检索结果-南通市图书馆

Synthesis,Structure,and luminescent property of a 3-D Zinc Complex {[Zn_8^(II)(4-APha)_8(CH_3COO)_8](CH_3CH_2OH)_2}_n

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2014年第7期33卷 1019-1024页

作者：杨华胡道道 College of Chemistry and Chemical Engineering Yan’an University School of Materials Science and Engineering Shaanxi Normal University

The title complex [ZN8II（4-APha）8（CH3COO）8（CH3CH2OH）2]n （1, 4-APha = 4-ami- nophenylhydroxamic acid） has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a = 39.074（4）, b = 9.9645（8）, c=38.846（3） A, β = 136.438°, V= 10423.1（14） A3, C84H118N16O39Zn8, Mr = 2498.90, Z = 4, Dc = 1.592 g/cm3,μ= 1.900 mm-1, F（000） = 5144, the final R = 0.1036 and wR = 0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha＂ ligands. The luminescent property of the title complex has been investigated.

关键词： zinc complex hydroxamic acftls 3-D framework luminescent property

Synthesis, Structure and luminescent property of an Europium(Ⅲ) Coordination Polymer

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2014年第11期33卷 1649-1654页

作者：叶燕珠林深吴新建 Department of Science Research and Training Fujian Institute of Education College of Chemistry and Chemical Engineering Fujian Normal University

A novel europium（Ⅲ） coordination polymer, [Eu3（pydc）3（SO4）（H2O）5（ox）0.5]·3H2O（1, H2ox = oxalic acid, H2 pydc = pyridine-2,6-dicarboxylic acid）, has been synthesized hydrothermally from the self-assembly of lanthanide ions（Eu3＋） with the flexible oxalic acid and the rigid pyridine-2,6-dicarboxylic acid ligands, respectively. It crystallizes in the triclinic system, space group P1 with a = 11.225（4）, b = 12.390（5）, c = 13.752（5）A, α = 89.228（7）, β = 71.142（6）, γ = 75.552（6）°, Dc = 2.317 g/cm^3, μ = 5.480 mm^-1, F（000） = 1150, Z = 2, the final R = 0.0351 and w R = 0.0949 for 8782 observed reflections with I 〉 2σ（I）. Structural analysis reveals that complex 1 exhibits a three-dimensional metal-organic framework via π-π stacking interactions. In addition, complex 1 displays a red fluorescence emission in the solid state at room temperature, which corresponds to the 5D0 → 7F2 transition of Eu3＋ ions.

关键词： coordination polymer lanthanide luminescent property

Synthesis,Structure and luminescent property of a Zn(Ⅱ)Complex with Mixed Multi-N Donor and 2,5-Dihydroxy-terephthalic Acid Ligands

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2018年第7期37卷 1117-1124页

作者：郭星哲李家乐施珊珊周慧韩帅帅陈水生 College of Chemistry & Chemical Engineering Fuyang Normal College Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment

A new complex, [Zn2（HL）2（2,5-OH-pbda）]n（1, L = 1-（1 H-imidazol-4-yl）-4-（4 Htetrazol-5-yl）benzene（H2L） and 2,5-OH-H2 pbda = 2,5-dihydroxy-terephthalic acid）, has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and PXRD. Complex 1 crystallizes in monoclinic, space group P21/n with a = 8.8101（10）, b = 17.105（2）, c = 9.4014（11）A, β = 105.704（2）o, V = 1363.9（3） A3, Z = 4, C（14）H9N6O3Zn, Mr = 374.64, Dc = 1.824 g/cm3, μ = 1.831 mm^（-1）, S = 1.042, F（000） = 756, the final R = 0.0309 and w R = 0.1003 for 3130 observed reflections（I 2σ（I））. The H2L ligand was deprotonated to be an HL-anion, and coordinated with Zn^（2＋） to form two-dimensional（2D） Zn2（HL^-）2^（2＋） sheets, which were pillared by the 2,5-OH-pbda2-ligands to form a three-dimensional（3D） dmc net with Point（Schlafli） symbol of（4·82）（4·85）. The large vacancy of the dmc net is filled via mutual interpenetration of another independent framework, leading to the formation of a 2-fold interpenetrating architecture. Solid state luminescent property of 1 has been investigated.

