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Integration of a fused silica capillary and in-situ Raman spectroscopy for investigating CO_(2) solubility in n-dodecane at near-critical and supercritical conditions of CO_(2)

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Petroleum Science 2022年第6期19卷 3124-3133页

作者： Jun-Liang Wang Zi-Hao Song Lin-Jun Li Li-Li Yang Quan-Yuan Wang I-Ming Chou Zhi-Yan Pan College of Environment Zhejiang University of TechnologyHangzhouZhejiang310032China Hangzhou Academy of Environmental Protection HangzhouZhejiang310032China Laboratory for Experimental Study Under Deep-sea Extreme Conditions Institute of Deep-sea Science and EngineeringChinese Academy of SciencesSanyaHainan572000China

To determine the solubility of CO_(2)in n-dodecane at T=303.15-353.15 K,P≤11.00 MPa,an integrated fused silica capillary and in-situ Raman spectroscopy system was *** Raman peak intensity ratio(I_(CO_(2))/IC-H)between the upper band of CO_(2)Fermi diad(I_(CO_(2)))and the C-H stretching band of n-dodecane(IC-H)was employed to determine the solubility of CO_(2)in n-dodecane based on the calibrated correlation equation between the known CO_(2)molality in n-dodecane and the I_(CO_(2))/IC-Hratio with R^(2)=*** results indicated that the solubility of CO_(2)decreased with increasing temperature and increased with increasing *** maximum CO_(2)molality(30.7314 mol/kg)was obtained at 303.15 K and7.00 ***,a solubility prediction model(lnS=(P-A)/B)based on the relationship with temperature(T in K)and pressure(P in MPa)was developed,where S is CO_(2)molality,A=-8×10^(-6)T^(2)+0.0354T-8.1605,and B=*** results indicated that the solubilities of CO_(2)derived from this model were in good agreement with the experimental data.

关键词： CO_(2)solubility n-dodecane Raman spectroscopy fused silica capillary In-situ

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CO_2 Density-Raman Shift Relation Derived from Synthetic Inclusions in fused silica Capillaries and Its Application

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Acta Geologica Sinica(English Edition) 2009年第5期83卷 932-938页

作者： SONG Yucai CHOU I＇Ming HU Wenxuan Burruss ROBERT LU Wanjun Institute of Geology China Academy of Geological Sciences Beijing 100037 China Department of Earth Sciences Nanjing University Nanjing 210093 China US Geological Survey National Center Reston VA 20192 USA State Key Laboratory of Geological Processes and Mineral Resources China University of GeosciencesWuhan 430074 China

The densities of CO2 inclusions in minerals are commonly used to determine the crystallizing conditions of the host minerals. However, conventional microthermometry is difficult to apply for inclusions of small size （〈 5-10 μm） or low density. Raman analysis is an alternative method for determining CO2 density, provided that the CO2 density-Raman shift relation is known. This study aims to establish this CO2 density-Raman shift relation by using CO2 inclusions synthesized in fused silica capillaries. By using this newly-developed synthetic technique, we formed pure CO2 inclusions, and their densities were determined by microthermometry. The Raman analysis showed that the relation between CO2 density （D in g/cm^3） and the separations （△ in cm^-1） between the two main bands （i.e. Fermi diad bands） in CO2 Raman spectra can be represented by a cubic equation： D （g/cm^3）=0.74203（-0.019^3＋5.90332△^2-610.79472△＋21050.30165）-3.54278 （r^2=0.99920）. Our calculated D value for a given A is between those obtained from two previously-reported equations, which were derived from different experimental methods. An example was given in this study to demonstrate that the densities of natural CO2 inclusions that could not be derived from microthermometry could be determined by using our method.

关键词： synthetic fluid inclusion fused silica capillary COz inclusion C02 density equation,Raman analysis

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