检索结果-南通市图书馆

high performance Zn-I_(2)battery with acetonitrile electrolyte working at low temperature

在线全文

学校读者我要写书评

暂无评论

Nano Research 2022年第4期15卷 3170-3177页

作者： Chunlai Song Zongshuai Gong Chong Bai Fengshi Cai Zhihao Yuan Xizheng Liu School of Materials Science and Engineering Tianjin Key Laboratory of Photoelectric Materials&DevicesKey Laboratory of Display Materials and Photoelectric Devices of Ministry of EducationTianjin University of TechnologyNo.391 Binshuixi RoadTianjin 300384China

Large scale applications of metal-iodine batteries working at sub-zero degree have been challenged by the limited capacity and performance degradation.Herein,we firstly propose a Zn-I_(2)battery working at low temperature with a carbon composite material/iodine(CCM-I_(2))cathode,a Zn anode and an environmentally tolerable Zn(ClO4)2-ACN electrolyte.The CCM framework with hierarchical porous structure endows a powerful iodine-anchoring to overcome undesirable dissolution of iodine in organic electrolyte,and the Zn(ClO4)2-ACN electrolyte with low freezing point and high ionic conductivity enhances the low temperature performance.The synergies enable an efficiently reversible conversion of Zn-I_(2)battery even at-40℃.Therefore,the resultant Zn-I_(2)battery delivers a high specific capacity of 200 mAh·g^(-1),which is fairly approximate to the theoretical capacity of I_(2)(211 mAh·g^(-1))and a superior cycling stability with minimal capacity fading of 0.00043%per cycle over 7,000 times under 2C at-20℃.Furthermore,even at-40℃,this Zn-I_(2)battery still exhibits a good capacity retention of 68.7%compared to the capacity at 25℃ and a rapid capacity-recover ability with elevating temperature change.Our results distinctly indicate this Zn-I_(2)battery can be 1competent for the practical application under low temperature operation.

关键词： Zn-I_(2)battery low temperature acetonitrile electrolyte carbon composite material high performance

high performance ethylene sensor based on palladium-loaded tin oxide:Application in fruit quality detection

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2020年第8期31卷 2045-2049页

作者： Qiuni Zhao Zaihua Duan Zhen Yuan Xian Li Si Wang Bohao Liu Yajie Zhang Yadong Jiang Huiling Tai State Key Laboratory of Electronic Thin Films and Integrated Devices School of Optoelectronic Science and EngineeringUniversity of Electronic Science and Technology of China(UESTC)Chengdu 610054China Agricultural Information Institute Chinese Academy of Agricultural SciencesKey Laboratory of Agricultural Information Service Technology of Ministry of AgricultureBeijing 100081China

Ethylene(C2 H4),as a plant hormone,its emission can be served as an indicator to measure fruit quality.Due to the limited physiochemical reactivity of C2 H4,it is a challenge to develop high performance C2 H4 sensors for fruit detection.Herein,this paper presents a resistive-type C2 H4 sensor based on Pd-loaded tin oxide(SnO2).The C2 H4 sensing performance of proposed sensor are tested at optimum operating temperature(250℃)with ambient relative humidity(51.9%RH).The results show that the response of Pd-loaded SnO2 sensor(11.1,Ra/Rg)is about 3 times higher than that of pristine SnO2(3.5)for 100 ppm C2 H4.The response time is also significantly shortened from 7 s to 1 s compared with pristine SnO2.Especially,the Pd-loaded SnO2 sensor possesses good sensitivity(0.58 ppm 1)at low concentration(0.05-1 ppm)with excellent linearity(R2=0.9963)and low detection limit(50 ppb).The high sensing performance of Pd-loaded SnO2 are attributed to the excellent adsorption and catalysis effects of Pd nanoparticle.Meaningfully,the potential applications of C2 H4 sensor are performed for monitoring the maturity and freshness of fruits,which presents a promising prospect in fruit quality evaluation.

