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Effects of hot-pressing parameters on microstructure and mechanical properties of composites synthesized by Al-TiO_(2) in-situ reaction

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中国科学:技术科学英文版 2023年第9期66卷 2725-2734页

作者： LIU Yin CHEN WanQi GU LiMing LI XiaoNan ZAN YuNing WANG QuanZhao WANG Dong XIAO BoLv MA ZongYi School of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Shi-changxu Innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Nuclear Equipment Division Beijing Institute of Nuclear EngineeringChina Nuclear Power Engineering Co.Ltd.Beijing 100840China

As a classic in-situ reaction, the Al-TiO_(2) reaction is expected to prepare aluminum matrix composites with high thermal stability.In this study, it was found that the preparation method of ensuring sufficient reaction using higher temperatures in previous studies was not conducive to acquiring optimized high-temperature strength. With the increase of hot-pressing temperature and the extension of holding time, the in-situ reaction became more thorough, but the strength of the composites first increased and then decreased. Coarsening of the microstructure at high temperatures would lead to degradation of strength and controlling the in-situ reaction process by the hot-pressing parameters could optimize the mechanical properties of the composites. Strengthening mechanisms at room and high temperatures were studied, and it was found that the load-transfer and Orowan strengthening mechanisms are the main strengthening effects at room temperature, while the pinning effect of fine particles became more crucial at elevated temperatures. As a result, the coarsening of the reinforcing phases was more detrimental to the hightemperature strength. Therefore, an insufficient in-situ reaction led to more excellent mechanical properties, and the composite hot-pressed at 605℃ and held for 2 h exhibited the highest strength, which was 367 MPa at room temperature and 170 MPa at 350℃.

关键词： metal matrix composites high energy ball milling high-temperature properties nanoparticles in-situ reaction

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Microstructure and mechanical properties of Fe/NbC composite layer prepared by in-situ reaction

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China Foundry 2023年第4期20卷 356-364页

作者： Le Chen Ji-lin Li Meng-jun Wang Jie Zheng Yao Zhu Zhuo-lin Liu Bing-gui Lü School of Materials Science and Engineering Central South UniversityChangsha 410083China School of Materials Science and Engineering Xi'an University of TechnologyXi'an 710048China Institute of New Materials Guangdong Academy of SciencesGuangzhou 510650China Guangdong Provincial Key Laboratory of Metal Toughening Technology and Application Guangzhou 510650China Guangdong Guangyun New Material Co. Ltd.Yunfu 527527GuangdongChina Yunfu Guangyun Technology R&D Co. Ltd.Yunfu 527527GuangdongChina

NbC ceramic surface-reinforced steel matrix composites were prepared by an in-situ reaction method at different temperatures(1,050℃,1,100℃and 1,150℃)for different times(1 h,2 h and 3 h).The phase constitution,microstructure and fracture morphology of NbC ceramic surface-reinforced steel matrix composites were analyzed by XRD,SEM and EDS,and the effects of the in-situ reaction temperature and time on the mechanical properties were systematically studied.The results indicate that the NbC reinforcement layer is formed through the reaction between Nb atoms and carbon atoms diffused from the steel matrix to the Nb plate.The thickness of this reinforcement layer increases as the reaction time prolongs.Additionally,an increase in reaction temperature results in a thicker reinforcement layer,although the rate of increase gradually decreases.The relationship among the thickness of the Nb C reinforcement layer,the reaction time and temperature was established by data fitting.The optimal tensile performance is achieved at 1,100℃for 1 h,with a tensile strength of 228 MPa.It is also found that the defects between the reinforcement layer and the steel matrix are related to reaction temperature.At 1,100℃,these defects are minimal.Fracture mostly occurs in the NbC reinforced layer of the composites,and the fracture mode is characterized by typical intergranular brittle fracture.

