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macroporous and Antibacterial Hydrogels Enabled by Incorporation of Mg-Cu Alloy Particles for Accelerating Skin Wound Healing

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Acta Metallurgica Sinica(English Letters) 2022年第5期35卷 853-866页

作者： Jiewei Yin Pengcheng Xu Kang Wu Huan Zhou Xiao Lin Lili Tan Huilin Yang Ke Yang Lei Yang College of Chemistry Chemical Engineering and Materials ScienceOrthopedic InstituteSoochow UniversitySuzhou215006China Department of Orthopaedics The First Affiliated HospitalSoochow UniversitySuzhou215006China Center for Health Science and Engineering(CHSE) School of Health Sciences and Biomedical EngineeringHebei University of TechnologyTianjin300130China Institute of Metal Research Chinese Academy of SciencesShenyang110016China

Repair of severe skin tissue injury remains a great challenge and wound infection is still a formidable problem.In this study,new macroporous and antibacterial gelatin/alginate(SAG)-based hydrogels for wound repair were designed and developed based on in-situ gas foaming method and ion release strategy as a result of Mg-Cu particles degradation in the hydrogel matrix.The addition of Mg-Cu particles decreased the storage modulus of SAG,maintained its mechanical resilience and enhanced its water-absorbing capability.Moreover,the water vapor transmission rate of SAG added with 2 wt.%Mg-Cu(SAG-2 MC)was 124%of that of medical gauze and 804%of commercial Tegaderm^(TM)film dressing.The bacterial inhibition rates of SAG-2 MC against S.aureus.E.coli and P.aeruginosa reached 99.9%±0.1%,98.7%±1.2%and 98.0%±0.7%,respectively,significantly greater than those of the SAG hydrogel and Mg particle-modified hydrogels.In addition,SAG-2 MC hydrogel was biocompatible and promoted cell migration.In vivo experiment results indicated that SAG-2 MC significantly accelerated the skin wound healing in murine model as demonstrated by higher epidermis thickness,more collagen deposition and enhanced angiogenesis compared with SAG-OMC,SAG-2 M and TegadermTM film.In summary,Mg-Cu particles have great potential to modulate the physiochemical and biological properties of SAG hydrogels.Mg-Cu particle-modified SAG hydrogels reveal significant promise in the treatment of severe skin wound or other soft tissue lesions.

关键词： Mg-Cu alloy Wound repair macroporous Hydrogel Bacterial inhibition

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A macroporous Cryogel with Enhanced Mechanical Properties for Osteochondral Regeneration In vivo

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Chinese Journal of Polymer Science 2023年第1期41卷 40-50页

作者： Xin-Yu Wu Jun Yang Fang-Hui Wu Wang-Bei Cao Tong Zhou Zhao-Yi Wang Chen-Xi Tu Zhong-Ru Gou Lei Zhang Chang-You Gao Ministry of Education Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou310027China Department of Orthopaedics the Third Hospital Affiliated to Wenzhou Medical University&Rui’an People’s HospitalRui’an325200China Bio-nanomaterials and Regenerative Medicine Research Division Zhejiang-California International Nanosystem InstituteZhejiang UniversityHangzhou310058China

The dense networks of conventional hydrogel hinder the efficient cell penetration and thus tissue regeneration.In this study,a macroporous cryogel with excellent mechanical properties was designed and fabricated through cryogelation and crosslinking of methacrylated gelatin(Gel-MA)and gelatin grafted with 2-ureido-4[1H]-6-methyl-pyrimidinone(Gel-UPY).The successful modification of the two functional units on the side chain of gelatin was confirmed by ^(1)H-NMR and infrared spectroscopy.The macroporous structure of cryogel was verified by scanning electron microscopy and confocal microscopy.The compressive modulus of cryogel(110 kPa)was 2 magnitudes higher than that of the conventional hydrogel of the same chemical compositions(8 kPa).Both the hydrogel and cryogel exhibited excellent stress-recovery ability.The cryogel could well maintain the viability of chondrocytes and facilitated their migration into the scaffold interior.After being implanted into osteochondral defects in rabbits for 12 w,the Gel-MA/Gel-UPY cryogel better facilitated the regeneration of upper cartilage and subchondral bone compared to the conventional hydrogel.

