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Characteristics of remaining oil viscosity in water-and polymer-flooding reservoirs in Daqing oilfield

Science China Earth Sciences 2010年第1期53卷 72-83页

作者： XU ZhengShun,ZHANG JuHe,FENG ZiHui,FANG Wei & WANG FengLan Exploration and Development Research Institute,Daqing oilfield Company Ltd.,Daqing 163712,China Exploration and Development Research Institute Daqing Oilfield Company Ltd. Daqing China

The experimental analysis of 21 crude oil samples shows a good correlation between high molecular-weight hydrocarbon components (C 40+) and viscosity.Forty-four remaining oil samples extracted from oil sands of oilfield development coring wells were analyzed by high-temperature gas chromatography (HTGC),for the relative abundance of C 21-,C 21-C 40 and C 40+ hydrocarbons.The relationship between viscosity of crude oil and C 40+ (%) hydrocarbons abundance is used to expect the viscosity of remaining oil.The mobility characteristics of remaining oil,the properties of remaining oil,and the next displacement methods in reservoirs either water-flooded or polymer-flooded are studied with rock permeability,oil saturation of coring wells,etc.The experimental results show that the hydrocarbons composition,viscosity,and mobility of remaining oil from both polymer-flooding and water-flooding reservoirs are heterogeneous,especially the former.Relative abundance of C 21- and C 21-C 40 hydrocarbons in polymer-flooding reservoirs is lower than that of water-flooding,but with more abundance of C 40+ hydrocarbons.It is then suggested that polymer flooding must have driven more C 40- hydrocarbons out of reservoir,which resulted in relatively enriched C 40+,more viscous oils,and poorer mobility.Remaining oil in water-flooding reservoirs is dominated by moderate viscosity oil with some low viscosity oil,while polymer-flooding mainly contained moderate viscosity oil with some high viscosity oil.In each oilfield and reservoir,displacement methods of remaining oil,viscosity,and concentration by polymer-solution can be adjusted by current viscosity of remaining oil and mobility ratio in a favorable range.A new basis and methods are suggested for the further development and enhanced oil recovery of remaining oil.

关键词： remaining oil viscosity mobility ratio water-flooding polymer-flooding heterogeneity polymer-solution viscosity

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Microscopic and macroscopic atomization characteristics of a pressure-swirl atomizer, injecting a viscous fuel oil

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Chinese Journal of Chemical Engineering 2020年第1期28卷 9-22页

作者： Seyed Mohammad Ali Najafi Pouria Mikaniki Hojat Ghassemi School of Mechanical Engineering Iran University of Science and Technology(IUST)P.O.B.16765-163TehranIran

Combustion of heavy fuels is one of the main sources of greenhouse gases, particulate emissions, ashes, NOxand SOx. Gasification is an advanced and environmentally friendly process that generates combustible and clean gas products such as hydrogen. Some entrained flow gasifiers operate with Heavy Fuel oil(HFO) feedstock. In this application, HFO atomization is very important in determining the performance and efficiency of the gasifiers.The atomization characteristics of HFO(Mazut) discharging from a pressure-swirl atomizer(PSA) are studied for different pressures difference(Δp) and temperatures in the atmospheric ambient. The investigated parameters include atomizer mass flow rate( _m), discharge coefficient(CD), spray cone angle(θ), breakup length(Lb), the unstable wavelength of undulations on the liquid sheet(λs), global and local SMD(sauter mean diameter) and size distribution of droplets. The characteristics of Mazut sheet breakup are deduced from the shadowgraph technique. The experiments on Mazut film breakup were compared with the predictions obtained from the liquid film breakup model. Validity of the theory for predicting maximum unstable wavelength was investigated for HFO(as a highly viscous liquid). A modification on the formulation of maximum unstable wavelength was presented for HFO. SMD decreases by getting far from the atomizer. The measurement for SMD and θ were compared with the available correlations. The comparisons of the available correlations with the measurements of SMD andθ show a good agreement for Ballester and Varde correlations, respectively. The results show that the experimental sizing data could be presented by Rosin-Rammler distributions very well at different pressure difference and temperatures.