关键词： in-situ reaction NbC reinforcement layer microstructure mechanical property

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Dense copper azide synthesized by in-situ reaction of assembled nanoporous copper microspheres and its initiation performance

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Defence Technology（防务技术） 2022年第6期18卷 1065-1072页

作者： Xing-yu Wu Ming-yu Li Qing-xuan Zeng Qing-xia Yu State Key Laboratory of Explosion and Technology Beijing Institute of TechnologyBeijing100081PR China

Copper azide with high density was successfully synthesized by in-situ reaction of nanoporous copper(NPC)precursor with HN_(3) gaseous.NPC with pore size of about 529 nm has been prepared by electroless plating using polystyrene(PS)as templates.The copper shells thickness of NPC was controlled by adjusting the PS loading amount.The effects of copper shell on the morphology,structure and density of copper azide were investigated.The conversion increased from 87.12%to 95.31%when copper shell thickness decrease from 100 to 50 nm.Meanwhile,the density of copper azide prepared by 529 nm NPC for 24 h was up to 2.38 g/cm^(3).The hollow structure of this NPC was filled by swelling of copper azide which guaranteed enough filling volume for keeping the same shape as well as improving the charge density.Moreover,HNS-IV explosive was successfully initiated by copper azide with minimum charge thickness of 0.55 mm,showing that copper azide prepared has excellent initiation performance,which has more advantages in the application of miniaturized explosive systems.

关键词： Nanoporous copper Electroless plating in-situ reaction Copper azide

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Microstructure and Mechanical Property of (TiNbTaZrHf)C Synthesized by in-situ reaction

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Journal of Wuhan University of Technology(Materials Science) 2022年第2期37卷 177-183页

作者：周庆张金咏 FU Zhengyi WANG Dangqiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The(TiNbTaZrHf)C high entropy carbide(HEC)was successfully synthesized by complete commercial transition metal powders,obtained fine sintered bulks without additives by in-situ reaction element synthesis method.(TiNbTaZrHf)C bulk shows a face centered cubic rock salt structure with homogeneous single-phase FCC structure in composition and structure.The optimum sintering temperature is about 1900℃at which the best mechanical properties are obtained.The mechanical properties of(TiNbTaZrHf)C ceramic block are better than those of binary transition metal carbides,and it has obvious high entropy effect.Adding a small amount of Al as sintering additive,the mechanical properties of(TiNbTaZrHf)C ceramics continue to improve,the bending strength of the samples at each temperature is increased by at least 38%,and the highest is 486 MPa.The elastic modulus and hardness of the sample at 1900℃are also slightly increased by 4%and 14%,respectively.The above conclusions illustrate that the properties of high entropy ceramics are greatly improved by in-situ reaction sintering.

关键词： high entropy carbide in-situ reaction microstructure mechanical property sintering additive

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PARTICLES ANALYSIS OF Al_2O_3 PARTICLE REINFORCED ZL202 MATRIX COMPOSITES PREPARED BY in-situ reaction

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Acta Metallurgica Sinica(English Letters) 2002年第6期15卷 531-537页

作者： X.H. Yan, S.C. Sun and Z.Y. JiangSchool of Materials Science and Engineering, Jiangsu University, Jiangsu 212013, China School of Materials Science and Engineering Jiangsu University Jiangsu 212013 China

ZL202 matrix composite reinforced by Al2O3 particles was prepared by combining in-situ reaction and casting techniques. Particles' size in the composites was from 1 to 5 microns in diameter. X-ray diffraction analysis verified that the reinforcing particleswere δ-Al2O3 which belong to γ-Al2O3 series. The wetting angle between matrix andreinforcement was less than 90°. Energy spectrum analysis indicated that the reactionin bell cover pressing process took place not so completely as in flouring stir process. When the reaction was finished, the matrix was still ZL202 alloy in both.processes.

关键词： metal matrix composites in-situ reaction particles

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Microstructure and Properties of A IN Coating/Graphite Fabricated via in-situ reaction

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Journal of Wuhan University of Technology(Materials Science) 2007年第4期22卷 718-721页

作者：贾铁昆 State Key Lab of Advanced Technology for Material Synthesis and Processing Wuhan University of Technology

A novel method was used to fabricate AlN coating on graphite substrate. This approach included two steps： firstly, the emulsion composed of BN and anhydrous ethanol was sprayed on the surface of the graphite substrate; secondly, AlN coating was formed through the in-situ reaction of Al with the sprayed BN. The reaction was investigated by thermogravimetric-differential thermal analysis （TG-DTA）, and the phase composition in the synthetic process was characterized by X-ray diffraction （XRD）. Scanning electronic microscopy （SEM） was used to observe the morphology, and electron probe microanalysis （EPMA） was used to observe the distribution of the elements. The experimental results show that the AlN coating is dense and bonded with graphite tightly.

