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Petroleum Research 2023年第2期8卷 151-166页

作者： Siqi Liu Hu Jia Hongshen Wang Yanbin Liang Duansheng Shi Zhichong Lu Junyi Wu State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengduChina CNOOC Energy Technology&Services Limited Engineering Technology BranchTianjinChina Oil Production Technology Institute of PetroChina Dagang Oilfield Company TianjinChina

The reservoir heterogeneity of Suizhong 36-1 oilfield is very obvious,the average permeability reaches 2000mD.Long-term water injection development leads to serious water channeling in high permeability layers,resulting in ineffective circulation of injected water and reduction of oil recovery.It is urgent to form an effective EOR method.In this paper,the oil displacement effect of different combination slugs including polymer gel,polymer microsphere and surfactant is evaluated by means of conformance control and chemical flooding.Three-layer heterogeneous 3-D plate model is used for oil displacement experiment.The experimental results show that the combination slug sequentially composed of polymer gel,polymer microspheres and surfactant have the best oil displacement effect with the oil recovery increment by 21.2% after the first water flooding.In addition,using the best slug combination for two rounds flooding,the recovery factor increased by 28.2% compared with the first water flooding.This paper provides some new insights for enhanced oil recovery in strong heterogeneity reservoir.

关键词： Heterogeneity reservoir EOR Polymer gel microsphere Surfactant Combined slug

microsphere femtosecond laser sub-50 nm structuring in far field via non-linear absorption

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Opto-Electronic Advances 2023年第6期6卷 8-17页

作者： Zhenyuan Lin Kuan Liu Tun Cao Minghui Hong Pen-Tung Sah Institute of Micro-Nano Science and Technology Xiamen UniversityXiamen 361102China School of Optoelectronic Engineering and Instrumentation Science Dalian University of TechnologyDalian 116024China Department of Electrical and Computer Engineering National University of Singapore4 Engineering Drive 3117576Singapore

Creation of arbitrary features with high resolution is critically important in the fabrication of nano-optoelectronic devices.Here,sub-50 nm surface structuring is achieved directly on Sb2S3 thin films via microsphere femtosecond laser irradi-ation in far field.By varying laser fluence and scanning speed,nano-feature sizes can be flexibly tuned.Such small patterns are attributed to the co-effect of microsphere focusing,two-photons absorption,top threshold effect,and high-repetition-rate femtosecond laser-induced incubation effect.The minimum feature size can be reduced down to~30 nm(λ/26)by manipulating film thickness.The fitting analysis between the ablation width and depth predicts that the feature size can be down to~15 nm at the film thickness of~10 nm.A nano-grating is fabricated,which demonstrates desirable beam diffraction performance.This nano-scale resolution would be highly attractive for next-generation laser nano-lithography in far field and in ambient air.

关键词： non-linear effect microsphere femtosecond laser far field

A New Method for Ultra-sensitive P24 Antigen Assay Based on Near-infrared Fluorescent microsphere Immunochromatography

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Biomedical and Environmental Sciences 2020年第3期33卷 174-182页

作者： WANG Qi HOU Mei Ling LIU Li Peng MA Jing ZHANG Xiao Guang ZHOU Zhi Xiang CAO Yu Xi Beijing University of Technology College of Life Science and BioengineeringBeijing 100124China Beijing Runbio Biotechnology Development Co. LtdBeijing 100106China National Institute for Viral Disease Control and Prevention Chinese Center for Disease Control and PreventionBeijing 102206China

Objective To develop a rapid,highly sensitive quantitative method for detecting P24 antigen based on near-infrared fluorescent microsphere immunochromatography.Methods First,we prepared a lateral flow assay test strip,and labeled the detection antibody using a fluorescent microsphere.Second,we optimized the antibody labeling conditions.Third,we optimized the detection conditions.Fourth,we created a working curve.Fifth,we conducted a methodological assessment of the established fluorescent microsphere immunochromatography method.Sixty-six clinical samples were tested,and we compared the established fluorescent microsphere immunochromatography with the quantitative ELISA method.Results According to the working curve,the detection limit of the method is 3.4 pg/mL,and the detection range is 3.4 pg/mL to 10 ng/mL.The average intra-assay recovery was 99.6%,and the Coefficient of Variation(CV)was 5.4%–8.6%;the average inter-assay recovery was 97.3%,and the CV was 8.5%–11%.The detection rate of fluorescent microsphere immunochromatography was higher than ELISA method,and had a good correlation with ELISA.Conclusion The P24 antigen quantitative detection method based on near-infrared fluorescent microsphere immunochromatography has the advantages of rapid detection,high sensitivity,and wide detection range;thus,it is suitable for early clinical diagnosis and continuous monitoring of AIDS.