关键词： Gasifier Heavy fuel oil Atomization Pressure-swirl atomizer Mazut Size distribution Wavelength Viscosity

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Soft-sensing modeling and intelligent optimal control strategy for distillation yield rate of atmospheric distillation oil refining process

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Chinese Journal of Chemical Engineering 2019年第5期27卷 1113-1124页

作者： Zheng Wang Cheng Shao Li Zhu Institute of Advanced Control Technology Dalian University of Technology

It is a challenge to conserve energy for the large-scale petrochemical enterprises due to complex production process and energy diversification. As critical energy consumption equipment of atmospheric distillation oil refining process, the atmospheric distillation column is paid more attention to save energy. In this paper, the optimal problem of energy utilization efficiency of the atmospheric distillation column is solved by defining a new energy efficiency indicator - the distillation yield rate of unit energy consumption from the perspective of material flow and energy flow, and a soft-sensing model for this new energy efficiency indicator with respect to the multiple working conditions and intelligent optimizing control strategy are suggested for both increasing distillation yield and decreasing energy consumption in oil refining process. It is found that the energy utilization efficiency level of the atmospheric distillation column depends closely on the typical working conditions of the oil refining process, which result by changing the outlet temperature, the overhead temperature, and the bottom liquid level of the atmospheric pressure tower. The fuzzy C-means algorithm is used to classify the typical operation conditions of atmospheric distillation in oil refining process. Furthermore, the LSSVM method optimized with the improved particle swarm optimization is used to model the distillation rate of unit energy consumption. Then online optimization of oil refining process is realized by optimizing the outlet temperature, the overhead temperature with IPSO again. Simulation comparative analyses are made by empirical data to verify the effectiveness of the proposed solution.

关键词： Energy efficiency optimization Crude oil distillation Particle warm optimization Fuzzy C-means algorithm Working condition

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Fault-sand combination modes and hydrocarbon accumulation in Binhai fault nose of Qikou Sag, Bohai Bay Basin, East China

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Petroleum Exploration and Development 2019年第5期46卷 919-934页

作者： ZHOU Lihong HAN Guomeng DONG Yueqi SHI Qianru MA Jianying HU Jinnan REN Shichao ZHOU Kejia WANG Jincheng SI Weiliu Dagang oilfield Company PetroChinaTianjin 300280China

Based on seismic and logging data,taking the downthrow fault nose of Binhai fault in Qikou Sag as the object of study,we analyzed fault characteristics,sand body distribution,fault-sand combinations and hydrocarbon accumulation to reveal the hydrocarbon enrichment law in the fault-rich area of fault depression lake basin.The results show that the Binhai Cenozoic fault nose is characterized by east-west zoning,the main part of the western fault segment is simple in structure,whereas the broom-shaped faults in the eastern segment are complex in structure,including several groups of faults.The difference of fault evolution controls the spatial distribution of sand bodies.The sand bodies are in continuous large pieces in the downthrow fault trough belt along the Gangdong Fault in the middle segment of the fault nose,forming consequent fault-sand combination;whereas the fault activity period of the eastern part of the fault nose was later,and the sand bodies controlled by paleogeomorphology are distributed in multi-phase north-south finger-shaped pattern,forming vertical fault-sand combination pattern matching with the fault.The configuration between faults and sand bodies,and oil sources and caprocks determine the vertical conductivity,plane distribution and vertical distribution of oil and gas.Two oil and gas accumulation modes,i.***.single main fault hydrocarbon supply-fault sand consequent matching-oil accumulation in multi-layers stereoscopically and fault system transportation-fault sand vertical matching-oil accumulation in banded overlapping layers occur in the middle and eastern segments of the fault nose respectively,and they control the difference of oil and gas distribution and enrichment degree in the Binhai fault nose.