关键词： in-situ reaction AlN coating nitridation spray interface

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Boosting Zn^(2+)kinetics via the multifunctional pre-desolvation interface for dendrite-free Zn anodes

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Journal of Energy Chemistry 2023年第2期77卷 632-641,I0016页

作者： Bin Luo Yang Wang Leilei Sun Sinan Zheng Guosheng Duan Zhean Bao Zhizhen Ye Jingyun Huang State Key Laboratory of Silicon Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027ZhejiangChina Institute of Wenzhou Zhejiang UniversityWenzhou 325006ZhejiangChina Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Taiyuan 030032ShanxiChina

Aqueous zinc ion batteries(AZIBs)are an advanced secondary battery technology to supplement lithiumion batteries.It has been widely concerned and developed recently based on the element abundance and safety advantages.However,AZIBs still suffer from serious problems such as dendrites Zn,hydrogen evolution corrosion,and surface passivation,which hinder the further commercial application of AZIBs.Herein,an in-situ ZnCr_(2)O_(4)(ZCO)interface endows AZIBs with dendrite-free and ultra-low polarization by realizing Zn^(2+)pre-desolvation,constraining H2O-induced corrosio n,and boosting Zn^(2+)transport/deposition kinetics.The ZCO@Zn anode harvests an ultrahigh cumulative capacity of~20000 mA h cm^(-2)(cycle time:over 4000 h)at a high current density of 10 mA cm^(-2),indicating excellent reversibility of Zn deposition,Such superior performance is among the best cyclability in AZIBs.Moreover,the multifunctional ZCO interface improves the Coulombic efficiency(CE)to 99.7%for more than 2600 cycles.The outstanding electrochemical performance is also verified by the long-term cycle stability of ZCO@Zn//α-MnO_(2) full cells.Notably,the as-proposed method is efficient and low-cost enough to enable mass production.This work provides new insights into the uniform Zn electrodeposition at the scale of interfacial Zn^(2+)predesolvation and kinetics improvement.

关键词： Zinc ion battery Dendrite-free Zn anode in-situ reaction Pre-desolvation Zn^(2+)kinetics

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Mechanical strength and corrosion resistance of Al-additive friction stir welded AZ31B joints

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Journal of Magnesium and Alloys 2023年第5期11卷 1519-1535页

作者： Jae-Yeon Kim Eun-Woo Kim Dong-O Kim Eun-Kyo Ju Ji-Eun Lee Jaeheon Lee Jai-Won Byeon Mining Engineering Department Colorado School of MinesGoldenCO 80401USA Department of Materials Science and Engineering Seoul National University of Science and TechnologySeoul 01811Republic of Korea

Compared to other structural alloys,magnesium alloys have a relatively poor corrosion resistance and low mechanical strength,which can be further deteriorated when these alloys are subjected to joining processes using the existing joining methods.Herein,we propose for the first time an additive friction stir-welding(AFSW)using fine Al powder as an additive to improve the mechanical strength as well as corrosion resistance of AZ31B weld joints.AFSW is a solid-state welding method of forming a high-Al AZ31B joint via an in-situ reaction between pure Al powders filled in a machined groove and the AZ31B matrix.To optimize the process parameters,AFSW was performed under different rotational and transverse speeds,and number of passes,using tools with a square or screw pin.In particular,to fabricate a weld zone,where the Al was homogenously dispersed,the effects of the groove shape were investigated using three types of grooves:surface one-line groove,surface-symmetric grooves,and inserted symmetric grooves.The homogenous and defect-less AFS-welded AZ31B joint was successfully fabricated with the following optimal parameters:1400 rpm,25 mm/min,four passes,inserted symmetric grooves,and the tool with a square pin.The AFSW fully dissolved the additive Al intoα-Mg and in-situ precipitated Mg_(17)Al_(12)particles,which was confirmed via scanning electron microscopy,transmission electron microscope,and X-ray diffraction analyses.The microhardness,joint efficiency,and elongation at the fracture point of the AFS-welded AZ31B joint were 80 HV,101%,and 8.9%,respectively.These values are higher than those obtained for the FS-welded AZ31 joint in previous studies.The corrosion resistance of the AFS-welded AZ31B joint,evaluated via hydrogen evolution measurements and potentiodynamic polarization tests,was enhanced to 55%relative to the FS-welded AZ31B joint.

