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Differences in Toxicokinetics and Maternal Transfer between Lipophilic and Proteinophilic halogenated organic pollutants in Laying Hens

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Environment & Health 2024年第10期2卷 712-720页

作者： Xiao-Jun Luo Qun-Jie Feng Chu-Hong Zhu Xi Chen Peng-Peng Chen Yan-Hong Zeng Bi-Xian Mai State Key Laboratory of organic Geochemistry and Guangdong Key Laboratory of Environmental Resources Utilization and Protection and Guangdong-Hong Kong-Macao Joint Laboratory for Environmental Pollution and Control Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640P.R.China State Key Laboratory of organic Geochemistry and Guangdong Key Laboratory of Environmental Resources Utilization and Protection Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640P.R.China University of Chinese Academy of Sciences Beijing 100049P.R.China

In this study,we conducted exposure experiments on egg-laying hens to explore the toxicokinetics and maternal transfer characteristics of lipophilic and proteinophilic halogenated organic pollutants(HOPs).The lipophilic HOPs included polychlorinated biphenyls(PCBs),polybrominated diphenyl ethers(PBDEs),and dechlorane plus(DPs),while the proteinophilic HOPs included perfluorocarboxylic acids(PFCAs).The results revealed that most of lipophilic HOPs exhibit lower depuration rate(kd)than *** kd of lipophilic HOPs correlated with the octanol−water partition coefficient(log KOW)values in a V-shaped curve,whereas that of PFCAs correlated with the protein−water partition coefficient(log KPW)values in an inverted V-shaped *** depuration rate,rather than the uptake rate,was a leading factor in determining the bioaccumulation potential of HOPs in *** the dominant factors determining the tissue distribution of the two types of compounds were explicit(fats vs phospholipids),chemical-specific tissue distribution was still *** egg-maternal concentration ratio was dependent on the exposure status,concentration,and maternal tissue *** a single maternal tissue may not be an appropriate method for assessing chemical maternal transfer *** have a greater maternal transfer potential(>80%of the total body burden)than lipophilic HOPs(approximately 30%for BDE209 and DPs,and less than 10%for the others).Their lipophilic and partly proteinophilic nature makes the toxicokinetics and maternal transfer characteristics of BDE209 and DPs different from those of other lipophilic *** findings are crucial for enhancing our understanding of the behavior and fate of HOPs in egg-laying hens.

关键词： halogenated organic pollutants laying hens toxicokinetic maternal transfer

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Light-driven activation of carbon-halogen bonds by readily available amines for photocatalytic hydrodehalogenation

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Chinese Journal of Catalysis 2020年第10期41卷 1474-1479页

作者： Di Meng Qian Zhu Yan Wei Shengli Zhen Ran Duana Chuncheng Chen Wenjing Song Jincai Zhao Key Laboratory of Photochemistry CAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing100190China University of Chinese Academy of Sciences Beijing100049China Beijing GeoEnviron Engineering&Technology Inc.Beijing100095China

A straightforward protocol using readily available aromatic amines,N,N,N',N'-tetramethyl-p-phenylenediamine or N,N,N',N'-tetramethylbenzidine,as photocatalysts was developed for theefficient hydrodehalogenation of organic halides,such as 4'-bromoacetophenone,polyfluoroarenes,cholorobenzene,and 2,2',4,4'-tetrabromodiphenyl ether(a resistant and persistent organic pollu-tant).The strongly reducing singlet excited states of the amines enabled diffusion-controlled disso-ciative electron transfer to effectively cleave carbon-halogen bonds,followed by radical *** served as the terminal electron/proton donor and regenerated theamine sensitizers.

关键词： Carbon-halogen bond activation Photocatalysis halogenated organic pollutants Reductive dehalogenation Environmental remediation

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