关键词： Bohai Bay Basin Qikou Sag Binhai fault nose sandstone development mechanism fault-sand combination oil and gas accumulation reservoir control mechanism

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Influence of olive oil and its components on mesenchymal stem cell biology

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World Journal of Stem Cells 2019年第12期11卷 1045-1064页

作者： Antonio Casado-Díaz Gabriel Dorado Jose Manuel Quesada-Gómez CIBER de Fragilidad y Envejecimiento Saludable(CIBERFES) Instituto Maimónides de Investigación Biomédica de Córdoba(IMIBIC)Hospital Universitario Reina SofíaCórdoba 14004Spain Departement Bioquímica y Biología Molecular Campus Rabanales C6-1-E17Campus de Excelencia Internacional Agroalimentario(ceiA3)Universidad de CórdobaCIBERFESCórdoba 14071Spain Unidad de Gestión Clínica de Endocrinología y Nutrición CIBER de Fragilidad y Envejecimiento Saludable(CIBERFES)Instituto Maimónides de Investigación Biomédica de Córdoba(IMIBIC)Hospital Universitario Reina SofíaCórdoba 14004Spain

Extra virgin olive oil is characterized by its high content of unsaturated fatty acid residues in triglycerides,mainly oleic acid,and the presence of bioactive and antioxidant compounds.Its consumption is associated with lower risk of suffering chronic diseases and unwanted processes linked to aging,due to the antioxidant capacity and capability of its components to modulate cellular signaling pathways.Consumption of olive oil can alter the physiology of mesenchymal stem cells(MSCs).This may explain part of the healthy effects of olive oil consumption,such as prevention of unwanted aging processes.To date,there are no specific studies on the action of olive oil on MSCs,but effects of many components of such food on cell viability and differentiation have been evaluated.The objective of this article is to review existing literature on how different compounds of extra virgin olive oil,including residues of fatty acids,vitamins,squalene,triterpenes,pigments and phenols,affect MSC maintenance and differentiation,in order to provide a better understanding of the healthy effects of this food.Interestingly,most studies have shown a positive effect of these compounds on MSCs.The collective findings support the hypothesis that at least part of the beneficial effects of extra virgin olive oil consumption on health may be mediated by its effects on MSCs.

关键词： Olive oil Mesenchymal stem cells Cellular differentiation Aging Cellular

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In-depth investigation on the factors affecting the performance of high oil-absorption resin by response surface method

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Chinese Journal of Chemical Engineering 2021年第5期34卷 286-296页

作者： Lei Ma Hongxia Lv Haonan Yu Lingtong Kong Rongyue Zhang Xiaoyan Guo Haibo Jin Guangxiang He Xiaoyan Liu Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology College of Chemical EngineeringBeijing Institute of Petrochemical TechnologyBeijing 102617China Water Resource Office of Jining City Shandong ProvinceJining 272019China

A series of high oil-absorption resins with low cross-linking degree were synthesized by suspension polymerization using stearyl methacrylate(SMA),2-Ethylhexyl methacrylate(EHMA),and styrene(St)as monomers.Response surface methodology(RSM)with central composite design(CCD)was also applied to determine the optimal parameters that are mainly known to affect their synthesis.Thus,the effects of the monomer mass ratio(EHMA:SMA),the rigid monomer(St)dosage,the porous agent(acetone)dosage,and their pairwise interaction on the resin's oil-absorption capacity were analyzed,highlighting PSES-R_(2) as the resin with the optimum performance.The pure oil-absorption rates of PSES-R_(2) for gasoline,diesel,and kerosene were 11.19 g·g^(-1),16.25 g·g^(-1),and 14.84 g·g^(-1),respectively,while the oil removal rates from oily wastewater were 98.82%,65.11%,and 99.63%,respectively.

