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Influence of Organo-metal Interactions on Regeneration of Exhausted Clay Mineral Sorbents in Soil Columns Loaded with heavy metals

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Pedosphere 2017年第3期27卷 579-587页

作者： Yasser REFAEY Boris JANSEN Pim DE VOOGT John R.PARSONS Abdel-Hamid EL-SHATER Abdel-Aziz EL-HADDAD Karsten KALBITZ Institute for Biodiversity and Ecosystem Dynamics (IBED) University of Amsterdam Geology Department Faculty of Science Sohag University Soil Resources and Land Use Institute of Soil Science and Site Ecology Faculty of Environmental Sciences Technical University Dresden

Natural clay minerals can play an important role in crude remediation of wastewater polluted with the heavy metals （HMs） Cu, Zn and Ni. The presence and timing of ddition of natural dissolved organic matter （DOM） have a significant effect on the HM removal by clay mineral sorbents. However, the influence of the presence of DOM on the remediation of the used clay mineral sorbents once saturated with HMs is largely unknown. To resolve this, clay mineral-rich soil column of varying composition, loaded （i） with Cu, Zn and Ni only, （ii） first with DOM followed by Cu, Zn and Ni, or （iii） with DOM, Cu, Zn and Ni simultaneously, was used in a set of desorption experiments. The soil columns were leached with 0.001 mol L-1 CaCI2 dissolved in water as control eluent and 0.001 tool L-1 CaC12 dissolved in DOM as treatment eluent. During the preceding loading phase of the sorbent, the timing of DOM addition （sequential or concurrent with HMs） was found to have a significant influence on the subsequent removal of the HMs. In particular when the column was loaded with DOM and HMs simultaneously, largely irreversible co-precipitation took place. Our results indicate that the regeneration potential of clay mineral sorbents in wastewater treatment will be significantly reduced when the treated water is rich in DOM. In contrast, in manured agricultural fields （where HMs enter together with DOM）, HM mobility will be lower than expected from interaction dynamics of HMs and clay minerals.

关键词： dissolved organic matter heavy metal mobility remediation timing of addition wastewater treatment

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Reduction of Cd, Cu, Ni and Pb mobility by Active Si

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Agricultural Science & Technology 2015年第1期16卷 182-186,196页

作者：魏晓 Matichenkov V.V. Bocharnikova E.A. 占强 Matichenkov I.V. 湖南省经济地理研究所中国湖南长沙410004 俄罗斯科学院基础生物研究所俄国普希诺142290 俄罗斯科学院物理化学和生物研究所俄国普希诺142290 莫斯科大学土壤科学院俄国莫斯科119991

A series of column experiments were performed to investigate the mechanisms of silicon （Si） and heavy metals （HM） interaction in the soil. The column experiments were conducted with Gray Forest Soil treated by various forms of active Si （diatomaceous earth, zeolite, amorphous silicon dioxide and concentrated monosilicic acid） in environment polluted conditions with soluble salts of Cd, Cu, Ni and Pb. All Si-rich substances used in the test were analyzed with electron scan microscope. The results of HM immobilization in soil by Si-rich materials showed that diatomaceous earth and concentrated monosilicic acid immobilized HM better than zeolite and amorphous silicon dioxide. The reductions in HM mobility were re- alized by the reaction between monosilicic acid and HM in soil solution and by adsorption of HM on Si-rich surface. The intensity of HM movement through soil depended on the type of HM. The maximum reduction of HM mobility with application of Si-rich substances was obtained for Cd and Ni and less effect was observed for Cu and Pb.

关键词： Cd Ni Cu Pb Monosilicic acid heavy metal mobility

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