconds volatile modulation wasdemonstrated. For the first time, a concept is presented for electrically programmable phase-changematerial-driven photonic memory integrated with nanosecond modulation to allow fast in situ training and zerostatic power consumption data processing in ONNs. ONNs with an optical convolution kernel constructedby our photonic memory theoretically achieved an accuracy of predictions higher than 95% when testedby the MNIST handwritten digit database. This provides a feasible solution to constructing large-scalenonvolatile ONNs with high-speed in situ training capability.

关键词： phase-change materials optical neural networks photonic memory silicon photonics reconfigurable photonics

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Heat Absorbing and Releasing Experiments with Improved phase-change Thermal Storage Canisters

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Chinese Journal of Aeronautics 2010年第3期23卷 306-311页

作者：徐伟强袁修干邢玉明北京航空航天大学航空科学与工程学院

This article,based on authors＇ long-term study,proposes an improved foamed-Ni-packed phase-change thermal storage canister,which takes advantage of the foamed-Ni characteristic of instinctive porous structure and excellent properties to ameliorate its void distribution and thermal conductivity. The improved canister and the unimproved one without foamed-Ni package,are put to heat absorbing and releasing tests to investigate the effects of heat absorbing temperature upon the phase-change materials （PCM） melting time under three temperature schemes by using platinum resistance thermometers （PT100） and data acquisition modules （ADAM-4000） to gather the data of varying temperature. Afterwards,the computerized tomography （CT） is employed to scan the void distribution in both canisters. Compared to the unimproved canister,the experimental results evidence the superiority of the improved one in higher uniformity in void and temperature distribution as well as faster thermal responses.

关键词： thermal storage experiment phase-change materials foamed-Ni void distribution melting time

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A self-regulated phototheranostic nanosystem with single wavelength-triggered energy switching and oxygen supply for multimodal synergistic therapy of bacterial bioﬁlm infections

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Aggregate 2024年第5期5卷 371-384页

作者： Cheng Wang Shuyi Lv Zhencheng Sun Minghui Xiao Hao Fu Liang Tian Xianhao Zhao Linqi Shi Chunlei Zhu Key Laboratory of Functional Polymer materials of Ministry of Education State Key Laboratory of Medicinal Chemical BiologyTianjin Key Laboratory of Functional Polymer MaterialsFrontiers Science Center for New Organic MatterCollege of ChemistryNankai UniversityTianjinChina Beijing National Laboratory for Molecular Sciences BeijingChina

The exploration of antibiotic-independent phototherapy strategies for the treatment of bacterial bioﬁlm infections has gained signiﬁcant ***,efﬁcient eradication of bacterial bioﬁlms remains a ***,a self-regulated pho-totheranostic nanosystem with single wavelength-triggered photothermal therapy(PTT)/photodynamic therapy(PDT)transformation and oxygen supply for multi-modal synergistic therapy of bacterial bioﬁlm infections is *** approach combines a eutectic mixture of natural phase-change materials(PCMs)and an aggregation-induced emission(AIE)phototheranostic agent TPA-ICN to form col-loidally stable nanopartcicles(***@PCM NPs).The reversible solid-liquid phase transition of PCMs facilitates the adaptive regulation of the aggregation states of TPA-ICN,enabling a switch between the energy dissipation pathways for enhanced PDT in solid PCMs or enhanced PTT in liquid ***-ally,oxygen-carrying thermoresponsive nanoparticles are also introduced to alleviate the hypoxic microenvironment of bioﬁlms by releasing oxygen upon heating by AIE@PCM NPs with enhanced *** nanosystem exhibits outstanding therapeu-tic efﬁcacy against bacterial bioﬁlms both in vitro and in vivo,with an antibacterial efﬁciency of 99.99%.This study utilizes a self-regulated theranostic nanoplatform with adaptive PTT/PDT transformation via the phase transition of PCMs and heat-triggered oxygen release,holding great promise in the safe and efﬁcient treatment of bacterial bioﬁlm infections.

关键词： bacterial bioﬁlm infections hypoxic microenvironments multimodal synergistic therapy phase-change materials phototheranostic agents

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Dynamic multifunctional all-chalcogenide metasurface filter with ultra-multiple cycles

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Advanced Photonics Nexus 2024年第5期3卷 120-129页

作者： Mingjie Zhang Zhanbo Wen Zhenqi Huang Yuanzhi Chen Minsi Lin Yue Shen Yan Li Shunyu Yao Zhen Li Zhenqiang Chen Zhaohui Li Jinan University College of Physics and Optoelectronic EngineeringGuangzhouChina Shanghai Institute of Technology School of Material Science and EngineeringShanghaiChina Sun Yat-sen University School of Electrical and Information TechnologyGuangzhouChina

Dynamically tunable metasurfaces employing chalcogenide phase-change materials(PCMs)such as Ge_(2)Sb_(2)Te_(5)alloys have garnered significant attention and research ***,the utilization of chalcogenide PCMs in dynamic metasurface devices necessitates protection,owing to their susceptibility to volatilization and *** protective layer materials such as Al_(2)O_(3),TiO_(2),and SiO_(2)present potential drawbacks including diffusion,oxidation,or thermal expansion coefficient mismatch with chalcogenide PCMs during high-temperature phase transition,severely limiting the durability of chalcogenide PCM-based *** this paper,we propose,for the first time to our knowledge,the utilization of chalcogenide glass characterized by high thermal stability as a protective material for chalcogenide *** approach addresses the durability challenge of current dynamic photonic devices based on chalcogenide PCM by virtue of their closely matched optical and thermal *** upon this innovation,we introduce an all-chalcogenide dynamic tunable metasurface filter and comprehensively simulate and analyze its *** pioneering work paves the way for the design and practical implementation of optically dynamically tunable metasurface devices leveraging chalcogenide PCMs,ushering in new opportunities in the field.

关键词： metasurface chalcogenide glass Ge_(2)Sb_(2)Te_(5) phase-change materials

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