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Nickel-based metal-organic framework-derived whisker-shaped nickel phyllosilicate toward efficiently enhanced mechanical,flammable and tribological properties of epoxy nanocomposites

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Frontiers of Chemical Science and Engineering 2022年第10期16卷 1493-1504页

作者： Yuxuan Xu Guanglong Dai Shibin Nie Jinian Yang Song Liu Hong Zhang Xiang Dong School of Safety Science and Engineering State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal MinesAnhui University of Science and TechnologyHuainan 232001China School of Materials Science and Engineering State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal MinesAnhui University of Science and TechnologyHuainan 232001China

Metal−organic framework-derived materials have attracted significant attention in the applications of functional *** this work,the rod-like nickel-based metal−organic frameworks were first synthesized and subsequently employed as the hard templates and nickel sources to prepare the whisker-shaped nickel phyllosilicate using a facile hydrothermal ***,the nickel phyllosilicate whiskers were evaluated to enhance the mechanical,thermal,flammable,and tribological properties of epoxy *** results show that adequate nickel phyllosilicate whiskers can disperse well in the matrix,improving the tensile strength and elastic modulus by 13.6%and 56.4%,*** the addition of nickel phyllosilicate whiskers could not obtain any UL-94 ratings,it enhanced the difficulty in burning the resulted epoxy resin nanocomposites and considerably enhanced thermal ***,it was demonstrated that such nickel phyllosilicate whiskers preferred to improve the wear resistance instead of the antifriction ***,the wear rate of epoxy resin nanocomposites was reduced significantly by 80%for pure epoxy resin by adding 1 phr *** as-prepared nickel phyllosilicate whiskers proved to be promising reinforcements in preparing of high-performance epoxy resin nanocomposites.

关键词： metal−organic framework nickel phyllosilicate whisker epoxy resin mechanical response tribological performance flammable property

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