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Extreme high reversible capacity with over 8.0 wt% and excellent hydrogen storage properties of MgH2 combined with LiBH4 and Li3AlH6

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Journal of Energy Chemistry 2020年第11期29卷 296-306页

作者： Wenping Lin Xuezhang Xiao Xuancheng Wang Jie-Wei Wong Zhendong Yao Man Chen Jiaguang Zheng Zhencan Hu Lixin Chen State Key Laboratory of Silicon Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027ZhejiangChina Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province.Hangzhou 310013 ZhejiangChina Guangdong Provincial Key Laboratory of Advance Energy Storage Materials South China University of TechnologyGuangzhou 510640GuangdongChina

Magnesium hydride has attracted great attention because of its high theoretical capacity and outstanding reversibility, nevertheless, its practical applications have been restricted by the disadvantages of the sluggish kinetics and high thermodynamic stability. In this work, an unexpected high reversible hydrogen capacity over 8.0 wt% has been achieved from MgH2 metal hydride composited with small amounts of LiBH4 and Li3AlH6 complex hydrides, which begins to release hydrogen at 276 ℃ and then completely dehydrogenates at 360 ℃. The dehydrogenated MgH2+LiBH4/Li3AlH6 composite can fully reabsorb hydrogen below 300 ℃ with an excellent cycling stability. The composite exhibits a significant reduction of dehydrogenation activation energy from 279.7 kJ/mol(primitive MgH2) to 139.3 kJ/mol(MgH2+LiBH4/Li3AlH6),as well as a remarkable reduction of dehydrogenation enthalpy change from 75.1 k J/mol H2(primitive MgH2) to 62.8 kJ/mol H2(MgH2+LiBH4/Li3AlH6). The additives of LiBH4 and Li3AlH6 not only enhance the cycling hydrogen capacity, but also simultaneously improve the reversible de/rehydrogenation kinetics, as well as the dehydrogenation thermodynamics. This notable improvement on the hydrogen absorption/desorption behaviors of the MgH2+LiBH4/Li3AlH6 composite could be attributed to the dehydrogenated products including Li3Mg7, Mg17Al12 and MgAlB4, which play a key role on reducing the dehydrogenation activation energy and increasing diffusion rate of hydrogen. Meanwhile, the LiBH4 and Li3AlH6 effectively destabilize MgH2 with a remarkable reduction on dehydrogenation enthalpy change in terms of thermodynamics. In particular, the Li3Mg7, Mg17Al12 and MgAlB4 phases can reversibly transform into MgH2, Li3AlH6 and LiBH4 after rehydrogenation, which contribute to maintain a high cycling *** constructing strategy can further promote the development of high reversible capacity Mg-based materials with suitable de/rehydrogenation properties.

关键词： Magnesium hydride Complex hydride Hydrogen storage high reversible capacity Synergistic effect

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Preparation of biomass-derived carbon loaded with MnO_(2) as lithium-ion battery anode for improving its reversible capacity and cycling performance

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Frontiers of Chemical Science and Engineering 2024年第1期18卷 107-120页

作者： Likai Zhu Huaping Lin Wenli Zhang Qinhui Wang Yefeng Zhou National&Local United Engineering Research Centre for Chemical Process Simulation and Intensification Chemical Process Simulation and Optimization Engineering Research Center of Ministry of EducationXiangtan UniversityXiangtan 411100China Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light IndustryGuangdong University of TechnologyGuangzhou 510006China State Key Laboratory of Clean Energy Utilization Zhejiang UniversityHangzhou 310027China

