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Influence of cathode Modification by Chitosan and Fe^(3+)on the Electrochemical Performance of Marine Sediment Microbial Fuel Cell

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Journal of Ocean University of China 2023年第3期22卷 709-716页

作者： ZAI Xuerong GUO Man HUANG Xiang ZHANG Huaijing CHEN Yan JI Hongwei FU Yubin School of Materials Science&Engineering Ocean University of ChinaQingdao 266100China College of Chemistry and Chemical Engineering Ocean University of ChinaQingdao 266100China College of Marine Geosciences Ocean University of ChinaQingdao 266100China

The electrochemical performances of cathode play a key role in the marine sediment microbial fuel cells(MSMFCs)as a long lasting power source to drive instruments,especially when the dissolved oxygen concentration is very low in seawater.A CTS-Fe^(3+)modified cathode is prepared here by grafting chitosan(CTS)on a carbon fiber surface and then chelating Fe^(3+)through the coordination *** electrochemical performance in seawater and the output power of the assembled MSMFCs are both *** results show that the exchange current densities of CTS and the CTS-Fe^(3+)group are 5.5 and 6.2 times higher than that of the blank group,*** potential of the CTS-Fe^(3+)modified cathode increases by 138 *** output power of the fuel cell(613.0 mW m^(-2))assembled with CTS-Fe^(3+)is 54 times larger than that of the blank group(11.4 mW m^(-2))and the current output corresponding with the maximum power output also increases by 56 *** to the valence conversion between Fe^(3+)and Fe^(2+)on the modified cathode,the kinetic activity of the dissolved oxygen reduction is accelerated and the depolarization capability of the cathode is enhanced,resulting higher cell *** the basis of this study,the new cathode materials will be encouraged to design with the complex of iron ion in natural seawater as the catalysis for oxygen reduction to improve the cell power in deep sea.

关键词： marine sediments microbial fuel cell chitosan and iron chelation modified cathode electrochemical performance power output

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Removal of refractory organics and heavy metals in landfill leachate concentrate by peroxi-coagulation process

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Journal of Environmental Sciences 2022年第6期34卷 43-51页

作者： Dun Liu Ying Yuan Yuquan Wei Hao Zhang Yanxiao Si Fang Zhang School of Environment and State Key Joint Laboratory of Environment Simulation and Pollution Control Tsinghua UniversityBeijing 100084China Beijing Advanced Innovation Center for Big Data-based Precision Medicine Beihang UniversityBeijing 100191China

Landfill leachate is a complex effluent and it is difficult to deal with. Electrochemical methods have been considered as a promising alternative technology for treatment of landfill leachate with refractory organic contaminants and heavy metals. Peroxi-coagulation(PC)process with iron anode and modified graphite felt cathode was developed for efficient landfill leachate concentrate treatment. Compared to electro-Fenton(EF) and electrocoagulation(EC) processes, the PC process was more cost-effective due to the combined action of·OH oxidation and iron hydroxides coagulation. A maximal TOC removal of 77.2% ± 1.4% was obtained after 360 min at initial p H = 5.0 and current density of 10 m A/cm^(2). After the PC process, concentrations of all seven heavy metals in the final effluents were below the allowable emission limits given by the present regulatory standards. The method preference for heavy metal removal was PC > EC > EF. Based on the three-dimensional fluorescence spectroscopy coupled with regional integration analysis during the PC treatment, the florescence peaks of both humic acids and fulvic acids disappeared after treatment for 360min. Decreasing trends were observed in the fluorescent regional standard volumes for aromatic protein Ⅰ(31.4%), aromatic protein Ⅱ(63.7%), fulvic acid-like(69.5%), soluble microbial by-product-like(75%) and humic acid-like regions(76.3%). The results indicate that comparing to the EF and EC process, the PC process provide a promising and more cost-effective alternative for the treatment of landfill leachate concentrate.

关键词： Landfill leachate Peroxi-coagulation Electro-Fenton Electrocoagulation modified cathode

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