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Conversion of Biomass to Hydrocarbon-rich Bio-oil via microwave-assisted Catalytic Pyrolysis： A Review

China Petroleum Processing & Petrochemical Technology 2018年第3期20卷 7-16页

作者： Wang Yunpu Zhang Shumeil Yu Zhenting Jiang Lin Liu Yuhuan Ruan Roger Fu Guiming Nanchang University State Key Laboratory of Food Science and Technology Nanchang 330047 Nanchang University Engineering Research Center for Biomass Conversion Ministry of Education Nanchang 330047 Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development Guangzhou 510640 Center for Biorefining and Department of Bioproducts and Biosystems Engineering University of Minnesota USA

The method for pyrolysis of biomass to manufacture hydrocarbon-rich fuel remains challenging in terms of conversion of multifunctional biomass with high oxygen content and low thermal stability into a high-quality compound, featuring high content of hydrocarbons, low oxygen content, few functional groups, and high thermal stability. This study offers a promising prospect to derive hydrocarbon-rich oil through microwave-assisted fast catalytic pyrolysis by improving the effective hydrogen to carbon ratio(H/Ceff) of the raw materials. The proposed technique can promote the production of high-quality bio-oil through the molecular sieve catalyzed reduction of oxygenated compounds and mutagenic polyaromatic hydrocarbons. This work aims to review and summarize the research progress on microwave copyrolysis and microwave catalytic copyrolysis to demonstrate their benefits on enhancement of bio-oils derived from the biomass. This review focuses on the potential of optimizing the H/Ceff ratio, the microwave absorbent, and the HZSM-5 catalyst during the microwave copyrolysis to produce the valuable liquid fuel. This paper also proposes future directions for the use of this technique to obtain high yields of bio-oils.

关键词： biomass microwave pyrolysis H/Ceff microwave absorbent HZSM-5 catalyst hydrocarbon-rich bio-oil

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