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Graphene enables equiatomic FeNiCrCoCu high-entropy alloy with improved TWIP and TRIP effects under shock compression

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Journal of Materials Science & Technology 2024年第3期170卷 186-199页

作者： Hongcai Xie Zhichao Ma Wei Zhang Hongwei Zhao Luquan Ren School of Mechanical and Aerospace Engineering Jilin UniversityChangchun 130025China Key Laboratory of CNC Equipment Reliability Ministry of Education Jilin UniversityChangchun 130025China Key Laboratory of Bionic Engineering Ministry of Education Jilin UniversityChangchun 130025China Weihai Institute for Bionics-Jilin University Weihai 264400China Institute of Structured and Architected Materials Liaoning Academy of MaterialsShenyang 110167China

Graphene(Gr)reinforced high-entropy alloy(HEA)matrix composites are expected as potential candidates for next-generation structural applications in light of outstanding mechanical properties.A deep comprehension of the underlying deformation mechanisms under extreme shock loading is of paramount importance,however,remains lacking due to experimentally technical limitations in existence.In the present study,by means of nonequilibrium molecular dynamics simulations,dynamic deformation behaviors and corresponding mechanisms in equiatomic FeNiCrCoCu HEA/Gr composite systems were investigated in terms of various shock velocities.The resistance to dislocation propagation imparted by Gr was corroborated to encourage the elevated local stress level by increasing the likelihood of dislocation interplays,which facilitated the onset of twins and hexagonal close-packed(HCP)martensite laths.Meanwhile,the advent of Gr was demonstrated to endow the HEA with an additional twinning pathway that induced a structural conversion from HCP to parent face-centered cubic(FCC)inside HCP martensite laths,different from the classical one that necessitated undergoing the intermediate procedure of extrinsic stacking fault(ESF)evolution.More than that,by virtue of an increase in flow stress,the transformation-induced plasticity(TRIP)effect was validated to be additionally evoked as the predominant strain accommodation mechanism at higher strains on the one hand,but which only assisted plasticity in pure systems,and on the other hand,can also act as an auxiliary regulation mode together with the twinning-induced plasticity(TWIP)effect under intermediate strains,but with enhanced contributions relative to pure systems.One may expect that TRIP and TWIP effects promoted by introducing Gr would considerably inspire a synergistic effect between strength and ductility,contributing to the exceptional shock-resistant performance of FeNiCrCoCu HEAs under extreme regimes.

关键词： Molecular dynamics high-entropy alloy Graphene TRIP TWIP Shock

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Abnormal mechanochemical effect in ultraprecision machining of an additively manufactured precipitation-strengthened high-entropy alloy

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Journal of Materials Science & Technology 2024年第3期170卷 221-237页

作者： Long Xu Yuchao Bai Yunfa Guo Chang Ren Xiaohua Tan Yandong Jia Gang Wang Hao Wang Institute of Materials Shanghai UniversityShanghai 200444China Zhejiang Institute of Advanced Materials Shanghai UniversityJiashan 314100China Department of Mechanical Engineering National University of SingaporeSingapore 117575Singapore

Recently,researchers have explored the use of precipitation strengthening and finer microstructures with high-density dislocations in additive manufacturing to produce high-entropy alloys(HEAs)with adjustable properties.However,the inherent surface roughness and lack of machinability research in AMed HEAs limit their engineering applications.In this study,we systematically investigated the microstructural characteristics,mechanical properties,and machinability of Fe_(29.3)Co_(28.7)Ni_(28.6)Al_(6.8)Ti_(6.6)(at.%)HEAs with three different structures:single FCC phase cellular(SPC),dual precipitation-strengthened(DPS),and single precipitation-strengthened(SPS).These structures were fabricated by selective laser melting and isothermally annealing at 780 and 940℃.Compared to SPC HEA,DPS HEA exhibits a significant increase in yield strength and ultimate tensile strength but with a dramatic sacrifice in ductility.SPS HEA exhibits similar mechanical properties to SPC HEA due to the pronounced coarsening of L21 precipitates.The ultraprecision machining micro-cutting test showed that SPC HEA had a significant mechanochem-ical effect,as evidenced by a sharp drop in cutting force for inked workpieces,but not DPS HEA.An abnormal finding was that the negligible reflection of cutting force for SPS HEAs suggested a negative mechanochemical effect,even though SPS HEA had equally excellent plasticity like SPC HEA.It was found that nanocrystallization-induced strength enhancement and ductility reduction of SPS HEA lead to chips’deformation dominated by shear avalanche rather than chip folding of SPC HEA,which involves the reduction of surface energy and friction of chips’interfaces.Overall,these results and our research findings may guide the machining of AMed precipitation-strengthened HEAs and accelerate their engineering ap-plication.