关键词： AZ31B magnesium alloy Additive friction stir-welding in-situ reaction Mg_(17)Al_(12)particles Joint efficiency Corrosion resistance

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In-situ construction of hybrid artificial SEI with fluorinated siloxane to enable dendrite-free Li metal anodes

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Journal of Materiomics 2023年第2期9卷 318-327页

作者： Lei Wei Zhaoqing Jin Jianhao Lu Yang Guo Zilong Wang Gaoping Cao Jingyi Qiu Anbang Wang Weikun Wang State Key Laboratory of NBC Protection for Civilian Beijing102205China Research Institute of Chemical Defense Beijing100191China Beijing Key Laboratory of Electrochemical Process and Technology for Materials Beijing University of Chemical TechnologyBeijing100029China

Lithium(Li)metal anode holds great promise for high-energy-density rechargeable batteries.However,it suffers from the Li dendrites growth and uncontrollable side reactions with electrolyte due to the unstable solid electrolyte interphase(SEI)layer.Herein,we propose a facile strategy for the in-situ fabricate of organic-inorganic composite artificial SEI layers on Li surfaces,which consist of organic fluorinated siloxane and inorganic LiF-rich phases.The hybrid artificial SEI endows high mechanical strength(13.1 GPa)and Liþtransfer number(0.62).Such robust SEI protective layers can not only guide uniform nucleation and deposition of Li metal by facilitating uniform Li-ion distribution,but also prevent unfavourable side reactions.Accordingly,the protected metallic lithium anode(PMTFPS-Li)anode enables stable Li plating/stripping performance in symmetric cells for more than 300 h at 4 mA$h/cm^(2)under a high areal capacity of 4 mA/cm^(2).Moreover,the PMTFPS-Li/S cells could maintain more than 300 stable cycles at 0.5C and the PMTFPS-Li/LFP cells present excellent cycling performance(400 cycles at 1C)and enhanced rate capability(110.4 mA$h/g at 3 C).This work will inspire the design of artificial SEI on Li anodes for advanced Li metal batteries.

关键词： Fluorinated siloxane Lithium metal anode Dendrite growth Artificial SEI in-situ reaction

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Nanoceramic composites with duplex microstructure break the strength-toughness tradeoff

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Journal of Materials Science & Technology 2020年第23期58卷 1-9页

作者： Ji Zou Hai-Bin Ma Jing-Jing Liu Wei-Min Wang Guo-Jun Zhang Zheng-Yi Fua State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China School of Metallurgy and Materials University of BirminghamB152TTBirminghamUK China Nuclear Power Technology Research Institute Shenzhen518026China State Key Laboratory for Modification of Chemical Fibers and Polymer Materials Institute of Functional MaterialsDonghua UniversityShanghai201620China

There is a strength and fracture toughness tradeoff in nanoceramic composite. The strength varies reciprocally with the grain size whereas the toughness contributed by compressive residual stress increases with the dimension of the second phase. In this work, a novel duplex microstructure with reinforced clusters composing of nanosized grains was proposed and validated using a model system of B_(4)C-TiB_(2) ceramics densified by carbide boronizing. As-obtained ceramics exhibit excellent combined mechanical properties at room temperature, including Vickers hardness, Young's modulus, flexural strength and fracture toughness(by surface crack in flexure method) of 32.1 ± 2.7 GPa, 506.9 ± 2.0 GPa,1175 ± 71 MPa and 5.1 ± 0.4 MPa m^(0.5), respectively. Both strength and toughness are at least ~30 % higher than the counterparts with similar composition but homogenously distributed TiB_(2) grains. Graphite onion was confirmed to be an intermediate product during reactive sintering, it facilitated the grain pullout during fracture and retained the nanometric TiB_(2) grain in the cluster, both of which also contribute the toughening and strengthening mechanisms in the B_(4)C-TiB_(2) ceramics.

关键词： Borides Microstructure in-situ reaction Mechanical properties Boron carbide Ceramics

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