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Hybrid effect on mechanical properties and high-temperature performance of copper matrix composite reinforced with micro-nano dual-scale particles

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Journal of Materials Science & Technology 2024年第5期172卷 94-103页

作者： Xingde Zhang Yihui Jiang Fei Cao Tian Yang Fan Gao Shuhua Liang School of Materials Science and Engineering Xi’an University of TechnologyXi’an 710048China Engineering Research Center of Conducting Materials and Composite Technology Ministry of EducationXi’an University of TechnologyXi’an 710048China Shaanxi Province Key Laboratory of Electrical Materials and Infiltration Technology Xi’an University of TechnologyXi’an 710048China

A dual-scale hybrid HfB_(2)/Cu-Hf composite with HfB_(2) microparticles and Cu_(5) Hf nanoprecipitates was designed and prepared.The contribution of the hybrid effect to the mechanical properties and high-temperature performances was studied from macro and micro perspectives,respectively.The hybrid of dual-scale particles can make the strain distribution of the composite at the early deformation stage more uniform and delay the strain concentration caused by the HfB_(2) particle.The dislocation pinning of HfB_(2) particles and the coherent strengthening of Cu_(5) Hf nanoprecipitates simultaneously play a strengthening role,but the strength of the hybrid composite is not a simple superposition of two strengthening mod-els.In addition,both Cu_(5) Hf nanoprecipitates and HfB_(2) microparticles contribute to the high-temperature performance of the composite,the growth and phase transition of nanoprecipitates at high temperature will reduce their contribution to strength,while the stable HfB_(2) particles can inhibit the coarsening of matrix grains and maintain the high-density geometrically necessary dislocations(GNDs)in the matrix,which ensures more excellent high-temperature resistance of the hybrid composite.As a result,the hy-brid structure can simultaneously possess the advantages of multiple reinforcements and make up for the shortcomings of each other.Finally,a copper matrix composite with high strength,high conductivity,and excellent high-temperature performance is displayed.

关键词： Copper matrix composite HfB 2 particles Hybrid effect high strength and high conductivity high-temperature performance

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Effect of crystal morphology of ultrahigh-nickel cathode materials on high temperature electrochemical stability of lithium ion batteries

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Journal of Energy Chemistry 2024年第1期88卷 327-335,I0008页

作者： Bi Luo Hui Li Haoyu Qi Yun Liu Chuanbo Zheng Weitong Du Jiafeng Zhang Lai Chen School of Metallurgy Engineering Jiangsu University of Science and TechnologyZhangjiagang 215600JiangsuChina National Engineering Laboratory for high-Efficiency Recovery of Refractory Nonferrous Metals School of Metallurgy and EnvironmentCentral South UniversityChangsha 410083HunanChina School of Materials Science and Engineering Beijing Key Laboratory of Environmental Science and EngineeringBeijing Institute of TechnologyBeijing 100081China

higher nickel content endows Ni-rich cathode materials LiNi_(x)Co_yMn_(1-x-y)O_(2)(x>0.6)with higher specific capacity and high energy density,which is regarded as the most promising cathode materials for Li-ion batteries.However,the deterioration of structural stability hinders its practical application,especially under harsh working conditions such as high-temperature cycling.Given these circumstances,it becomes particularly critical to clarify the impact of the crystal morphology on the structure and high-temperature performance as for the ultrahigh-nickel cathodes.Herein,we conducted a comprehensive comparison in terms of microstructure,high-temperature long-cycle phase evolution,and high-temperature electrochemical stability,revealing the differences and the working mechanisms among polycrystalline(PC),single-crystalline(SC)and Al doped SC ultrahigh-nickel materials.The results show that the PC sample suffers a severe irreversible phase transition along with the appearance of microcracks,resulting a serious decay of both average voltage and the energy density.While the Al doped SC sample exhibits superior cycling stability with intact layered structure.In-situ XRD and intraparticle structural evolution characterization reveal that Al doping can significantly alleviate the irreversible phase transition,thus inhibiting microcracks generation and enabling enhanced structure.Specifically,it exhibits excellent cycling performance in pouch-type full-cell with a high capacity retention of 91.8%after 500 cycles at 55℃.This work promotes the fundamental understanding on the correlation between the crystalline morphology and high-temperature electrochemical stability and provides a guide for optimization the Ni-rich cathode materials.

