检索结果-南通市图书馆

Nano-channel-based physical and chemical synergic regulation for dendrite-free lithium plating

Nano Research 2021年第10期14卷 3585-3597页

作者： Qiang Guo Wei Deng Shengjie Xia Zibo Zhang Fei Zhao Binjie Hu Sasa Zhang Xufeng Zhou George Zheng Chen Zhaoping Liu Key Laboratory of Graphene Technologies and Applications of Zhejiang Province and Advanced Li-ion Battery Engineering Laboratory of Zhejiang Province Ningbo Institute of Materials Technology and EngineeringChinese Academy of Sciences(CAS)Ningbo 315201China Department of Chemical and Environmental Engineering Faculty of Science and EngineeringUniversity of NottinghamNingbo 315100China Department of Chemical and Environmental Engineering Faculty of EngineeringUniversity of NottinghamNottingham NG72RDUK

Uncontrollable dendrite growth resulting from the non-uniform lithium ion(Li^(+))flux and volume expansion in lithium metal(Li)negative electrode leads to rapid performance degradation and serious safety problems of lithium metal *** N-containing functional groups in carbon materials are reported to be effective to homogenize the Li^(+)flux,the effective interaction distance between lithium ions and N-containing groups should be relatively small(down to nanometer scale)according to the Debye length ***,it is necessary to carefully design the microstructure of N-containing carbon materials to make the most of their roles in regulating the Li^(+)*** this work,porous carbon nitride microspheres(PCNMs)with abundant nanopores have been synthesized and utilized to fabricate a uniform lithiophilic coating layer having hybrid pores of both the nano-and micrometer scales on the Cu/Li ***,the three-dimensional(3D)porous framework is favorable for absorbing volume changes and guiding Li ***,this coating layer can render a suitable interaction distance to effectively homogenize the Li^(+)flux and contribute to establishing a robust and stable solid electrolyte interphase(SEI)layer with Li-F,Li-N,and Li-O-rich contents based on the Debye length *** a physical-chemical synergic regulation strategy using PCNMs can lead to dendrite-free Li plating,resulting in a low nucleation overpotential and stable Li plating/stripping cycling performance in both the Li||Cu and the Li||Li symmetric ***,a full cell using the PCNM coated Li foil negative electrode and a LiFePO4 positive electrode has delivered a high capacity retention of~80%after more than 200 cycles at 1 C and achieved a remarkable rate *** pouch cell fabricated by pairing the PCNM coated Li foil negative electrode with a NCM 811 positive electrode has retained~73%of the initial capacity after 150 cycles at 0.2 C.

关键词： carbon nitride Debye length lithiophilic coating porous structure Li negative electrode

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：