关键词： high-entropy alloy Selective laser melting Precipitation strengthening Machinability Mechanochemical effect

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Accelerated intermetallic phase amorphization in a Mg-based high-entropy alloy powder

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Journal of Magnesium and alloys 2024年第5期12卷 1792-1798页

作者： Prince Sharma Purvam Mehulkumar Gandhi Kerri-Lee Chintersingh Mirko Schoenitz Edward L.Dreizin Sz-Chian Liou Ganesh Balasubramanian Institute for Functional Materials&Devices Lehigh University Center of Materials for Advanced Energetics New Jersey Institute of Technology

We describe a novel mechanism for the synthesis of a stable high-entropy alloy powder from an otherwise immiscible Mg-Ti rich metallic mixture by employing high-energy mechanical milling. The presented methodology expedites the synthesis of amorphous alloy powder by strategically injecting entropic disorder through the inclusion of multi-principal elements in the alloy composition. Predictions from first principles and materials theory corroborate the results from microscopic characterizations that reveal a transition of the amorphous phase from a precursor intermetallic structure. This transformation, characterized by the emergence of antisite disorder, lattice expansion, and the presence of nanograin boundaries, signifies a departure from the precursor intermetallic structure. Additionally, this phase transformation is accelerated by the presence of multiple principal elements that induce severe lattice distortion and a higher configurational entropy. The atomic size mismatch of the dissimilar elements present in the alloy produces a stable amorphous phase that resists reverting to an ordered lattice even on annealing.

关键词： high-entropy alloy high-energy milling Antisite disorder Amorphous Intermetallic

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Enhanced antibacterial behavior of a novel Cu-bearing high-entropy alloy

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Journal of Materials Science & Technology 2022年第22期117卷 158-166页

作者： Guangyu Ren Lili Huang Kunling Hu Tianxin Li Yiping Lu Dongxu Qiao Haitao Zhang Dake Xu Tongmin Wang Tingju Li Peter K.Liaw Engineering Research Center of high entropy alloy Materials(Liaoning Province) School of Materials Science and EngineeringDalian University of TechnologyDalian 116024China College of Food Science and Engineering Ocean University of ChinaQingdao 266100China Shenyang National Laboratory for Materials Science Northeastern UniversityShenyang 110819China Department of Materials Science and Engineering The University of TennesseeKnoxvilleTN 37996United States

Contact infection of bacteria and viruses has been a critical threat to human health. The worldwideoutbreak of COVID-19 put forward urgent requirements for the research and development of the selfantibacterial materials, especially the antibacterial alloys. Based on the concept of high-entropy alloys, thepresent work designed and prepared a novel Co_(0.4)FeCr_(0.9)Cu_(0.3) antibacterial high-entropy alloy with superior antibacterial properties without intricate or rigorous annealing processes, which outperform the antibacterial stainless steels. The antibacterial tests presented a 99.97% antibacterial rate against Escherichiacoli and a 99.96% antibacterial rate against Staphylococcus aureus after 24 h. In contrast, the classic antibacterial copper-bearing stainless steel only performed the 71.50% and 80.84% antibacterial rate, respectively. The results of the reactive oxygen species analysis indicated that the copper ion release and theimmediate contact with copper-rich phase had a synergistic effect in enhancing antibacterial properties.Moreover, this alloy exhibited excellent corrosion resistance when compared with the classic antibacterialstainless steels, and the compression test indicated the yield strength of the alloy was 1015 MPa. Thesefindings generate fresh insights into guiding the designs of structure-function-integrated antibacterial alloys.