关键词： Ethylene sensing Pd-loaded SnO2 high performance Low detection limit Fruit quality monitoring

Design and synthesis of thiol-terminated imidothioether oligomer as thermally latent hardener and modifier for high-performance epoxy/thiol thermosets

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2024年第2期67卷 632-641页

作者： Xing Liu Jianjun Zhou Shumei Liu Jianqing Zhao School of Materials Science and Engineering South China University of TechnologyGuangzhou510640China Key Lab Guangdong high Property&Functional Polymer Materials Key Laboratory of Polymer Processing EngineeringMinistry of EducationGuangzhou510640China

Conventional base-catalyzed epoxy/aliphatic thiol systems have a poor storage stability,and are impossible to be one-pot systems.A widely accepted solution is to use the latent catalysts,which are usually insoluble anionic initiators sensitive to impurities and moisture,and have many limitations in practical use.In this work,a soluble thiol-terminated imidothioether oligomer(TPI) was synthesized and used as a latent hardener and modifier to prepare one-pot epoxy/thiol systems without the latent catalysts.The latent behavior and curing mechanism of epoxy systems(EP/TPI series),consisted of bisphenol A diglycidyl ether(DGEBA),pentaerythritol tetrakis(mercaptoacetate)(PETMP) and TPI,were proposed.The thiol exchange reaction between TPI and PETMP preceded the curing reaction of DGEBA,and produced aromatic thiols,which were unreactive at ambient conditions and reacted with DGEBA to form the thermosets at temperatures above 130 ℃.At the loading of 24.4 wt%TPI,the epoxy system(EP/TPI-3) had a shelf life of 13 days and was completely cured within 20 min at 180 ℃.Meanwhile,the catalyst-free curing process of EP/TPI-3 system was insensitive to impurities and moisture.Furthermore,the thermal and mechanical properties of EP/TPI-3 thermoset were simultaneously improved,thereinto,the glass transition temperature,Young's modulus and ultimate tensile strength were increased by 16.7 ℃,12.9%,and 13.6%,respectively,compared with those of the commercial DGEBA/PETMP thermoset.This work shows that TPI has the potential to be a powerful alternative to commercial latent catalysts,and EP/TPI thermosets with high performance have broad application prospects.

关键词： thiol-terminated imidothioether oligomer epoxy systems thiol exchange reaction thermal latency high performance

high-performance broadband photodetector based on PtSe2/MoS2 heterojunction from visible to near-infrared region

在线全文

学校读者我要写书评

暂无评论

Science China(Information Sciences) 2024年第3期67卷 263-270页

作者： Bin WANG Jian YUAN Mengqi CHE Mingxiu LIU Yuting ZOU Junru AN Fan TAN Yaru SHI Nan ZHANG Liujian QI Shaojuan LI State Key Laboratory of Luminescence and Applications Changchun Institute of OpticsFine Mechanics and PhysicsChinese Academy of Sciences University of Chinese Academy of Sciences State Key Laboratory of Applied Optics Changchun Institute of OpticsFine Mechanics and PhysicsChinese Academy of Sciences School of Physics and Electronic Information Huaibei Normal University

Broadband photodetectors based on narrow bandgap 2D materials have garnered considerable interest for application in the field of optoelectronic devices. However, their large dark current hinders device performance. In this work, a PtSe2/MoS2heterojunction was fabricated for a broadband photodetector operating within the range of visible to near-infrared. The device exhibited suppressed dark currents with a high rectification ratio of 104. The built-in electric field of the heterojunction promoted carrier separation effectively, and the device achieved excellent photoelectric performance with responsivities of 1.7 × 103,27.52, and 21 mA/W at 635, 785, and 1550 nm wavelengths, respectively. Moreover, the specific detectivities(D*) were 2.2 × 1013Jones(635 nm), 3.55 × 1011Jones(785 nm), and 2.72 × 108Jones(1550 nm). The device demonstrated a rise/fall time of 131/241 μs under 1550 nm laser illumination. Visible and near-infrared imaging detection was also demonstrated based on the heterojunction device at room temperature. This work sheds light on the remarkable potential of PtSe2/MoS2heterojunctions in the domain of high-performance broadband photodetectors.

