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phase transition regulation and caloric effect

能源前沿:英文版 2023年第4期17卷 463-477页

作者： Yuan LIN Jiazheng HAO Kaiming QIAO Yihong GAO Fengxia HU Jing WANG Tongyun ZHAO Baogen SHEN Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing100190China School of Physical Sciences University of Chinese Academy of SciencesBeijing101408China Spallation Neutron Source Science Center Dongguan523803China Institute of High Energy Physics Chinese Academy of SciencesBeijing100049China School of Materials Science and Engineering University of Science and Technology BeijingBejing 100083China Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China School of Physical Sciences University of Chinese Academy of SciencesBeijing 101408China Songshan Lake Materials Laboratory Dongguan523808China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou 341000China Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo315201China

Solid state refrigeration based on caloric effect is regarded as a potential candidate for replacing vapor-compression *** methods have been proposed to optimize the refrigeration properties of caloric materials,of which single field tuning as a relatively simple way has been systemically ***,single field tuning with few tunable parameters usually obtains an excellent performance in one specific aspect at the cost of worsening the performance in other aspects,like attaining a large caloric effect with narrowing the transition temperature range and introducing *** of the shortcomings of the caloric effect driven by a single field,multifield tuning on multicaloric materials that have a coupling between different ferro-orders came into *** review mainly focuses on recent studies that apply this method to improve the cooling performance of materials,consisting of enlarging caloric effects,reducing hysteresis losses,adjusting transition temperatures,and widening transition temperature spans,which indicate that further progress can be made in the application of this ***,research on the sign of lattice and spin contributions to the magnetocaloric effect found new phonon evolution mechanisms,calling for more attention on multicaloric *** progress including improving cyclability of FeRh alloys by introducing second phases and realizing a large reversible barocaloric effect by hybridizing carbon chains and inorganic groups is described in brief.

关键词： phase transition regulation caloric effect solid state refrigeration

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