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graphene-confined ultrafast radiant heating for high-loading subnanometer metal cluster catalysts

National Science Review 2023年第6期10卷 191-199页

作者： Ye-Chuang Han Jun Yi Beibei Pang Ning Wang Xu-Cheng Li Tao Yao Kostya S.Novoselov Zhong-Qun Tian State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Graphene Industry and Engineering Research Institute School of Electronic Science and Engineering Xiamen University Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) National Synchrotron Radiation Laboratory University of Science and Technology of China Faculty of Environment and Life Beijing University of Technology Institute for Functional Intelligent Materials National University of Singapore

Thermally activated ultrafast diffusion,collision and combination of metal atoms comprise the fundamental processes of synthesizing burgeoning subnanometer metal clusters for diverse ***,so far,no method has allowed the kinetically controllable synthesis of subnanometer metal clusters without compromising metal ***,we have developed,for the first time,a graphene-confined ultrafast radiant heating(GCURH) method for the synthesis of high-loading metal cluster catalysts in microseconds,where the impermeable and flexible graphene acts as a diffusion-constrained nanoreactor for high-temperature *** from graphene-mediated ultrafast and efficient laser-to-thermal conversion,the GCURH method is capable of providing a record-high heating and cooling rate of～109℃/s and a peak temperature above 2000 ℃,and the diffusion of thermally activated atoms is spatially limited within the confinement of the graphene *** a result,due to the kinetics-dominant and diffusion-constrained condition provided by GCURH,subnanometer Co cluster catalysts with high metal loading up to 27.1 wt% have been synthesized by pyrolyzing a Co-based metal-organic framework(MOF)in microseconds,representing one of the highest size-loading combinations and the quickest rate for MOF pyrolysis in the reported *** obtained Co cluster catalyst not only exhibits an extraordinary activity similar to that of most modern multicomponent noble metal counterparts in the electro catalytic oxygen evolution reaction,but is also highly convenient for catalyst recycling and refining due to its single metal *** a novel GCURH technique paves the way for the kinetically regulated,limited diffusion distance of thermally activated atoms,which in turn provides enormous opportunities for the development of sophisticated and environmentally sustainable metal cluster catalysts.

关键词： photothermal conversion ultrafast radiant heating graphene-confined high-loading metal clusters solid catalysts

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