关键词： photodetector PtSe 2 /MoS 2 heterojunction visible to near infrared high performance

Mechanical behavior and permeability properties of sustainable and high-performance anisotropic three-dimensional printable concrete

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Frontiers of Structural and Civil Engineering 2023年第11期17卷 1662-1674页

作者： Fatih OZALP Civil Engineering Department Istanbul Medeniyet UniversityIstanbul 34700Turkey

Three-dimensional printable concrete requires further development owing to the challenges encountered,including its brittle behavior,high cement requirement for the buildability of layers,and anisotropic behavior in different directions.The aim of this study is to overcome these challenges.First,three-dimensional printable concrete mixtures were prepared using silica fume,ground blast furnace slag,and metakaolin,instead of cement,to reduce the amount of cement.Subsequently,the rheological and mechanical behaviors of these concretes were investigated.Second,threedimensional printable concrete mixtures were prepared using 6-mm-long steel and synthetic fibers to eliminate brittleness and determine the effect of those fibers on the anisotropic behavior of the concrete.As a result of this study,it is understood that printable concretes with extremely low permeability and high buildability can be achieved using mineral additives.In addition,results showed that three-dimensional concrete samples containing short steel fibers achieve fracture energies up to 36 times greater than that of plain concrete.Meanwhile,its characteristic length values,as indicators of ductility,are 22 times higher than those of plain concrete.The weakest strength was recorded at the interfaces between layers.The bending and splitting tensile strengths of three-dimensional printed plain concrete samples were 15%and 19%lower than those of casted samples,respectively.However,the addition of fibers improved the mechanical strength of the interfaces significantly.

关键词： three-dimensional concrete printing rheology high performance mineral additives anisotropy fiber

A nonchlorinated solvent-processed polymer semiconductor for high-performance ambipolar transistors

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

National Science Review 2022年第4期9卷 139-147页

作者： Jie Yang Yaqian Jiang Zhiyuan Zhao Xueli Yang Zheye Zhang Jinyang Chen Junyu Li Wei Shi Shuai Wang Yunlong Guo Yunqi Liu Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of Sciences School of Chemistry and Chemical Engineering Huazhong University of Science and Technology

Ambipolar polymer semiconductors are potentially serviceable for logic circuits, light-emitting field-effect transistors(LFETs) and polymer solar cells(PSCs). Although several high-performance ambipolar polymers have been developed, their optoelectronic devices are generally processed from toxic chlorinated solvents. To achieve the commercial applications of organic FETs(OFETs), the polymers should be processed from nonchlorinated solvents, instead of chlorinated solvents. However, most conjugated polymers show poor solubility in nonchlorinated solvents. It is of great importance to develop ambipolar polymers that can be processed from nonchlorinated solvents. Here, we develop a nonchlorinated solvent processed polymer named poly[7-fluoro-N, N′-di(4-decyltetradecyl)-7′-azaisoindigo-6′,6′′-(thieno[3,2-b]thiophene-2,5-diyl)-7′′′-fluoro-N′′, N′′′-di(4-decyltetradecyl)-7′′-azaisoindigo-6,6′′′-([2,2′′-bithiophene]-5,5′′-diyl)](PITTI-BT) by designing a monomer with a large molar mass. The polymer displays good solubility in p-xylene(PX). Well-aligned films of PITTI-BT are achieved by an off-center spin-coating(SC) method. Based on the high-quality films, the OFETs fabricated from PX solution achieve record ambipolar performance with hole and electron mobilities of 3.06 and2.81 cm~2 V-1s-1, respectively. The combination of nonchlorinated solvents and good alignment process offers an effective and eco-friendly approach to obtain high-performance ambipolar transistors.

关键词： nonchlorinated solvent high performance ambipolar transistor alignment

3D MoS_(2) foam integrated with carbon paper as binder-free anode for high performance sodium-ion batteries

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2022年第2期31卷 26-33页

作者： Fangying Zheng Zeyu Wei Huicong Xia Yunchuan Tu Xiangyu Meng Kaixin Zhu Jiao Zhao Yimin Zhu Jianan Zhang Yan Yang Dehui Deng Institute of Environmental Remediation Dalian Maritime UniversityDalian 116026LiaoningChina State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina College of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001HenanChina Zhang Dayu School of Chemistry Dalian University of TechnologyDalian 116024LiaoningChina

Molybdenum sulfide(MoS_(2))with well-designed porous structure has the potential to be great electrode materials in sodium-ion batteries due to its high theoretical capacity and abundant resource,however,hindered by its intrinsic low conductivity and stability.Herein,MoS_(2) with 3 D macroporous foam structure and high conductivity was obtained through SiO_(2) templates and integrated with carbon paper(3 D FMoS_(2)/CP).It has showed superior specific capacity(225 m A h g^(-1),0.4–3 V)and cycling stability(1000 cycles)at high rate(2000 m A g^(-1)),with a low decay rate(0.033%per cycle)in sodium-ion batteries.The excellent electrochemical performance may originate from its unique integrated structure:3 D MoS_(2) macropores providing high surface area and abundant transfer channels while carbon paper enhancing the conductivity of MoS_(2) and avoiding unnecessary side reactions brought by binder addition.

