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Plasma cascaded solid wastes for possible adsorption of NO_(2)in diesel exhaust

waste Disposal and Sustainable Energy 2023年第3期5卷 383-393页

作者： Apoorva Sahu Shivani Mishra Preeti Jain Bangalore S.Rajanikanth Department of Electrical Engineering Indian Institute of ScienceBangaloreIndia Department of Electrical Engineering Jabalpur Engineering CollegeJabalpurIndia

Extensive use of fossil fuel has led to an increase in solid and gaseous particulates in the environment,which in turn necessitated newer,effective,and economical control strategies to abate pollutants,particularly gaseous *** the current research work,focus has been placed on utilizing industry wastes to adsorb nitrogen oxides present in diesel engine exhaust,which is pre-treated by *** exhaust from a 5 kW diesel generator is exposed to discharge plasma where the oxidation of nitric oxide to nitrogen dioxide occurs,which is then made to flow through another reactor filled with industry wastes drawn from agriculture,foundry,utility,marine industry,etc.,comprising mulberry waste,rice husk,wheat husk,areca nut husk,sugarcane bagasse,coffee husk,foundry sand,lignite ash,red mud,and oyster *** the adsorption of nitrogen dioxide was observed in all the wastes,reduction of nitric oxide was observed in metallic compound-based industry *** about 184 J/L,specific energy plasma cascaded industrial waste red mud yielded 98%NO_(x)removal efficiency,and that with agriculture rice husk waste yielded 53%NOx ***_(2)/Fe_(2)O_(3)present in industry wastes might have exhibited photo-catalysis in visible light resulting in the possible reduction of NO.A new pathway for recycling the waste can be expected through nitrogen dioxide adsorption,and the results are further discussed with respect to plasma-alone and cascaded plasma adsorbent systems.

关键词： industry waste Electrical discharge Diesel exhaust Nitrogen oxide reduction Agriculture waste Plasma adsorption

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Use of lime mud from paper mill as a heterogeneous catalyst for transesterification

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Science China(Technological Sciences) 2014年第2期57卷 438-444页

作者： LI Hui NIU ShengLi LU ChunMei LIU MengQi HUO MengJia School of Energy and Power Engineering National Engineering Laboratory for Coal-Burning Pollutants Emission Reduction Shandong University

Lime mud （LM）, a solid waste from the paper mill, is used as an economic and environmental friendly heterogeneous basic catalyst for transesterification, which is accompanied by characterization of X-ray fluorescence, thermogravimetric-differential thermal analysis, X-ray diffraction, N2 adsorption, and Hammett indicator method. To investigate the performance of the achieved catalyst, which is activated through calcination, the aspects of calcination temperature, reaction time, mole ratio of methanol to oil, catalyst addition percentage, and reaction temperature are concerned. Characterization of catalyst reveals that LM could be activated through calcination to transform the carbonate and hydrate of calcium into the oxide forms and higher calcination temperature could lead to stronger basic strength. However, N2 adsorption results indicate that higher temperature causes the sintering of the catalyst and shrinkage of the catalyst grains. When LM is activated at 800℃ （LM-800） and the reac- tion is carried out at 64℃ with a methanol to oiL mole ratio of 15：1, catalyst addition percentage of 6%, and reaction time of 2 h, the maximum transesterification conversion of 94.35% could be achieved. Reusability of LM-800 is also investigated com- pared with laboratory grade CaO in five reaction cycles and the results indicate that the catalysts derived from LM can be used as an economic and efficient catalyst for biodiesel production.

关键词： lime mud biodiesel heterogeneous catalyst transesterification industry waste

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Modification of Fluorgypsum as Cement Retarder

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Journal of Wuhan University of Technology(Materials Science) 2007年第4期22卷 745-748页

作者：王锦华 School of Materials Science and Engineering Wuhan University of Technology

The chemical composition and mineral structure of fluorgypsum as well as its harm to application in cement were elaborately analyzed. The primary fluorgypsum was modified and its applications in cement＇s production were studied. The technological flow chart of preparing modified fluorgypsum was given. Experimental results indicate that hydration ratio the modified fluorgypsum through adding compound additive for 14d is about 70%. The modified fluorgypsum as cement retarder has certain stimulation to fly ash and increases the strength of compound cement. In addition, its adding amount is lower than that of natural gypsum. The modified fluorgypsum is a good substitute for natural gypsum.

关键词： fluorgypsum industry waste modification cement retarder

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