关键词： macroporous Cryogel Gelatin Ureido pyrimidinone Osteochondral regeneration

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macroporous Ni foam-supported Co_3O_4 nanobrush and nanomace hybrid arrays for high-efficiency CO oxidation

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Journal of Environmental Sciences 2019年第1期31卷 136-144页

作者： Shengpeng Mo Hui He Quanming Ren Shuangde Li Weixia Zhang Mingli Fu Limin Chen Junliang Wu Yunfa Chen Daiqi Ye School of Environment and Energy South China University of Technology State Key Laboratory of Multi-phase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control (SCUT) Guangdong Provincial Engineering and Technology Research Centre for Environmental Risk Prevention and Emergency Disposal South China University of Technology Center for Excellence in Urban Atmospheric Environment Institute of Urban Environment Chinese Academy of Sciences

Herein, we reported the synthesis of well-defined Co_3O_4 nanoarrays(NAs) supported on a monolithic three-dimensional macroporous nickel(Ni) foam substrate for use in highefficiency CO oxidation. The monolithic Co_3O_4 NAs catalysts were obtained through a generic hydrothermal synthesis route with subsequent calcination. By controlling the reaction time,solvent polarity and deposition agent, these Co_3O_4 NAs catalysts exhibited various novel morphologies(single or hybrid arrays), whose physicochemical properties were further characterized by using several analytical techniques. Based on the catalytic and characterization analyses, it was found that the Co_3O_4 NAs-6 catalyst with nanobrush and nanomace arrays displayed enhanced catalytic activity for CO oxidation, achieving an efficient 100% CO oxidation conversion at a gas hourly space velocity(GHSV) 10,000 hr^(-1) and 150°C with longterm stability. Compared with the other Co_3O_4 NAs catalysts, it had the highest abundance of surface-adsorbed oxygen species, excellent low-temperature reducibility and was rich in surface-active sites(Co^(3+)/Co^(2+)= 1.26).

关键词： CO oxidation Nanomace Co3O4 Hybrid arrays macroporous Ni foam

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Facile synthesis of bimodal macroporous g-C_3N_4/SnO_2 nanohybrids with enhanced photocatalytic activity

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Science Bulletin 2019年第1期64卷 44-53页

作者： Yingzhi Chen Wenhao Li Dongjian Jiang Kuo Men Zhen Li Ling Li Shizheng Sun Jingyuan Li Zheng-Hong Huang Lu-Ning Wang School of Materials Science and Engineering University of Science and Technology Beijing State Key Laboratory of Advanced Materials for Smart Sensing General Research Institute for Non-Ferrous Metals Key Laboratory of Advanced Materials (MOE) School of Materials Science and Engineering Tsinghua University State Key Laboratory for Advanced Metals and Materials University of Science and Technology Beijing