关键词： metal-organic framework crystal structure luminescent property

Synthesis, Structure, and luminescent property of a 3-D Strontium Complex [Sr_3(pda)_2(Hpda)_2(H2O)_2]_n·2nH_2O

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2014年第5期33卷 746-752页

作者：陈砚美高倩高丹丹王德荣李亚红刘玮李武 Key Laboratory of Organic Synthesis of Jiangsu Province College of ChemistryChemical Engineering and Materials Science Soochow University Key Laboratory of Salt Lake Resources and Chemistry Qinghai Institute of Salt Lakes Chinese Academy of Sciences

The title complex [Sr3（pda）2（Hpda）2（H2O）2]n·2nH2O（H2pda = pyridine-2,6-dicar- boxylic acid） has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group P21/c with a = 10.3795（8）, b = 9.2225（7）, c = 18.5726（14） , β = 104.377（2）o, V = 1722.2（2） 3, C28H22N4O20Sr3, Mr = 997.36, Z = 2, Dc = 1.923 g/cm3, μ = 4.722 mm-1, F（000） = 984, the final R = 0.0269 and wR = 0.0538. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by carboxylate groups. The luminescent property of the title complex has been investigated.

关键词： strontium complex crystal structure luminescent property 3-D framework

Two New Coordination Complexes Based on 2,2'-H2biimidazole: Synthesis, Structure, luminescent property and Theoretical Calculation

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2020年第8期39卷 1451-1457,1359页

作者： ZHANG Hua XU Tongtong XING Tianyi WANG Xueying ZUO Jiamei KONG Zhiguo Key Laboratory of Preparation and Applications of Environmental Friendly Materials Jilin Normal UniversityMinistry of EducationChangchun 130103China Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education Jilin Normal UniversityMinistry of EducationChangchun 130103China Department of Chemistry Jilin Normal UniversitySiping 136000China

Two new coordination complexes[Cd(L)2(1,2,3-HBTC)]·3H2O(1)and{[Zn(L)(1,2-BDC)]-H2O}n(2)were synthesized under hydrothermal conditions(1,2,3-H3 BTC=1,2,3-tricarboxybenzene,1,2-H2 BDC=1,2-dicarboxybenzene and L=2,2’-H2 biimidazole).1 crystallizes in monoclinic,space group P21/c with a=12.256(5),b=11.620(5),c=17.479(5)A,β=95.548(5)°,V=2477.6(16)A^3,Z=4,C21H22N8 O9 Cd,Mr=642.86,Dc=1.724 g/cm^3,F(000)=1296,μ(MoKa)=0.950 mm^-1,R=0.0546 and wR=0.1724.2 belongs to the monoclinic system,space group P21/c with a=7.408(4),b=20.743(10),c=10.194(5)A,β=95.648(6)°,V=1477.3(12)A^3,Z=4,C14H12N4 O5 Zn,Mr=381.65,Dc=1.716 g/cm3,F(000)=776,μ(MoKa)=1.698 mm^-1,R=0.0574 and wR=*** central Cd(Ⅱ)ion in 1 is coordinated with five atoms,forming a slightly distorted square-pyramidal *** central Zn(Ⅱ)ion in 2 is four-coordinated by two nitrogen atoms from one L ligand and two oxygen atoms from two different 1,2-BDC *** addition,luminescent property of 1 has been investigated,and natural bond orbital(NBO)analysis of 2 has been calculated by the B3LYP/LANL2DZ method.

关键词： structure coordination complex 2,2'-H_(2)biimidazole luminescent property

Synthesis, Structure and luminescent property of a New Zinc(Ⅱ) Complex

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2015年第10期34卷 1513-1518页

作者：翟吉全张雨程建开杨锦霞张鑫覃业燕姚元根 College of Chemistry Fuzhou University State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences

One new coordination polymer, namely {[Zn（HL）（Hbipy）]2·3H2O}n（bipy = 4,4A-bipyridine, H4 L = 6-（3＇,4＇-dicarboxyl-phenoxy） isophthalic acid）, has been synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectra（IR）, and thermogravimetric（TG） analysis. The crystal structure is of monoclinic, space group P21/n with a = 9.6435（3）, b = 19.8515（7）, c = 12.9731（5） A, β = 103.023（4）o, V = 2419.67（15） A3, C52H38Zn2N4O21, Mr = 1185.6, Z = 2, Dc = 1.619 g/cm^3, F（000） = 1200, μ = 1.083 mm-1, the final R = 0.0443 and w R = 0.1079 for 4269 observed reflections（I 2σ（I）. The compound features a two-dimensional（2D） framework and stabilizes itself by interlayer π···π interactions and innerlayer hydrogen bonds. The 2D layer presents a simple 3-connected 63 topology. Moreover, the thermal dynamic stability and luminescent property of the compound have also been discussed in detail.

