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Ni Single Atoms and Ni Phosphate Clusters Synergistically Triggered Surface-Functionalized MoS_(2)Nanosheets for High-performance freshwater and seawater electrolysis

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Energy & Environmental Materials 2022年第4期5卷 1340-1349页

作者： Min Sung Kim Duy Thanh Tran Thanh Hai Nguyen Van An Dinh Nam Hoon Kim Joong Hee Lee Department of Nano Convergence Engineering Jeonbuk National UniversityJeonju 54896Republic of Korea Department of Precision Engineering Graduate School of EngineeringOsaka University2-1Yamada-okaSuita 565-0871Japan Carbon Composite Research Center Department of Polymer-Nanoscience and TechnologyJeonbuk National UniversityJeonju 54896Republic of Korea

Two-dimensional metal dichalcogenides have been evidenced as potential electrocatalysts for hydrogen evolution reaction(HER);however,their application is limited by a poor oxygen evolution reaction(OER)activity due to insufficient number/types of multi-integrated active *** this study,we report a novel bifunctional catalyst developed by simultaneous engineering of single nickel atoms(Ni_(SA)) and nickel phosphate clusters(Ni_(Pi)) to synergistically trigger surface-functionalized MoS_(2) nanosheets(NSs)resulting in high reactivities for both HER and *** Ni_(SA)-Ni_(Pi)/MoS_(2)NSs material exhibits a fairly Pt-like HER behavior with an overpotential of 94.0 mV and a small OER overpotential of 314.0 mV to reach 10 mA cm^(-2) in freshwater containing 1.0 M *** results of the catalyst are well supported by theoretical study,which reveals the significant modulation of electronic structure and enrichment of electroactive site number/types with their reasonably adjusted free adsorption *** evaluating practicability,the Ni_(SA)-Ni_(Pi)/MoS_(2)NSs-based electrolyzer delivers effective operation voltage of 1.62,1.52,and 1.66 V at 10 mA cm^(-2) and superior long-term stability as compared to Pt/C//RuO_(2) system in freshwater,mimic seawater,and natural seawater,*** present study indicates that the catalyst is a promising candidate for the practical production of green hydrogen via water electrolysis.

关键词： bifunctional electrocatalyst freshwater and seawater electrolysis nickel phosphate clusters nickel single atoms surface-functionalized-MoS_(2)nanosheets

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