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Tuning Polymer Molecular Weight Distribution in Cationic RAFT polymerization by Mixing Chain Transfer Agents

Chinese Journal of Chemistry 2023年第14期41卷 1684-1690页

作者： Miao Chen Jiajia Li Dong Xing Xiangqiang Pan Jian Zhu State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Functional Polymer Design and ApplicationSuzhou Key Laboratory of Macromolecular Design and Precision SynthesisDepartment of Polymer Science and EngineeringCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhouJiangsu215123 China

Polymer dispersity (Đ) or molecular weight distribution (MWD) is a basic but vital parameter for the properties of polymeric materials. Developing new methodologies for controlling polymer MWD is emerging as a research hotspot. However, the methods to tune polymer MWD in cationic polymerization are still not well explored. Herein, we present a simple method to control the dispersity of poly(isobutyl vinyl ether) (PIBVE) by mixing two different chain transfer agents in batch visible light induced cationic RAFT polymerization. A broad dispersity range (Đ ≈ 1.16—1.80) was successfully achieved while maintaining monomodal MWD. Moreover, chain extension of PIBVE through both cationic polymerization and radical polymerization has been studied, which also provides a method to tune polymer MWD in mechanism transformation polymerization.

关键词： RAFT Photopolymerization Copolymers lonic polymerization Molecular weight distribution Dispersity

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Vinylogous Fluorine Stabilizing Effect Enables Rational Design of a Novel Donor-Acceptor Cyclopropane and Its Applications in[3+2]Cycloaddition Reaction and Ring-Opening polymerization

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Chinese Journal of Chemistry 2024年第22期42卷 2723-2727页

作者： Yue Li Dian-Feng Chen Hefei National Research Centerfor Physical Sciences at the Microscale and Department of Polymer Science and Engineering University of ScienceandTechnologyof ChinaHefeiAnhui 230026China

Comprehensive Summary Discovery of unprecedented donor-acceptor patterns can essentially enrich the chemistry of donor-acceptor *** herein introduce a concept of vinylogous fluorine stabilizing effect,which guides rational design of a novel donor-acceptor cyclopropane employing gem-difluorovinyl group as the electron donor,namely *** of such dFVCPs in a[3+2]cycloaddition with aldehydes and a controlled ring-opening polymerization by a Mg(OTf)2/DIPEA/C(sp3)-H initiator system have been demonstrated,providing direct access to fluorine-containing tetrahydrofurans and all-carbon main-chain polymers.

关键词： Donor-acceptor cyclopropane gem-Difluorovinyl group Vinylogous fluorine stabilizing effect [3+2]cycloaddition Ring-opening polymerization Strainedmolecules Monomers lonic polymerization

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