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Investigation of solution chemistry to enable efficient lithium recovery from low-concentration lithium-containing wastewater

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Frontiers of Chemical Science and Engineering 2020年第4期14卷 639-650页

作者： Chunlong Zhao Mingming He Hongbin Cao Xiaohong Zheng Wenfang Gao Yong Sun He Zhao Dalong Liu Yanling Zhang Zhi Sun State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China Beijing Engineering Research Center of Process Pollution Control Key Laboratory of Green Process and EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China University of Nottingham Ningbo China Ningbo 315100China Henan Bingsheng Biotechnology Company Limited Kaifeng 475103China

In the production of lithium-ion batteries(LIBs)and recycling of spent LIBs,a large amount of low-concentration lithium-containing wastewater(LCW)is *** recovery of Li from this medium has attracted significant global attention from both the environmental and economic *** achieve effective Li recycling,the features of impurity removal and the interactions among different ions must be ***,it is generally dificult to ensure highly efficient removal of impurity ions while retaining Li in the solution for further *** this study,the removal of typical impurity ions from LCW and the interactions between these species were systematically investigated from the thermodynamic and kinetics *** was found that the main impurities(e.g.,Fe^+,AIP^+,Ca^2+,and Mg^2+)could be efficiently removed with high Li recovery by control-ling the ionic strength of the *** mechanisms of Fe^3+,Al^+,Ca^2+,and Mg^2+removal were investigated to identify the controlling steps and reaction *** was found that the precipitates are formed by a zero-order reaction,and the activation energies tend to be low with a sequence of fast chemical reactions that reach equilibrium very ***,this study focused on Li loss during removal of the impurities,and the corresponding removal rates of Fe^+,Al^+,Ca^2+,and Mg^2+were found to be 99.8%,99.5%,99%,and 99.7%,***-quently,high-purity LisPO4 was obtained via one-step ***,this research demonstrates a potential route for the effective recovery of Li from low-concentra-tion LCW and for the appropriate treatment of acidic LCW.

关键词： lithium-containing wastewater lithium phos-phate precipitation impurity ion

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lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery manufacturing

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Frontiers of Chemical Science and Engineering 2022年第5期16卷 755-763页

作者： Rongzhen Chen Xinfei Dong Qingchun Ge College of Environment and Safety Engineering Fuzhou UniversityFuzhou 350116China

As draw solute is the core element of forward osmosis(FO)technology,here Li-Bet-Tf_(2)N synthesized from a customized ionic liquid betainium bis(trifluoromethylsulfonyl)imide([Hbet][Tf_(2)N])and Li2CO_(3) recovered from lithium-ion battery(LIB)wastes is proposed as a novel draw solute to treat Li+-containing wastewater from LIB manufacturing through FO *** high dissociation ability and an extended structure,Li-Bet-Tf_(2)N generates a sufficiently high osmotic pressure to drive the FO filtration efficiently along with insignificant reverse solute ***-Bet-Tf_(2)N produces a water flux of 21.3 L·(m^(2)·h)–1 at 1.0 mol∙L^(-1) against deionized water,surpassing conventional NaCl and MgCl2 draw solutes with a higher water recovery efficiency and a smaller solute ***-Bet-Tf_(2)N induces a more stable and higher water permeation flux with a 10.0%water flux decline than NaCl and MgCl_(2) for which the water fluxes decline 16.7%and 16.4%,respectively,during the treatment of 2000 mg∙L^(-1) Li+-containing wastewater for 12 *** remarkably,unlike other draw solutes which require intensive energy input and complicated processes in recycling,Li-Bet-Tf_(2)N is easily separated from water via solvent *** results are achieved with the recycled Li-Bet-Tf_(2)***-Bet-Tf_(2)N thus demonstrates a novel class of draw solute with great potentials to treat wastewater economically.

关键词： forward osmosis lithium-ion battery draw solution lithium-containing wastewater water treatment

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