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The Effect of Rare Earth on the Activity of methanol synthesis catalyst

Chinese Chemical Letters 1999年第8期10卷 691-692页

作者： Hong Tao MA Guo Cai DENG Xian Zhi GUO Run Ti CHEN (Department of Chemistry. Nankai University, Tianjin 300071) Nankai Univ Dept Chem Tianjin 300071 Peoples R China

In this paper several rare earth oxides were added into methanol synthesis catalyst by solid-mixing method to improve the activity of methanol synthesis catalyst. Nd2O3, CeO2, La2O3 and Sm2O3 decrease the catalyst act... 详细信息

关键词： rare earth methanol synthesis catalyst

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Effect of Cu-ZnO-Al_2O_3 supported on H-ferrierite on hydrocarbons formation from CO hydrogenation

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Chinese Journal of Catalysis 2016年第3期37卷 378-388页

作者： J.H.Flores M.E.H.Maia da Costa M.I.Pais da Silva 里约热内卢天主教大学生物化学系里约热内卢天主教大学物理系

methanol synthesis catalysts based on Cu, Zn and Al were prepared by three methods and subsequently mixed with H-ferrierite zeolite in an aqueous suspension to disperse the catalysts over the support. These materials were characterized by X-ray diffraction, N2 adsorption, transmission electron microscopy, temperature programmed reduction, NH3 and H2 temperature-programmed desorption, and X-ray photoelectron spectroscopy. They were also applied to the CO hydrogenation reaction to produce dimethyl ether and hydrocarbons. The catalysts were prepared by coprecipitation under low and high supersaturation conditions and by a homogeneous precipitation method. The preparation technique was found to affect the precursor structural characteristics, such as purity and crystallinity, as well as the particle size distribution of the resulting catalyst. Low supersaturation conditions favored high dispersion of the Cu species, increasing the methanol synthesis catalyst＇s metallic surface area and resulting in a homogeneous particle size distribution. These effects in turn were found to modify the zeolite properties, promoting both a low micropore volume and blockage of the zeolite acid sites. The effect of the methanol synthesis catalyst on the reaction was verified by the correlation between the Cu surface area and the CO conversion rate.

关键词： methanol synthesis catalyst Low supersaturation precipitation High supersaturation precipitation Syngas Hydrotalcite Hydrocarbon Dimethyl ether

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