关键词： Fluorescent microsphere immunochromatography HIV P24 antigen POCT

Designing soft/hard double network hydrogel microsphere/UHMWPE composites to promote water lubrication performance

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Friction 2021年第3期9卷 551-568页

作者： Chaobao WANG Xiuqin BAI Conglin DONG Zhiwei GUO Chengqing YUAN Anne NEVILLE School of Energy and Power Engineering Wuhan University of TechnologyWuhan 430063China Key Laboratory of Marine Power Engineering&Technology(Ministry of Transport) Wuhan University of TechnologyWuhan 430063China Institute of Functional Surfaces School of Mechanical EngineeringUniversity of LeedsLeeds LS29JTUnited Kingdom

Several soft tissues residing in the living body have excellent hydration lubrication properties and can provide effective protection during relative motion.In order to apply this advantage of soft matters in practical applications and try to avoid its disadvantage,such as swelling and weakening in water,a design strategy of a soft/hard double network(DN)hydrogel microsphere modified ultrahigh molecular weight polyethylene(UHMWPE)composite is proposed in this study.A series of microspheres of urea-formaldehyde(UF),polyacrylamide(PAAm)hydrogel,UF/PAAm double network,and their composites were prepared.The mechanical properties,swelling,wettability,friction properties,and the lubrication mechanisms of the composites were investigated.The results show that DN microspheres can have an excellent stability and provide hydration lubrication.The performance of 75 DN-1 composite was superior to others.This finding will provide a novel strategy for the development of water-lubricated materials and have wide application in engineering fields.

关键词： double network microsphere composite friction properties hydration lubrication

Unveiling nanoplates-assembled Bi2MoO6 microsphere as a novel anode material for high performance potassium-ion batteries

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Nano Research 2020年第10期13卷 2650-2657页

作者： Junxian Hu Yangyang Xie Jingqiang Zheng Yanqing Lai Zhian Zhang School of Metallurgy and Environment Central South Universityy Changsha 410083China

Bismuth (Bi)-based electrode has aroused tremendous interest in potassium-ion batteries (PIBs) on account of its low cost, high electronic conductivity, low charge voltage and high theoretical capacity. However, the rapid capacity fading and poor lifespan induced by the normalized volume expansion (up to ~ 406%) and serious aggregation of Bi during cycling process hinder its application. Herein, bismuth molybdate (Bi2MoO6) microsphere assembled by 2D nanoplate units is successfully prepared by a facile solvothermal method and demonstrated as a promising anode for PIBs. The unique microsphere structure and the self-generated potassium molybdate (K-Mo-O species) during the electrochemical reactions can effectively suppress mechanical fracture of Bi-based anode originated from the volume variation during charge/discharge of the battery. As a result, the Bi2MoO6 microsphere without hybridizing with any other conductive carbon matrix shows superior electrochemical performance, which delivers a high reversible capacity of 121.7 mAh·g^−1 at 100 mA·g^−1 over 600 cycles. In addition, the assembled perylenetetracarboxylic dianhydride (PTCDA)//Bi2MoO6 full-cell coupled with PTCDA cathode demonstrates the potential application of Bi2MoO6 microsphere. Most importantly, the phase evolution of Bi2MoO6 microsphere during potassiation/depotassiation process is successfully deciphered by ex situ X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), and transmission electron microscopy (TEM) technologies, which reveals a combination mechanism of conversion reaction and alloying/dealloying reaction for Bi2MoO6 anode. Our findings not only open a new way to enhance the performance of Bi-based anode in PIBs, but also provide useful implications to other alloy-type anodes for secondary alkali-metal ion batteries.