关键词： oil-absorption resin Response surface method oil removal rate Waste water Absorption Polymerization

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Effect of Dietary Fatty Acids on Colon Tumorigenesis Induced by Methyl Nitrosourea in Rats

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Biomedical and Environmental Sciences 2000年第2期13卷 105-116页

作者： ZHOUSHAO－BO WANGGUI－JIE 等 InstituteofNutritionandFoodHygiene ChineseAcademyofPreventiveMedicineBeijing100050China MedicalCollege JiamusiUniversityHeilongjiang154003China

To study the effect of dietary fatty acid on the colon tumorigenesis induced by methyl nitrosourea in rats, male SD rats were fed five semi_synthetic diets composed of different proportions of beef tallow, soybean oil, alkana oil, corn oil and fish oil for 180 days. The experimental groups were injected with a solution of methyl nitrosourea in phosphate buffer intraperitoneally once a week for six weeks. The control groups were injected with phosphate buffer solution only. The incidence of colon cancer, the avergage volume of the tumors, proliferation cell nuclear antigen, cell kinetics, membrane lipid fluidity, alkaline phosphatase activities and the content of prostaglandin E\-2 in colon mucosa and the fatty acid of testis pad fat were measured at the end of the experiment. The results showed that the incidence of colon cancer and the average volume of tumors in animals fed with diets composed mainly of beef tallow, soybean oil or alkana oil were significantly higher than those that were fed fish oil. The most effective anticancer diet in our study contained saturated fatty acid, monounsaturated fatty acid and polyunsaturated fatty acid of fish oil in the proportion of 13.9%, 16 4% and 68.8% respectively. Inhibition of colon tumorigenesis appeared to be related to the regulation of membrane lipid fluidity, and a decrease in the proliferation of cell nuclear antigen in colon cells. In addition, a decrease was noted in the number of cells in S phase and alkaline phosphatase activity, along with inhibition of arachidonic acid products and a corresponding decrease in the amount of prostaglandin E\-2.

关键词： CELL NUCLEAR ANTIGEN F344 RATS CARCINOGENESIS CANCER oil INHIBITION PROMOTION OMEGA-3 GROWTH RISK

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Synthesis and characterization of poppy seed oil methyl esters

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Chinese Journal of Chemical Engineering 2016年第8期24卷 1087-1096页

作者： Umer Rashid Muhammad Ibrahim Imededdine Arbi Nehdi Saud Ibrahim Al-Resayes Sammi Ullah Muhammad Aamer Mehmood Saira Shahzadi Institute of Advanced Technology Universiti Putra Malaysia Chemistry Department College of Science King Saud University Department of Environmental Sciences & Engineering Faculty of Engineering Government College University Faisalabad Department of Chemistry Government College University Faisalabad Department of Bioinformatics & Biotechnology Government College University Faisalabad Department of Chemistry Quaid-i-Azam University

Response surface methodology(RSM) was used to determine the optimum conditions of the methanolysis of crude poppy seed oil using Na OCH3 as catalyst. The experiments were run according to five levels, four variable central composite rotatable design(CCRD) using RSM. The reaction variables, i.e., molar ratio of methanol/oil(3:1–9:1), catalyst concentration(0.5 wt%–1.25 wt% Na OCH3), reaction temperature(25–65 °C), and reaction time(20–90 min) were studied. We demonstrated that the molar ratio of methanol/oil, catalyst concentration,and reaction temperature were the significant parameters affecting the yield of poppy seed oil methyl esters(PSOMEs). The optimum transesterification reaction conditions, established using the RSM, which offered a89.35% PSOME yield, were found to be 7.5:1 molar ratio of methanol/oil, 0.75% catalyst concentration, 45 °C reaction temperature, and 90 min reaction time. The proposed process provided an average biodiesel yield of more than 85%. A linear correlation was constructed between the observed and predicted values of the yield.The gas chromatography(GC) analyses have shown that PSOMEs contain linoleic-, oleic-, palmitic-, and stearic-acids as main fatty acids. The FTIR spectrum of the PSOMEs was also analyzed to confirm the completion of the transesterification reaction. The fuel properties of the PSOMEs were discussed in light of biodiesel standards(ASTM D 6751 and EN 14214).