Biomass-derived carbon materials for lithiumion batteries emerge as one of the most promising anodes from sustainable ***,improving the reversible capacity and cycling performance remains a long-standing *** combining the benefits of K2CO_(3) activation and KMnO_(4) hydrothermal treatment,this work proposes a two-step activation method to load MnO_(2) charge transfer onto biomass-derived carbon(KAC@MnO_(2)).Comprehensive analysis reveals that KAC@MnO_(2) has a micro-mesoporous coexistence structure and uniform surface distribution of MnO_(2),thus providing an improved electrochemical ***,KAC@MnO_(2) exhibits an initial chargedischarge capacity of 847.3/1813.2 mAh·g^(-1) at 0.2 A·g^(-1),which is significantly higher than that of direct pyrolysis carbon and K2CO_(3) activated carbon,***,the KAC@MnO_(2) maintains a reversible capacity of 652.6 mAh·g^(-1) after 100 *** at a high current density of 1.0 A·g^(-1),KAC@MnO_(2) still exhibits excellent long-term cycling stability and maintains a stable reversible capacity of 306.7 mAh·g^(-1) after 500 *** with reported biochar anode materials,the KAC@MnO_(2) prepared in this work shows superior reversible capacity and cycling ***,the Li+insertion and de-insertion mechanisms are verified by ex situ X-ray diffraction analysis during the chargedischarge process,helping us better understand the energy storage mechanism of KAC@MnO_(2).

关键词： biomass-derived carbon MnO_(2) lithium-ion batteries anode material high reversible capacity

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Co-activation for enhanced K-ion storage in battery anodes

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National Science Review 2023年第7期10卷 183-195页

作者： Yanhong Feng Yawei Lv Hongwei Fu Mihir Parekh Apparao M.Rao He Wang Xiaolin Tai Xianhui Yi Yue Lin Jiang Zhou Bingan Lu School of Physics and Electronics Hunan University Department of Physics and Astronomy Clemson Nanomaterials Institute Clemson University Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China School of Materials Science and Engineering Central South University State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body Hunan University

The relative natural abundance of potassium and potentially high energy density has established potassium-ion batteries as a promising technology for future large-scale global energy ***,the anodes’ low capacity and high dis charge platform lead to low energy density,which impedes their rapid ***,we present a possible co-activation mechanism between bismuth(Bi) and tin(Sn)that enhances K-ion storage in battery *** co-activated Bi-Sn anode delivered a high capacity of634 mAh g-1,with a discharge plateau as low as 0.35 V,and operated continuously for 500 cycles at a current density of 50 mA g-1,with a high Coulombic efficiency of 99.2%.This possible co-activation strategy for high potassium storage may be extended to other Na/Zn/Ca/Mg/Al ion battery technologies,thus providing insights into how to improve their energy storage ability.

关键词： potassium ion batteries anode co-activation high reversible capacity

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Enhanced hydrogen storage properties of MgH_(2) with the co-addition of LiBH_(4) and YNi_(5) alloy

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Journal of Materials Science & Technology 2024年第11期178卷 90-99页

作者： Shaoyang Shen Wenfang Liao Zhijie Cao Jiangwen Liu Hui Wang Liuzhang Ouyang Guangdong Engineering Research Center for Advanced Energy Storage Materials School of Materials Science and EngineeringSouth China University of TechnologyGuangzhou 510641China New Energy Materials Laboratory School of PhysicsNingxia UniversityYinchuan 750021China

MgH_(2),as one of the typical solid-state hydrogen storage materials,has attracted extensive ***,the slow kinetics and poor cycle stability limit its *** this work,LiBH_(4) and YNi_(5) alloy were co-added as additives to MgH_(2) via ball milling,thereby realizing an excellent dehydrogenation per-formance and good cycle stability at 300 ℃.The MgH_(2)-0.04LiBH_(4)-0.01YNi_(5) composite can release 7 wt.%of hydrogen in around 10 min at 300 ℃ and still have a reversible hydrogen storage capacity of 6.42 wt.%after 110 cycles,with a capacity retention rate as high as 90.3%based on the second dehydrogenation *** FTIR results show that LiBH_(4) can reversibly absorb and desorb hydrogen throughout the hydrogen ab/desorption process,which contributes a portion of the reversible hydrogen storage capacity to the MgH_(2)-0.04LiBH_(4)-0.01YNi_(5) *** to the small amount of LiBH_(4) and YNi_(5),the dehydro-genation activation energy of MgH_(2) did not decrease significantly,nor did the dehydrogenation enthalpy(△H)***,the MgNi3B2 and in-situ formed YH3 during the hydrogen absorption/desorption cycles is not only beneficial to the improvement of the kinetics performance for MgH_(2) but also improves its cycle *** work provides a straightforward method for developing high reversible hydrogen capacity on Mg-based hydrogen storage materials with moderate kinetic performance.