关键词： high-entropy alloy Antibacterial property Corrosion resistance Mechanical property

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high-entropy-alloy nanoparticles with 21 ultra-mixed elements for efficient photothermal conversion

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National Science Review 2022年第6期9卷 124-134页

作者： Yijun Liao Yixing Li Rongzhi Zhao Jian Zhang Lizhong Zhao Lianze Ji Zhengyu Zhang Xiaolian Liu Gaowu Qin Xuefeng Zhang Key Laboratory for Anisotropy and Texture of Materials (MOE) School of Materials Science and EngineeringNortheastern University Institute of Advanced Magnetic Materials College of Materials and Environmental EngineeringHangzhou Dianzi University

Multi-metallic nanoparticles have been proven to be an efficient photothermal conversion material, for which the optical absorption can be broadened through the interband transitions(IBTs), but it remains a challenge due to the strong immiscibility among the repelling combinations. Here, assisted by an extremely high evaporation temperature, ultra-fast cooling and vapor-pressure strategy, the arc-discharged plasma method was employed to synthesize ultra-mixed multi-metallic nanoparticles composed of 21 elements(FeCoNiCrYTiVCuAlNbMoTaWZnCdPbBiAgInMnSn), in which the strongly repelling combinations were uniformly distributed. Due to the reinforced lattice distortion effect and excellent IBTs, the nanoparticles can realize an average absorption of >92% in the entire solar spectrum(250 to 2500 nm). In particular, the 21-element nanoparticles achieve a considerably high solar steam efficiency of nearly 99%under one solar irradiation, with a water evaporation rate of 2.42 kg m-2h-1, demonstrating a highly efficient photothermal conversion performance. The present approach creates a new strategy for uniformly mixing multi-metallic elements for exploring their unknown properties and various applications.

关键词： high-entropy alloy nanoparticle ultra-mixing arc-discharged method photothermal conversion

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Dual precipitate simultaneous enhancement of tensile and fatigue strength in(FeCoNi)_(86)Al_(7)Ti_(7) high-entropy alloy fabricated using selective laser melting

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Journal of Materials Science & Technology 2023年第17期148卷 90-104页

作者： Long Xu Yandong Jia Zhenhui Wang Shiwei Wu Yuefei Jia Chuan Geng Jianchao Peng Xiaohua Tan Gang Wang Institute of Materials Shanghai UniversityShanghai 200444China Zhejiang Institute of Advanced Materials Shanghai UniversityJiashan 314100China Department of Mechanical Engineering National University of Singapore9 Engineering Drive 1Singapore 117575Singapore Laboratory for Microstructures Shanghai UniversityShanghai 200444China

Recent studies have indicated that precipitation-strengthened high-entropy alloys(HEAs)show superior mechanical performance and have been successfully fabricated by additive manufacturing.However,the lack of fatigue and fracture research has limited the engineering applications of additive manufacturing HEAs.This work explored a dual precipitation-strengthened(FeCoNi)_(86)Al_(7)Ti_(7) HEA with excellent tensile and fatigue strength,prepared through selective laser melting and heat treatment.Compared with the as-built samples,the tensile properties and fatigue endurance limit improved through aging by 48.7%and 30%,respectively.The strengthening mechanism and enhanced fatigue performance were clarified in detail.The improvement in fatigue strength was attributed to the improved resistance of the L1_(2) and L2_(1) precipitates.During deformation,the dislocation shear coherent L1_(2) precipitates reduced slip band energy and inhibited slip band expansion,while the L2_(1) particles acted as obstructions for further slip band propagation,severely limiting the rapid formation and propagation of crack growth.In-situ TEM cyclic tensile-tensile testing also clarified the fatigue crack growth behavior,demonstrating that crack deflection due to L2_(1) precipitate obstruction slowed down the crack growth rate and efficiently promoted the closure of the microcrack tips.This work offers im plications for a new strategy to develop additive manufacturing HEAs.