关键词： Poppy oil Optimization Gas chromatography FTIR Fuel properties

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Trend judgment of abandoned channels and fine architecture characterization in meandering river reservoirs: A case study of Neogene Minhuazhen Formation NmⅢ2 layer in Shijiutuo bulge, Chengning uplift, Bohai Bay Basin, East China

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Petroleum Exploration and Development 2019年第5期46卷 943-953页

作者： NIU Bo ZHAO Jiahong FU Ping LI Junjian BAO Zhidong HU Yong SU Jinchang GAO Xingjun ZHANG Chi YU Dengfei ZANG Dongsheng LI Min College of Geosciences China University of PetroleumBeijing 102249China Research Institute of Exploration and Development PetroChina Jilin Oilfield CompanySongyuan 138001China No.5 oil Production Plant PetroChina Changqing Oilfield CompanyXi’an 710020China Bohai oilfield Research Institute CNOOC Tianjin CompanyTianjin 300452China PetroChina Research Institute of Petroleum Exploration&Development Beijing 100083China

Based on well logging responses,sedimentary patterns and sandstone thickness,the distribution characteristics of meandering river sedimentary sand body of Neogene Minghuazhen Formation NmⅢ2 layer in the west of Shijiutuo Bulge,Chengning Uplift,Bohai Bay Basin were investigated.A new approach to calculate the occurrence of the sand-mudstone interfaces using resistivity log of horizontal well was advanced to solve the multiple solution problem of abandoned channel’s orientation.This method uses the trigonometric function relationship between radius,dip and length of the resistivity log to calculate the occurrence qualitatively-quantitatively to help determine the true direction of the abandoned channels.This method can supplement and improve the architecture dissection technique for meandering river sandbodies.This method was used to study the dip angle and scale of the lateral accretion layers in point bar quantitatively to help determine the spatial distribution of lateral accretion layers.The fine architecture model of underground meandering river reservoir in the study area has been established.Different from traditional grids,different grid densities for lateral accretion layers and bodies were used in this model by non-uniform upscaling to establish the inner architecture model of point-bars and realize industrial numerical simulation of the whole study area.The research results can help us predict the distribution of remaining oil,tap remaining oil,and optimize the waterflooding in oilfields.

关键词： Bohai Bay Basin meandering river horizontal well resistivity curve lateral accretion layers lateral accretion bodies architecture modeling remaining oil distribution

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Advances in the application of biomimetic surface engineering in the oil and gas industry

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Friction 2019年第4期7卷 289-306页

作者： Yanbao GUO ,Zheng ZHANG Siwei ZHANG College of Mechanical and Transportation Engineering China University of PetroleumBeijing 102249China State Key Laboratory of Petroleum Resources and Prospecting Beijing 102249China

Friction is widespread in almost every field in the oil and gas industry,and it is accompanied by huge energy losses and potential safety hazards.To deal with a series of questions in this regard,biomimetic surfaces have been developed over the past decades to significantly reduce economic losses.Presently,biomimetic surface engineering on different scales has been successfully introduced into related fields of the oil and gas industry,such as drill bits and the inner surfaces of pipes.In this review,we focused on the most recent and promising efforts reported toward the application of a biomimetic surface in oil and gas fields,indicating the necessity and importance of establishing this disciplinary study.Regarding the oil and gas industry,we mainly analyzed and summarized some important research results into the following three aspects:(i)applications in reducing the wear of exploration production equipment and its components,(ii)separation and drag release technologies in oil/gas storage and transportation,and(iii)functional coatings used in oil and gas development in oceans and polar regions.Finally,based on an in‐depth analysis of the development of biomimetic surface engineering in the fields of oil and gas,some conclusions and perspectives are also discussed.It is expected that biomimetic surface engineering can be used in oil and gas fields more widely and systematically,providing important contributions to green development in the near future.

关键词： friction and wear biomimetic surface engineering oil and gas industry

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