It is of vital importance to construct highly interconnected,macroporous photocatalyst to improve its efficiency and applicability in solar energy conversion and environment remediation.Graphitic-like C_3N_4(g-C_3N_4),as an analogy to two-dimensional(2D)graphene,is highly identified as a visible-lightresponsive polymeric semiconductor.Moreover,the feasibility of g-C_3N_4 in making porous structures has been well established.However,the preparation of macroporous g-C_3N_4 with abundant porous networks and exposure surface,still constitutes a difficulty.To solve it,we report a first facile preparation of bimodal macroporous g-C_3N_4 hybrids with abundant in-plane holes,which is simply enabled by in-situ modification through thermally treating the mixture of thiourea and SnCl_4(pore modifier)after rotary evaporation.For one hand,the formed in-plane macropores endow the g-C_3N_4 system with plentiful active sites and short,cross-plane diffusion channels that can greatly speed up mass transport and transfer.For another,the heterojunctions founded between g-C_3N_4 and SnO_2 consolidate the electron transfer reaction to greatly reduce the recombination probability.As a consequence,the resulted macroporous gC_3N_4/SnO_2 nanohybrid had a high specific surface area(SSA)of 44.3 m^2/g that was quite comparable to most nano/mesoporous g-C_3N_4 reported.The interconnected porous network also rendered a highly intensified light absorption by strengthening the light penetration.Together with the improved mass transport and electron transfer,the macroporous g-C_3N_4/SnO_2 hybrid exhibited about 2.4-fold increment in the photoactivity compared with pure g-C_3N_4.Additionally,the recyclability of such hybrid could be guaranteed after eight successive uses.

关键词： Highly macroporous g-C3N4 Nanohybrid Interconnected network Photocatalysis

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Separation and Purification of Glufosinate Through Combination of an Electrodialysis Membrane and a macroporous Adsorption Resin

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Chemical Research in Chinese Universities 2019年第4期35卷 647-653页

作者： CUI Menglong DU Xiaohua Catalytic Hydrogenation Research Center Zhejiang Green Pesticide Collaborative Innovation CenterCollege of Chemical EngineeringZhejiang University of TechnologyHangzhou 310014P. R.China

Glufosinate is a nonselective organophosphorus herbicide with low toxicity and high efficiency that is widely used in forestry, agriculture and other industries. In the process of manufacturing glufosinate, large amounts of ammonium chloride and coloured organic impurities are generated. Because of its high solubility in water, separation of glufosinate from inorganic salts is extremely difficult. Hence, a co-separation method combining an electrodialysis membrane and a macroporous adsorption resin was developed to obtain glufosinate with higlier purity. For the electrodialysis process, a glufosinate reaction solution was placed in a dilute chamber and desalinated. The concentration of inorganic salts in the resultant glufosinate aqueous solution was only 0.99 g/L under the optimal conditions of an operating voltage and a volume ratio of 9 V and 1:1, respectively. For the macroporous resin adsorption/desorption process, the sample solution treated by electrodialysis was pumped into the resin-filled column, which was eluted to obtain the eluent when the adsorption reached equilibrium. Consequently, nearly all the coloured organic impurities were removed under the optimal conditions, in which the resin type, pH value, flow rate, glufosinate concentration, temperature, ratio of ethanol and volume of eluent were LX-300C,3,0.5 mL·cm^2·min^-1,20 mg/mL,25℃, 50% and 400 mL, respectively. After the electrodialysis and adsorption/desorption process, the purity of the glufosinate was increased to 95.14%, and its recovery rate was as high as 98%. The advantages of this process included its ease of operation, environmental friendliness and low cost, which provided strong potential for its use in industrial applications.

关键词： Electrodialysis membrane Glufosinate macroporous adsorption resin Purification

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Preparation of the glucose sensor based on three-dimensional ordered macroporous gold film and room temperature ionic liquid

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Science China Chemistry 2009年第11期52卷 1999-2005页

作者： CHEN XiaoJun XUAN Jie JIANG LiPing ZHU JunJie Key Lab of Analytical Chemistry for Life Science(MOE) School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210093China College of Sciences Nanjing University of TechnologyNanjing 210009China

