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Recent advances in fire-retardant carbon-based polymeric nanocomposites through fighting free radicals

SusMat 2022年第4期2卷 411-434页

作者： Ting Sai Shiya Ran Zhenghong Guo Pingan Song Zhengping Fang Laboratory of Polymer Materials and Engineering NingboTech UniversityNingboChina MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhouChina Center for Future Materials University of Southern QueenslandSpringfield CentralQueenslandAustralia School of Agriculture and Environmental Science University of Southern QueenslandSpringfield CentralQueenslandAustralia

Polymeric materials are ubiquitously utilized in modern society and continuously improve quality of ***,most of them suffer from intrinsic flammability,significantly limiting their practical ***,free-radical reaction is a critical“trigger”for their thermal pyrolysis and following combustion process regardless of the anaerobic thermal pyrolysis in the condensed phase or aerobic combustion of polymers in the gaseous *** addition of free radical scavengers represents a promising and effective means to enhance the fire safety of polymeric *** review aims to offer a state-of-the-art overview on the creation of fire-retardant polymeric nanocomposites by adding fire retardants with an ability to trap free *** specific modes of action(condensed-phase action,gaseous-phase action,and dual-phases action)and performances in some typical polymers are reviewed and discussed in *** this,some key challenges associated with these free-radical capturers are discussed,and design strategies are also *** review provides some insights into the modes of action of free radical capturing agents and paves the avenue for the design of advanced fire-retardant polymeric nanocomposites for expanded real-world applications in industries.

关键词： fire retardants free radical capturers polymer nanocomposites thermal stability

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