关键词： Single-crystalline Ultrahigh-nickel cathode high-temperature performance Phase evolution

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Enhanced high-temperature performance of Li-rich layered oxide via surface heterophase coating

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Journal of Energy Chemistry 2020年第12期29卷 39-47页

作者： Yuefeng Su Feiyu Yuan Lai Chen Yun Lu Jinyang Dong Youyou Fang Shi Chen Feng Wu Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing Institute of Technology Chongqing Innovation Center Chongqing 401120China

Li-rich layered oxides have become one of the most concerned cathode materials for high-energy lithiumion batteries, but they still suffer from poor cycling stability and detrimental voltage decay, especially at elevated temperature. Herein, we proposed a surface heterophase coating engineering based on amorphous/crystalline Li3 PO4 to address these issues for Li-rich layered oxides via a facile wet chemical method. The heterophase coating layer combines the advantages of physical barrier effect achieved by amorphous Li3 PO4 with facilitated Li+diffusion stemmed from crystalline Li3 PO4. Consequently, the modified Li(1.2) Ni(0.2) Mn(0.6) O2 delivers higher initial coulombic efficiency of 92% with enhanced cycling stability at 55 °C(192.9 mAh/g after 100 cycles at 1 C). More importantly, the intrinsic voltage decay has been inhibited as well, i.e. the average potential drop per cycle decreases from 5.96 mV to 2.99 mV. This surface heterophase coating engineering provides an effective strategy to enhance the high-temperature electrochemical performances of Li-rich layered oxides and guides the direction of surface modification strategies for cathode materials in the future.

关键词： Li-rich layered oxide Surface heterophase coating Crystalline/amorphous Li3PO4 high-temperature performance Voltage decay

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Anhydride type film-forming electrolyte additives for high-temperature LiNi0.6Co0.2Mn0.2O2//graphite pouch cells

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Progress in Natural Science:Materials International 2023年第3期33卷 320-327页

作者： Anwei Zhang Chengyun Wang Weizhen Fan Jingwei Zhao Yanping Huo Xijun Xu GAC Automotive Research &Development Center Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials School of Materials Science and Engineering South China University of Technology Research and Development Center Guangzhou Tinci Materials Technology Co. Ltd. College of Chemical Engineering and Light Industry Guangdong University of Technology

LiNi0.6Co0.2Mn0.2O2//graphite full cell, due to its high energy density as the most promising candidate for power batteries received increased attention, but the severe capacity loss under high-temperature conditions prevents their large-scale application. Here, glutaric anhydride(GA) and succinic anhydride(SA) as electrolyte additives are investigated to overcome the high-temperature problem of LiNi0.6Co0.2Mn0.2O2//graphite cells. Due to the unique film-forming features and high-temperature stability, the cells containing 0.5% GA and 0.5% SA can retain capacity retention of 91.2% and 92.4% stored at 60°C for 15 days, corresponding to a negligible capacity loss of 4.6 and 0.8 m Ah g-1after 200 cycles, respectively. In addition, the lifespans of cells under 25°C are also significantly extended by introducing GA and SA into the electrolytes. Electrochemical and spectroscopic techniques results indicate the full cell capacity loss is predominantly caused by the unstable anode solid electrolyte interphase(SEI) layer and a stable SEI film derived from GA and SA is formed on the graphite electrode surfaces.The SEI film can effectively inhibit the consumption of electrolytes and enhance the high-temperature performance of cells. This work paves a way for moderating high energy density cells’ work under high-temperature operation by developing special anodic film-forming electrolyte additives.