A novel type of glucose sensor was fabricated based on a glucose oxidase(GOD)-N,N-dimethtylformamide(DMF)-[BMIm][BF4] composites modified three-dimensional ordered macroporous(3DOM) gold film electrode.The immobilized GOD exhibits a pair of well-defined reversible peaks in 50 mM pH 7.0 phosphate buffer solutions(PBS),which could be attributed to the redox of flavin adenine dinucleotide(FAD) in GOD.The research results show that ionic liquid([BMIm][BF4]),DMF and 3DOM gold film are crucial for GOD to exhibit a pair of stable and reversible peaks.It is believed that the large active area of 3DOM gold film can increase the amount of immobilized GOD.Simultaneously,the application of IL enhances the stability of GOD and facilitates the electron transfer between GOD and the electrode.The synergetic effect of DMF can help the GOD to maintain its bioactivity better.GOD immobilized on the electrode exhibits the favorable electrocatalytic property to glucose,and the prepared sensor has a linear range from 10 to 125 nM with a detection limit of 3.3 nM at a signal-to-noise ratio of 3σ.The apparent Km(Michaelis-Menten constant) for the enzymatic reaction is 0.018 mM.

关键词： ionic liquid glucose oxidase three-dimensional ordered macroporous gold film direct electrochemistry electrochemical catalysis

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Promising supercapacitor electrodes based immobilization of proteins onto macroporous Ni foam materials

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Journal of Energy Chemistry 2015年第1期24卷 31-38页

作者： Mohamed Khairy Sherif A.El-Safty National Institute for Materials Science (NIMS) 1-2-1 Sengen Tsukubalshi Ibaraki-ken 305-0047 Japan Chemistry Department Faculty of Science Sohag UniversityEgypt Graduate School for Advanced Science and Engineering Waseda University 3-4-1 Okubo Shinjuku-ku Tokyo 169-8555 Japan

Immobilizing biocomponents on solid surfaces is a critical step in the development of new devices for future biological, medical, and elec- tronic applications. Therefore, numerous integrated films were recently developed by immobilizing different proteins or enzymes on electrode surfaces. In this work, hemeproteins were safely immobilized onto macroporous nickel-based electrodes while maintaining their functionality. Such modified electrodes showed interesting pseudo-capacitive behavior. Among hemeproteins, hemoglobin （Hb） film has a higher electro- chemical performance and greater charge/discharge cycling stability than myoglobin （Mb） and cytochrome C （CytC）. The heme group in an alkaline medium could induce the formation of superoxides on the electrode surface. These capacitive features of hemeprotein-Ni electrode were related to strong binding sites between hemeproteins and porous Ni electrode, the accumulation of superoxide or radicals on the Ni sur- face, and facile electron transfer and electrolyte diffusion through the three-dimensional macroporous network. Thus, these new protein-based supercapacitors have potential use in free-standing platform technology for the development of implantable energy-storage devices.

关键词： whemeprotein nickel foam pseudocapacitor macroporous peroxide alkaline medium

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Zirconia modified monolithic macroporous Pt/CeO_2/Al_2O_3 catalyst used for water-gas shift reaction

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Journal of Rare Earths 2011年第8期29卷 753-757页

作者：梁皓苑宏刚魏枫张喜文刘源 Fushun Research Institute of Petroleum and Petrochemicals SINOPEC Fushun Environmental Science Academy Tianjin Key Laboratory of Applied Catalysis Science and Engineering Department of Catalysis Science and Technology School of Chemical Engineering and Technology Tianjin University

Monolithic macroporous Pt/CeO2/Al2O3 and zirconia modified Pt/CeO2/Al2O3 catalysts were prepared by using concentrated emulsions synthesis route. The catalytic performances over the platinum-based catalysts were investigated by water-gas shift （WGS） reaction in a wide temperature range （180–300 oC）. The samples were characterized with thermogravimetry （TG）, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, high resolution transmission electron microscopy （HRTEM） and temperature programmed reduction （TPR） techniques as well. The SEM and HRTEM results indicated that the monoliths possessed macroporosity, in size of 5–50 μm, and platinum particles were homogeneously dispersed on macroporous materials. XRD and TPR results showed that the interaction between ceria and zirconia oxide was formed and the addition of zirconia could promote the reducibility of platinum oxide on the interface of ceria and zirconia particles, which led to an improvement of catalytic activity in WGS reaction. The results indicated that zirconia modified monolithic macroporous Pt/CeO2/Al2O3 could be fabricated in small size （from millimeter lever to centimeter） and had good reaction activity, which was a potential new route for miniaturization of the WGS reactor.