关键词： 3D MoS_(2)foam Carbon paper Binder-free electrode high performance Sodium-ion batteries

high-performance ferroelectric based materials via high-entropy strategy:Design,properties,and mechanism

在线全文

学校读者我要写书评

暂无评论

InfoMat 2023年第12期5卷 28-53页

作者： Yueyun Zhang Liang Chen Hui Liu Shiqing Deng He Qi Jun Chen Beijing Advanced Innovation Center for Materials Genome Engineering and Department of Physical ChemistryUniversity of Science and Technology BeijingBeijingthe People's Republic of China Hainan University Haikouthe People's Republic of China

high-performance ferroelectric materials are widely used in various electronic devices owing to the function of mutual conversion among different energies,which mainly relates to their special structure gene of polarization configuration.Recent researches show that the high-entropy strategy has emerged as an effective and flexible approach for boosting physical properties in high-entropy ferroelectrics via the delicate design of local polarization configurations and other intrinsic effects caused by entropy increment,such as entropy stabilization,lattice disorder,inhibition of grain coarsening,improved mechanical properties,cocktail effect,and so on.In this review,the recent research progress about high-entropy ferroelectrics has been summarized,especially for the directional design of novel local polarization configurations according to the characteristics of different electrical properties such as high piezoelectricity,high-efficiency energy storage,and large electrostriction,providing a guidance for designing and exploring more novel local polarization configurations in high-entropy ferroelectrics for generating higher performance.

关键词： ferroelectric materials high performance high-entropy design local structure polarization configuration

PdSe_(2)/MoSe_(2) vertical heterojunction for self-powered photodetector with high performance

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2022年第3期15卷 2489-2496页

作者： Jiahong Zhong Biao Wu Yassine MADOUNE Yunpeng Wang Zongwen Liu Yanping Liu School of Physics and Electronics Hunan Key Laboratory for Super-microstructure and Ultrafast ProcessCentral South UniversityChangsha 410083China State Key Laboratory of high-performance Complex Manufacturing Central South UniversityChangsha 410083China School of Chemical and Biomolecular Engineering The University of SydneyNSW 2006Australia The University of Sydney Nano Institute The University of SydneyNSW 2006Australia Shenzhen Research Institute of Central South University A510aVirtual University BuildingSouthern DistrictHigh-tech Industrial ParkYuehai StreetNanshan DistrictShenzhen 518057China

Van der Waals’two-dimensional(2D)material heterostructure engineering offers an effective strategy for the design of multifunctional and high-performance optoelectronic devices.However,2D heterostructure photodetectors with a photoconductive effect tend to suffer from high driving source-drain voltages and significant dark noise currents.Herein,a self-powered photodetector with high performance was fabricated based on vertically stacked graphene/MoSe_(2)/PdSe_(2)/graphene heterojunctions through a dry transfer method.The fabricated device displays current rectification characteristics in darkness(on/off ratio>10^(3))and superior photovoltaic behaviors under illumination.In addition,benefitting from the strong built-in field,the Gr/PdSe_(2)/MoSe_(2)/Gr heterojunction photodetector is able to respond to a broad spectrum from visible to near-infrared(NIR)with a remarkable responsivity of 651 mA·W^(−1),a high specific detectivity of 5.29×10^(11) Jones and a fast response speed of 41.7/62.5μs.Moreover,an enhanced responsivity of 1.16 A·W^(−1) has been obtained by a reverse voltage(−1 V)and further evaluation on image recognition has also demonstrated the great application potential of the Gr/MoSe_(2)/PdSe_(2)/Gr heterojunction photodetector.The findings are expected to bring new opportunities for the development of highly sensitive,high-speed and energy-efficient photodetectors for comprehensive applications.

关键词： heterostructure MoSe_(2) PdSe_(2) self-powered photodetector high performance