关键词： Bi2MoO6 microsphere potassium ion batteries mechanism anode

KHCO_3 activated carbon microsphere as excellent electrocatalyst for VO^(2+)/VO_2^+ redox couple for vanadium redox flow battery

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Journal of Energy Chemistry 2019年第2期28卷 103-110页

作者： Chen Zhao Yuehua Li Zhangxing He Yingqiao Jiang Lu Li Fengyun Jiang Huizhu Zhou Jing Zhu Wei Meng Ling Wang Lei Dai School of Chemical Engineering North China University of Science and Technology State Key Laboratory Breeding Base of Nuclear Resources and Environment East China University of Technology Hebei Province Key Laboratory of Photocatalytic and Electrocatalytic Materials for Environment North China University of Science and Technology

In this paper,carbon microsphere prepared by hydrothermal treatment was activated by KHCO_3 at high temperature,and employed as the catalyst for VO^(2+)/VO_2^+redox reaction for vanadium redox flow battery(VRFB).Carbon microsphere can be etched by KHCO_3 due to the reaction between the pyrolysis products of KHCO_3 and carbon atoms.Moreover,KHCO_3 activation can bring many oxygen functional groups on carbon microsphere,further improving the wettability of catalyst and increasing the active sites.The electrocatalytic properties of carbon microsphere from hydrothermal treatment are improved by high temperature carbonization,and can further be enhanced by KHCO_3 activation.Among carbon microsphere samples,the VO^(2+)/VO_2^+redox reaction exhibits the highest electrochemical kinetics on KHCO_3 activated sample.The cell using KHCO_3 activated carbon microsphere as the positive catalyst demonstrates higher energy efficiency and larger discharge capacity,especially at high current density.The results reveal that KHCO_3 activated carbon microsphere is an efficient,low-cost carbon-based catalyst for VO^(2+)/VO_2^+redox reaction for VRFB system.

关键词： Energy storage Vanadium redox flow battery Carbon microsphere KHCO3 Etching

Super-resolution imaging of low-contrast periodic nanoparticle arrays by microsphere-assisted microscopy

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Chinese Physics B 2021年第4期30卷 193-197页

作者：石勤芳杨松林曹玉蓉王晓晴陈涛叶永红 Department of Physics Nanjing Normal UniversityNanjing 210023China Advanced Photonics Center Southeast UniversityNanjing 210096China Jiangsu Provincial Key Laboratory of Advanced Robotics Soochow UniversitySuzhou 215123China

We use the label-free microsphere-assisted microscopy to image low-contrast hexagonally close-packed polystyrene nanoparticle arrays with diameters of 300 and 250 nm.When a nanoparticle array is directly placed on a glass slide,it cannot be distinguished.If a 30-nm-thick Ag film is deposited on the surface of a nanoparticle array,the nanoparticle array with nanoparticle diameters of 300 and 250 nm can be distinguished.In addition,the Talbot effect of the 300-nm-diameter nanoparticle array is also observed.If a nanoparticle sample is assembled on a glass slide deposited with a 30-nm-thick Ag film,an array of 300-nm-diameter nanoparticles can be discerned.We propose that in microsphere-assisted microscopy imaging,the resolution can be improved by the excitation of surface plasmon polaritons(SPPs) on the sample surface or at the sample/substrate interface,and a higher near-field intensity due to the excited SPPs would benefit the resolution improvement.Our study of label-free super-resolution imaging of low-contrast objects will promote the applications of microsphere-assisted microscopy in life sciences.

关键词： super-resolution microsphere optical microscopy surface plasmon polariton

Porous polymer microsphere functionalized with benzimidazolium based ionic liquids as effective solid catalysts for esterification

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Chinese Journal of Chemical Engineering 2019年第10期27卷 2455-2466页

作者： Xiaomei Ling Yiwei Xie Xiaocheng Lin Ling Li Ting Qiu School of Chemical Engineering Fuzhou UniversityFuzhou 350116FujianChina