关键词： high-entropy alloy Selective laser melting Precipitation strengthening Fatigue Crack deflection

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Strengthening behavior of AlCoCrFeNi(TiN)_(x) high-entropy alloy coatings fabricated by plasma spraying and laser remelting

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Journal of Materials Science & Technology 2022年第26期121卷 163-173页

作者： Bingqian Jin Nannan Zhang Shuo Yin Department of Material Science and Engineering Shenyang University of TechnologyShenyang 110870China Department of Mechanical Manufacturing and Biomedical EngineeringTrinity College DublinThe University of DublinParsons BuildingDublin 2Ireland

high-entropy alloy(HEA)coatings are of great importance in the fabrication of wear resistance materials.HEA coatings containing ceramic particles as reinforcement phase usually have better wear performance.In this study,AlCoCrFe Ni(TiN)_(x)(x:molar ratio;x=0,0.2,0.4,0.6,0.8,1.0)HEA coatings were fabricated on Q235 steel by plasma spray first and then subjected to laser remelting.The experimental results confirm that plasma spray together with post laser remelting could result in the in-situ formation of TiN-Al_(2)O_(3) ceramic particles and cuboidal B2 phase in the AlCoCrFeNi(TiN)_(x) HEA coatings.The in-situ TiN-Al_(2)O_(3) and nano-cuboidal B2 precipitation phase strengthened the coatings and improved their wearresistance properties.Due to the dispersion of hard phase and nano-particles resulting from second heating,the microhardness of the Al Co Cr Fe Ni(Ti N)coatings significantly increased from 493 to 851 HV after laser remelting.For the same reasons,the wear-resistance performance was also significantly promoted after laser remelting.

关键词： high-entropy alloy Coatings Ceramics Laser remelting Microstructure Wear resistance

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high-entropy alloy nanoparticles as a promising electrocatalyst to enhance activity and durability for oxygen reduction

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Nano Research 2022年第9期15卷 7868-7876页

作者： Yanan Yu Fanjie Xia Chengjie Wang Jinsong Wu Xianbiao Fu Dongsheng Ma Bencai Lin Jiaao Wang Qin Yue Yijin Kang Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Nanostructure Research CenterWuhan University of TechnologyWuhan 430070China Jiangsu Province Cultivation base for State Key Laboratory of Photovoltaic Science and Technology Changzhou UniversityChangzhou 213164China Department of Chemistry and the Oden Institute for Computational Engineering and Sciences The University of Texas at AustinTX 78712USA

Developing efficient platinum-based electrocatalysts with super durability for the oxygen reduction reaction(ORR)is highly desirable to promote the large-scale commercialization of fuel cells.Although progress has been made in this aspect,the electrochemical kinetics and stability of platinum-based catalysts are still far from the requirements of the practical applications.Herein,PtPdFeCoNi high-entropy alloy(HEA)nanoparticles were demonstrated via a high-temperature injection method.PtPdFeCoNi HEA nanocatalyst exhibits outstanding catalytic activity and stability towards ORR due to the high entropy,lattice distortion,and sluggish diffusion effects of HEA,and the HEA nanoparticles delivered a mass activity of 1.23 A/mgPt and a specific activity of 1.80 mA/cmPt 2,which enhanced by 6.2 and 4.9 times,respectively,compared with the values of the commercial Pt/C catalyst.More importantly,the high durability of PtPdFeCoNi HEA/C was evidenced by only 6 mV negativeshifted half-wave potential after 50,000 cycles of accelerated durability test(ADT).