关键词： macroporous monolithic water-gas shift platinum zirconia rare earths

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Synthesis of 3D ordered macroporous indium tin oxide using polymer colloidal crystal template

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Science China(Technological Sciences) 2006年第5期49卷 537-546页

作者： ZHANG Xue'ao MAN Yahui WANG Jianfang LIU Changli WU Wenjian College of Aerospace and Materials Engineering National University of Defense Technology Changsha 410073 China College of Aerospace and Materials Engineering National University of Defense Technology Changsha 410073 China College of Aerospace and Materials Engineering National University of Defense Technology Changsha 410073 China College of Aerospace and Materials Engineering National University of Defense Technology Changsha 410073 China College of Aerospace and Materials Engineering National University of Defense Technology Changsha 410073 China

Three-dimensional (3D) ordered macroporous indium tin oxide (ITO) is pre- pared using a polymer colloidal crystal template that is formed by self-assembly of the monodisperse poly(methyl methacrylate) (PMMA) microspheres. The morphologies and BET surface area of the macroporous material is examined by scanning electron micro- scope, transmission electron microscopy and N2 adsorption/desorption. Results indicate that the macroporous material has highly ordered arrays of the uniform pores replicated from the PMMA colloidal crystal template when the polymer colloidal crystal template is removed by calcinations at 500℃. The pore diameter (about 450 nm) of macroporous ITO slightly shrank to the PMMA microspheres. The BET surface area and pore volume of the macroporous material are 389 m2·g-1 and 0.36 cm3·g-1, respectively. Moreover, the macroporous ITO, containing 5 mol% Sn and after annealing under vacuum, shows the minimum resistivity of ρ = 8.2×10-3 Ω· cm. The conductive mechanism of macroporous ITO is discussed, and it is believed that the oxygen vacancies are the major factor for excellent electrical properties.

关键词： template synthesis, polymer colloidal crystal, indium tin oxide, three-dimensional order, macroporous material.

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Uniform hierarchical silica film with perpendicular macroporous channels and accessible ordered mesopores for biomolecule separation

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Chinese Chemical Letters 2019年第5期30卷 1089-1092页

作者： Xiaodan Su Jun Tao Sui Chen Peng Xu Dan Wang Zhaogang Teng Key Laboratory for Organic Electronics&Information Displays and Institute of Advanced Materials Nanjing University of Posts and TelecommunicationsNanjing 210046China Department of Medical Imaging Jinling HospitalSchool of MedicineNanjing UniversityNanjing 210002China College of Chemical Engineering Nanjing Forestry UniversityNanjing 210037China Department of Gynecology&Obstetrics Affiliated Changzheng HospitalThe Second Military Medical UniversityShanghai 200003China

Herein, we demonstrate that silica films with perpendicular macroporous channels and accessible ordered mesopores can be conveniently prepared. The hierarchical macroporous–mesoporous silica films are synthesized by using zinc oxide nanorod array as macroporous template and CTAB surfactant as mesoporous template. In basic surfactant-containing solution, ordered mesoporous silica shells homogeneously grow on the zinc oxide nanorod array. The growth of the mesostructures do not require any chemical modification for the zinc oxide nanorod, which opens a new way for preparing hierarchical silica films with perpendicular mesochannels. The prepared hierarchical macroporous–mesoporous silica films possess a uniform thickness of 2μm, large perpendicular macropores with a length of 1.8μm and a width of 80 nm, and accessible ordered mesopores. Separation experiment demonstrates that this macroporous–mesoporous film can effectively separate biomolecules with different sizes.

关键词： Silica Film macroporous Mesoporous Separation

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