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Tin partition behavior and implications for the Furong tin ore formation associated with peralkaline intrusive granite in Hunan Province,China

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Acta Geochimica 2016年第2期35卷 138-147页

作者： Xiaoyan Hu Xianwu Bi Ruizhong Hu Guosheng Cai Youwei Chen State Key Laboratory of Ore Deposit Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guizhou Bureau of Nonferrous Metal and Nuclear Industry Geological Exploration

Tin deposits are often closely associated with granitic intrusions. In this study, we analyzed tin partition coefficients between different fluids and melts(D)as well as various crystals and melts D(D)from the Furong tin deposit associated with the Qitianling A-type granite. Our experimental results indicate that tin partition behavior is affected by the chemical compositions of fluids, melts, and minerals. Tin is prone to partitioning into the residual magma in fractional crystallization or other differential magmatic processes if the magma originated from crustal sources with high alkali content, high volatile content, and low oxygen fugacity. Highly evolved residual peralkaline granitic magma enriched in tin can lead to tin mineralization in a later stage. Furthermore, the volatiles F and Cl in the magma play important roles in tin partitioning behavior. Low F contents in the melt phase and high Cl content in the aqueous fluid phase are favorable factors for tin partitioning in the aqueous fluid phase. High Cl content in the aqueous fluid catalyzes water–rock interaction and leads to the extraction of tin from tinbearing minerals. All these findings support a hydrothermal origin for the tin deposits. In light of the geotectonic setting, petrochemical characteristics, and mineralizing physicochemical conditions of the Furong tin deposit, it is inferred that the ore-forming fluid of the Furong tin ore deposit could have derived from the Qitianling peralkaline intrusion.

关键词： Tin Partition peralkaline granite Hunan Province

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Geochemistry,Petrogenesis and Alteration of Rare-Metal-Bearing Granitoids and Mineralized Silexite of the Al-Ghurayyah Stock,Arabian Shield,Saudi Arabia

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Journal of Earth Science 2023年第5期34卷 1488-1510页

作者： Hisham A.Gahlan Mokhles K.Azer Paul D.Asimow Mansour H.Al-Hashim Department of Geology and Geophysics College of ScienceKing Saud UniversityRiyadh 11451Saudi Arabia Geological Sciences Department National Research CentreCairoEgypt Division of Geological&Planetary Sciences California Institute of TechnologyPasadena CA 91125USA

New data are presented for the rare-metal bearing A-type granitoids of the AlGhurayyah stock in the northwestern segment of the Arabian Shield, a composite pluton intruding metamorphosed volcano-sedimentary successions of the Silasia Formation. Metals in the granitoids are variably enriched, with up to 1 990 μg/g Zn, 7 680 μg/g Zr, 2 316 μg/g Nb, 232 μg/g Ta, 485 μg/g Hf, 670 μg/g Th, 137 μg/g U and 1 647 μg/g total rare earth elements(REE). The silexite is highly mineralized and yields higher maximum concentrations of several metals than the granitoids, including up to 1 860 μg/g Y, 9 400 μg/g Zr, 878 μg/g Hf, 1 000 μg/g Th, and 2 029 μg/g total REE. The Al-Ghurayyah stock has been assigned to an intraplate setting. Lithospheric delamination led to generation of mantle melts that supplied heat to melt the juvenile crust of the ANS. The fluorine and rare-metal enriched parental magma evolved by fractional crystallization. The quartz-rich silexite, distinct in character from ordinary hydrothermal vein quartz, is inferred to be co-genetic with the granitoids on the basis of their similar REE patterns;it is interpreted as a small volume of residual magma enriched in SiO2, volatiles, and trace metals. Mineralization took place both at the magmatic stage and later during a hydrothermal stage that concentrated these elements to economic grades.

关键词： Arabian Shield Al-Ghurayyah rare metals silexite peralkaline granite hydrothermal metasomatism

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