To prepare polymer supported ionic liquids(PSILs)as effective catalysts for esterification,the free radical suspension copolymerization of vinylbenzyl chloride(VBC,monomer),styrene(St,monomer)and divinylbenzene(DVB,crosslinker)with the addition of n-heptane(porogen)was carried out for the fabrication of the porous polymer(PVD)microsphere as support,followed by the immobilization of sulfonic acid-functionalized ionic liquids by the successive treatment of benzimidazole(BIm),1,3-propane sultone and sulfuric acid(H2SO4)or trifluoromethanesulfonic acid(CF3SO3H).The effects of the compositions of DVB and n-heptane on the internal structure of the polymer supports were investigated,and it was found that the support with 40 wt%DVB and 60 wt%n-heptane(with relative to the monomer)could endow the final PSILs with the relatively optimal catalytic performance.The preliminary experiment in the batch reactor indicated that PSILs herein exhibited higher catalytic activities than commercial Amberlyst 46 resin for the esterification of propanoic acid(PROAc)with n-propanol(PROOH).Consequently,the optimal PSILs catalyst,PVD-[Bim-SO3H]HSO4,was selected for further study in the batch reactive distillation column because of low cost and its ease of preparation.The yield of propyl ropionate(PROPRO)could reach up to 97.78%at the optimized conditions of PROOH/PROAc molar ratio(2:1)and catalyst dosage(2.0 wt%).The investigation of the reaction kinetic manifested that the calculated results of second order pseudo-homogeneous kinetic model were in good agreement with experimental values.The pre-exponential factor and activation energy were 4.12×107 L·mol-1·min-1 and 60.57 k J·mol-1,respectively.It is worth noting that the PSILs catalyst could be simply recovered and reused with relatively satisfactory decrease in the catalytic activity,which made it an environmental friendly and promising catalyst in the industrial application.

关键词： Supported ionic liquids Porous polymer microsphere Copolymerization Esterification Reactive distillation

Hydrothermal Synthesis of Polyoxovanadate-based MOFs microsphere as Supercapacitor

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Chinese Journal of Structural Chemistry 2019年第4期38卷 581-586页

作者：朱梅花吴屹伟郭鸿旭 College of Chemistry and Environment Minnan Normal University

Polyoxovanadate-based MOFs microsphere electrode material, [Ni_2(4,4?-bipyridine)_3(H_2O)_2V_4O_(12)]·2.5 H_2O, was synthesized through a simple hydrothermal method, and then characterized through FT-IR, XRD and SEM. Electrochemical properties of the sample as supercapacitor electrodes in aqueous electrolyte were developed and studied by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. Results showed that a high specific capacitance of 152.36 F g^(-1) at current density of 1 A g^(-1) in 2 M KOH electrolyte, and 97.62% retention after 2500 charge-discharge cycles at current density of 4 A g^(-1), which is promising for applications in supercapacitors.

关键词： polyoxovanadate microsphere supercapacitor electrode material

Shape-tailorable amine grafted silica aerogel microsphere for CO_(2) capture

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Green Chemical Engineering 2020年第2期1卷 140-146页

作者： Xing Jiang Jian Ren Yong Kong Zhiyang Zhao Xiaodong Shen Maohong Fan College of Materials Science and Engineering Nanjing Tech UniversityNanjing210009PR China Department of Chemical and Petroleum Engineering University of WyomingLaramieWY82071USA Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites Nanjing210009PR China School of Civil and Environmental Engineering Georgia Institute of TechnologyAtlantaGA30332USA Suqian Advanced Materials Industry Technology Innovation Center of Nanjing Tech University Suqian223800PR China

The purpose of this study was to prepare a proof-of-concept CO_(2) adsorbing material based on a new amine grafted silica aerogel microsphere(AGSAM)that could be used on both fixed and fluidized beds.A low-cost water glass and environment-friendly water were used as precursor and solvent of the silica aerogel,respectively.The silica aerogel microsphere(SAM)was prepared by dropping the siliceous solution into hot oil bath.The effect of the pH value of the siliceous solution,stirring speed and stirring paddle position on the sphericity and size of the SAM was investigated.The SAM with good sphericity was obtained when the pH value was 5.69–5.79.The mean diameter of the SAM decreased from 5 to 1 mm when the stirring speed increased from 1000 to 2000 rpm.The SAM with excellent sphericity was prepared when the paddle was placed on the top of the oil bath.When the paddle was placed at the middle and bottom of the oil bath,some liquid drops aggregated together and formed large aggregations.AGSAM was obtained by grafting the amine groups onto the framework of the silica gel microsphere.The CO2 adsorption capacity of the AGSAM was 1.04 mmol g^(-1) with 1%CO2 at 300 mL min^(-1).The AGSAM with 4,3.2,2 and 1 mm in diameters had the fluidizing velocities of 0.531,0.425,0.265 and 0.159 m s^(-1),respectively.The AGSAM with different sizes met different fluidizing conditions.

关键词： Silica aerogel microsphere Amine grafting CO_(2)adsorption