关键词： high-entropy alloy oxygen reduction reaction electrocatalyst high durability

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Ultrasound-driven fabrication of high-entropy alloy nanocatalysts promoted by alcoholic ionic liquids

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Nano Research 2022年第6期15卷 4792-4798页

作者： Francis Okejiri Zhenzhen Yang Hao Chen Chi-Linh Do-Thanh Tao Wang Shize Yang Sheng Dai Department of Chemistry The University of TennesseeKnoxvilleTN 37996USA Chemical Sciences Division Oak Ridge National LaboratoryOak RidgeTN 37831USA Center for Functional Nanomaterials Brookhaven National LaboratoryUptonNew York 11973USA Eyring Materials Center Arizona State UniversityTempeAZ 85287USA

high-entropy alloy nanoparticles(HEA-NPs)are highly underutilized in heterogeneous catalysis due to the absence of a reliable,sustainable,and facile synthetic method.Herein,we report a facile synthesis of HEA nanocatalysts realized via an ultrasounddriven wet chemistry method promoted by alcoholic ionic liquids(AILs).Owing to the intrinsic reducing ability of the hydroxyl group,AILs were synthesized and utilized as environmentally friendly alternatives to conventional reducing agents and volatile organic solvents in the synthetic process.Under high-intensity ultrasound irradiation,Au^(3+),Pd^(2+),Pt^(2+),Rh^(3+),and Ru^(3+)ions were coreduced and transformed into single-phase HEA(AuPdPtRhRu)nanocrystals without calcination.Characterization results reveal that the as-synthesized nanocrystals are composed of elements of Au,Pd,Pt,Rh,and Ru as expected.Compared to the monometallic counterparts such as Pd-NPs,the carbon-supported HEA nanocatalysts show superior catalytic performance for selective hydrogenation of phenol to cyclohexanone in terms of yield and selectivity.Our synthetic strategy provides an improved and facile methodology for the sustainable synthesis of multicomponent alloys for catalysis and other applications.

关键词： high-entropy alloy alcoholic ionic liquid sustainability ultrasonication nanoparticles hydrogenation

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Atomic scale structure dominated FCC and B2 responses to He ion irradiation in eutectic high-entropy alloy AlCoCrFeNi_(2.1)

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Journal of Materials Science & Technology 2022年第34期129卷 87-95页

作者： Jingyu Pang Ting Xiong Wenfan Yang Hualong Ge Xiaodong Zheng Miao Song Hongwei Zhang Shijian Zheng Institute of Metal Research Chinese Academy of Sciences7Shenyang 110016China School of Material Science and Engineering University of Science and Technology of ChinaShenyang 110016China Ji Hua Laboratory Foshan 528251China School of Nuclear Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Reliability and Intelligence of Electrical Equipment Hebei University of TechnologyTianjin 300130China

Radiation-tolerant materials are widely desired in nuclear reactors. high-entropy alloys(HEAs) exhibiting superior mechanical performance and swelling tolerance are being considered as next-generation nuclear structural materials. However, an understanding of HEAs irradiation tolerance at an atomic scale is still lacking. In this study, the atomic scale irradiation response of AlCoCrFeNi_(2.1), composed of face-centered cubic(FCC) phase and B2 phase, has been systematically investigated at 298 and 723 K. The bubble volume ratio of the B2 phase is much larger than that of the FCC phase under the same irradiation conditions, and hence, the FCC phase has superior swelling tolerance than the B2 phase. Also, order-disorder transformation occurred in both L12and B2 phases. The different irradiation responses between the FCC and B2 phases, depend firstly on composition and secondly on crystal structure. The higher compositional complexity and complicated atomic-level lattice environment of the FCC phase contribute to better radiation performance than B2 phase. The results pave a way for exploring radiation-tolerant structural high-entropy alloys.

关键词： high-entropy alloy AlCoCrFeNi_(2.1) He ion irradiation Radiation tolerance Electron microscopy

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