关键词： coordination polymer hydrogen bonds π···π interactions topology luminescent property

A New One-dimensional Coordination Polymer Based on 3,5-Dinitro-salicylic Acid:Synthesis,Crystal Structure,luminescent property and Theoretical Calculation

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2017年第5期36卷 841-847页

作者：孔治国刘东雪李芮江月王丽娟胡波 Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University) Ministry of Education Department of Chemistry Jilin Normal University

A new one-dimensional Mg（Ⅱ） coordination polymer, [Mg（L）（phen）（H2O）]（1）, has been hydrothermally synthesized by using 3,5-dinitro-salicylic acid（H2L） and 1,10-phenanthroline（phen）. It crystallizes in monoclinic, space group C2/c with a = 33.038（7）, b = 6.6481（13）, c = 22.750（5） A, β = 126.99（3）°, V = 3991.1（14） A3, Z = 8, C19H12 MgN4O8, Mr = 448.64, Dc = 1.493 g/cm3, F（000） = 1840, μ（Mo Ka） = 0.146 mm-1, R = 0.0559 and w R = 0.0975. In 1, each L anion bridges two Mg（Ⅱ） atoms to give one-dimensional zigzag chains with the Mg…Mg separation of 5.34 ？, which are extended by π-π stacking interactions between 1,10-phenanthroline ligands into a two-dimensional supramolecular layer. Moreover, the O–H…O hydrogen-bonding interactions further stabilize the layer structure of 1. The luminescent property was also studied for 1 in solid state at room temperature. In addition, natural bond orbital（NBO） analysis was performed by the B3LYP/LANL2 DZ method in Gaussian 09 Program. The calculation results show obvious covalent interaction between the coordinated atoms and Mg（Ⅱ） ion.

关键词： luminescent property crystal structure coordination polymer,theoretical calculation

Synthesis, Structure and luminescent property of a Zinc(Ⅱ) Coordination Polymer Incorporating Flexible Cyclohexane-1,2,3,4,5,6-hexacarboxylate Ligand

在线全文

学校读者我要写书评

暂无评论

Chemical Research in Chinese Universities 2011年第3期27卷 354-357页

作者： WANG jind LIU Zhao-qing SU Ting-ting School of Chemistry and Chemical Engineering Guangzhou University Guangzhou 510006 P. R. China

The hydrothermal reaction of Zn（NO3）2·4H2O, cyclohexane-1,2,3,4,5,6-hexacarboxylic acid hydrate （H6LI·H2O, cis-conformation LI： a,e,a,e,a,e） and 2,2＇-bpy yielded a new coordination polymer [Zn2（H2LII）（2,2＇-bpy）]·2H2O（trans-conformation LII： e,e,e,e,e,e）, which was characterized by single-crystal X-ray diffraction, elemental analysis, IR and XRPD（X-ray powder diffraction）. This complex crystallized in the triclinic system, with P1 space group and parameters a=0.66922（5） nm, b=0.97291（8） nm, c=1.22184（9） nm, α=99.0020（10）°, β=99.1300（10）°, γ=99.1910（10）°, V= 0.76176（10） nm3 and Z=2. The structure is a three-dimensional supramolecular network based on linear coordination chains through π-π stacking and hydrogen bonding interactions. The confromation of the starting ligand H6LI transfromed to the H2LII. The complex emits strong luminescence at room temperature.

关键词： Coordination polymer Cyclohexane-1 2 3 4 5 6-hexacarboxylate Conformation luminescent property

Synthesis, Crystal Structure and luminescent property of a Ag(Ⅰ) Coordination Polymer with a 3D Sandwich-like Framework

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Structural Chemistry 2016年第2期35卷 319-325页

作者： LU Jiu-Fu SHI Juan ZHENG Nan GUO Xiao-Hua GE Hong-Guang Chemical Engineering College Shaanxi University of Technology

A new coordination polymer,{[Ag2（bpp）2（H2O）2]·bpdc·3H2O}n,derived from the ligand biphenyl-4,4＇-dicarboxylic acid（H2bpdc）,has been obtained through a hydrothermal technique（bpp = l,3-bis（4-pyridyl）propane）.Its single-crystal structure has been characterized by single-crystal X-ray diffraction,powder XRD,FT-IR,TGA and elemental analysis *** single-crystal X-ray diffraction reveals that complex 1 consists of 1D infinite[Ag（bpp）（H2O）]n^（n＋）cationic chains,2D anionic layer constructed by bpdc anions and free water which provide charge compensation in the crystal *** 1D infinite[Ag（bpp）（H2O）]n^（n＋） cationic chains and 2D anionic layer are further stacked in-ABAB- fashion through intermolecular H-bonding to form a 3D sandwich-like *** addition,the luminescent property of complex 1 in the solid state at room temperature was investigated.

关键词： Ag(Ι) coordination polymer crystal structure luminescent property