关键词： Hydrogen storage Magnesium hydride Lithium borohydride YNi5 alloy high reversible capacity

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α-Fe_2O_3 nanoplates with superior electrochemical performance for lithium-ion batteries

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Green Energy & Environment 2018年第2期3卷 156-162页

作者： Li Xu Yuhui Tian Tiefeng Liu Henan Li Jingxia Qiu Sheng Li Huaming Li Shouqi Yuan Shanqing Zhang Institute for Energy Research School of Chemistry and Chemical Engineering Jiangsu University Centre for Clean Environment and Energy Environmental Futures Research Institute and Griffith School of Environment Griffith University Gold Coast Campus

On account of the high theoretical capacity, high corrosion resistance, environmental benignity, abundant availability and low cost, the research on a-Fe_2O_3 has been gradually fastened on as promising anodes materials toward lithium-ion batteries(LIBs). A high-performance anode for LIBs based on α-Fe_2O_3 nanoplates have been selectively prepared. The α-Fe_2O_3 nanoplates can be synthesized with iron ionbased ionic liquid as iron source and template. The α-Fe_2O_3 nanoplates as the anode of LIBs can display high capacity of around1950 mAh g^(-1) at 0.5 A g^(-1) which have exceeded the theoretical capacity of α-Fe_2O_3. On account of unique nanoplate structures and gum arabic as binder, the α-Fe_2O_3 nanoplates also exhibit high rate capability and excellent cycling performance.

关键词： α-Fe2O3 Nanoplates Li-ion battery high reversible capacity Anode

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Access to advanced sodium-ion batteries by presodiation:Principles and applications

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Journal of Energy Chemistry 2024年第5期92卷 162-175页

作者： Shihao Zhang Ruoyu Cao Xiangjun Pu Along Zhao Weihua Chen Chunhua Song Yongjin Fang Yuliang Cao College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power SourcesWuhan UniversityWuhan 430072HubeiChina College of Chemistry&Green Catalysis Center Zhengzhou UniversityZhengzhou 450001HenanChina Shenzhen Janaenergy techonulogy Co. Ltd.Shenzhen 518000GuangdongChina School of Chemistry and Chemical Engineering Jiangsu University of TechnologyChangzhou 213001JiangsuChina Zonergy Corporation NO.68 Fucang RoadYantan DistrictZigong 643030SichuanChina

Sodium-ion batteries(SIBs)are expected to offer affordability and high energy density for large-scale energy storage ***,the commercial application of SIBs is hurdled by low initial coulombic efficiency(ICE),continuous Na loss during long-term operation,and low sodium-content of cathode *** this scenario,presodiation strategy by introducing an external sodium reservoir has been rationally proposed,which could supplement additional sodium ions into the system and thereby markedly improve both the cycling performance and energy density of *** this review,the significance of presodiation is initially introduced,followed by comprehensive interpretation on technological properties,underlying principles,and associated approaches,as well as our perspectives on present inferiorities and future research ***,this contribution outlines a distinct pathway towards the presodiation methodology,of significance but still in its nascent phase,which may inspire the targeted guidelines to explore new chemistry in this field.

关键词： Presodiation Increased coulombic efficiency high reversible capacity Sodium ion batteries

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