关键词： Anhydride-based Electrolyte additives Film-forming high-temperature performance LiNi0.6Co0.2Mn0.2O2//graphite

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Effect of quaternary basicity on reduction behavior of iron-bearing dust pellets

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Journal of Iron and Steel Research(International) 2023年第7期30卷 1356-1366页

作者： Tao Yang Jing-shu An Xing-wang Li Shuang Liu Xu Gao Lei Ma Jie Lei Hong-ming Long School of Metallurgical Engineering Anhui University of TechnologyMa’anshan 243032AnhuiChina Key Laboratory of Metallurgical Emission Reduction&Resources Recycling(Anhui University of Technology) Ministry of EducationMa’anshan 243002AnhuiChina

The treatment of iron-bearing dusts and sludges by the rotary hearth furnace process has the advantage of sufficient utilization of valuable metals and a high impurity removal rate,but the lower strength of the metallized product needs to be addressed.The effects of quaternary basicity R4(w(CaO+MgO)/w(SiO_(2)+Al_(2)O_(3)))on the reduction behavior and physical and chemical properties of metallized pellets,including phase composition,compressive strength,microstructure and soft melting area,were investigated with FactSage thermodynamic software and experiments.The strength of metallized pellets depended on the gangue composition,such as CaO,MgO,Al_(2)O_(3) and SiO_(2),due to the altered chemical composition,physical phase composition,microscopic morphology and stability of the slag phase.The reduction of carbon-bearing pellets was significantly promoted by suitable basicity.The lower basicity(R_(4)higher basicity(R_(4)>1.8)also increased the amount of liquid phase and improved the strength of the pellets,due to the granular iron crystals bonded into sheets.Notably,the main component of the liquid phase in high-basicity conditions was calcium ferrite.Although the additional amount of liquid phase was beneficial to the strength of the metallized pellets,calcium disilicate was formed at R_(4)=1.6,resulting in a reduction in the compressive strength of the pellets to 1521.9 N/pellet.

关键词： Metallurgical solid waste Iron-bearing dust Iron-bearing sludge Rotary hearth furnace Quaternary basicity Metallized pellet high-temperature performance Metallized pellet high-temperature performance

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Laboratory Study on CR/SBS Modified Asphalt:Preparation and performance Characterization

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Journal of Renewable Materials 2022年第6期10卷 1659-1674页

作者： Liang Song Guoqiang Zhang Hongfei Xie Jie Gao College of Transportation Engineering Tongji UniversityShanghai201804China Xinjiang Transportation Planning Surveying and Design Institute Urumqi830006China Xinjiang NABA Expressway Development Co. Ltd.Urumqi830006China School of Civil Engineering and Architecture East China Jiaotong UniversityNanchang330013China

Crumble rubber(CR)can be used to prepare CR and styrene-butadiene-styrene(SBS)composite modified asphalt with a good high-and low-temperature performance,meanwhile the addition of CR could work as the substitute for SBS and help reduce the content of SBS.This study contains three main parts:effect of preparation and effect of material composition as well as rheological performance characterization.Factors during the preparation,including shearing temperature,shearing time,mixing time and swelling time,were selected,while base binder,CR content,CR particle size and SBS content in material composition were considered.The effects of these factors were assessed in terms of the conventional performance(penetration,softening point,ductility and storage stability).After identifying these effects,the sample of CR and SBS modified asphalt at the selected preparing condition and material composition(CR/SBSMA)was made,and the corresponding SBS modified and CR modified asphalt(SBSMA and CRMA)were produced for the comparing reason.Subsequently,temperature sweeps from 0℃ to 80℃ were utilized to depict the viscoelasticity of these modified asphalt binders by complex modulus and phase angle.Multiple stress creep recovery tests(MSCR)at 64℃ and bending beam rheometer tests(BBR)at various low temperatures were employed to evaluate the high-and low-temperature performance,respectively.Results highlight that that CR/SBSMA could exhibit an excellent high-temperature performance(better than SBSMA),and a good low-temperature performance(reaching the level of base binder).

关键词： Crumble rubber styrene-butadiene-styrene preparation material composition high-temperature performance low-temperature performance

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