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environmental chemistry(2000 ANNUAL INDEX)

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环境化学 2000年第6期 584-588页

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关键词： PASC ANNUAL INDEX environmental chemistry

environmental chemistry(2001 ANNUALINDEX)

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环境化学 2001年第6期 632-636页

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关键词： environmental chemistry ANNUALINDEX

Switchable Multicomponent Cyclization Reactions to Access Fluoroalkylated Dihydropyrimidines and Pyrimidines under Solvent-Free Conditions

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Chinese Journal of chemistry 2024年第12期42卷 1394-1398页

作者： Wanqing Zuo Zhizhen Zhu Yu Cheng Lingling Zuo Xiao Geng Zhifang Li Lei Wang College of Material chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Material TechnologyMinistryof EducationHangzhouNormal UniversityHangzhouZhejiang311121China Advanced Research Institute and School of Pharmaceutical Sciences Taizhou UniversityJiaojiangZhejiang 318000China state Key Laboratory of Organometallic chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai200032China

Comprehensive Summary The development of switchable solvent-free multicomponent reactions to build high-value-added products is an important demand for organic ***,we detailed the successful implementation of a switchable strategy for the construction of diverse 4-fluoroalkyl-1,4-dihydropyrimidines and 4-fluoroalkyl-pyrimidines via a solvent/additive-free[3+2+1]annulation,starting from readily available enamines,trifluoroacetaldehyde hydrate or 1-ethoxy-2,2-difluoroethanol and amidines *** reaction conforms to the concept of green synthesis,and provides a new avenue to access valuable fluorinated heterocycles.

关键词： Fluorine chemistry Multicomponent reactions environmental chemistry Heterocycles Enaminones Amidines

Metal-enriched nanoparticles and black carbon:A perspective from the Brazil railway system air pollution

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Geoscience Frontiers 2021年第3期12卷 624-635页

作者： Bianca D.Lima Elba C.Teixeira James C.Hower Matheus S.Civeira Omar Ramírez Cheng-Xue Yang Marcos L.S.Oliveira Luis F.O.Silva Postgraduate Program in Remote Sensing and Meteorology Geosciences InstituteUniversidade Federal do Rio Grande do SulAv.Bento Gonçalves9500Porto AlegreRS 91501–970Brazil Research Department Fundação Estadual de Proteção Ambiental Henrique Luís RoesslerAv.Borges de Medeiros261Porto AlegreRS 90020–021Brazil Center for Applied Energy Research University of Kentucky2540 Research Park DriveLexingtonKY 40511USA Postgraduate Program in Mines Metallurgy and MaterialsUniversidade Federal do Rio Grande do SulAv.Bento Gonçalves9500Porto AlegreRS 91501–970Brazil Faculty of Engineering Environmental EngineeringUniversidad Militar Nueva GranadaKm 2 CajicáZipaquiráColombia Institute of Earth Science China University of Geosciences(Beijing)29 Xueyuan RdHaidian DistrictChina Department of Civil and environmental Universidad de la CostaCUCCalle 58#55-66BarranquillaAtlanticoColombia Universidad de Lima Departamento de Ingeniería civil y Arquitectura.Avenida Javier Prado Este 4600–Santiago de Surco 1503Peru

Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public *** study measured,for the first time in Brazil,nanoparticles(NPs)and black carbon(BC)on two groundlevel platforms and inside trains of the Metropolitan Area of Porto Alegre(MAPA).An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy *** results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger ***,internal and external sources of pollution at the stations were *** predominance of NPs enriched with metals that increase oxidative stress like Cd,Fe,Pb,Cr,Zn,Ni,V,Hg,Sn,and Ba both on the platforms and inside trains,including Fe-minerals as hematite and magnetite,represents a critical risk to the health of passengers and employees of the *** interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols.

关键词： Nanoparticles Potential hazardous elements environmental chemistry Human health Railway environment Indoor air quality

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Surface activity of a series of fluoroether betaine amphoteric surfactants: Oxygen roles

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Chinese Chemical Letters 2023年第3期34卷 347-351页

作者： Xue Wang Meiwei Huang Zhaoben Su Libo Qian Yong Guo Qing-Yun Chen Chengying Wu Tao lv Qin Su Qing Shen Jie Ma School of Materials and chemistry University of Shanghai for Science and TechnologyShanghai 200093China Key Laboratory of Organofluorine chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China Sanming Hexafluo Chemicals Company Ltd.Fluorinated New Material Industry ParkSanming 365200China Shanghai Huayi 3F New Materials Co. Ltd.Shanghai 200241China

As PFOS, PFOA and their derivatives were banned according to the Stockholm Convention for their potential bioaccumulation and toxicity, people attempted to substitute the legacy fluorosurfactants with short-chain ones. Although short-chain alternatives can alleviate bioaccumulation, surface activity was compromised. Fluorine industry kept seeking for effective solution. In this work, we prepared and investigated a series of fluoroether betaine surfactants for their surface activity and spreading property. The role of oxygen on surface activity was discussed. We found that insertion of oxygen atoms into fluorinated chain could increase hydrophobicity and thus enhance surface activity. The contribution of one oxygen is approximately half of that of a difluoromethylene group by experience. Moreover, introducing oxygen diversified the structure to fill in the gap of surface activity between short and long fluorosurfactants. In summary, this work provided basic knowledge for molecular design.

关键词： environmental chemistry Surfactant Fluorine Oxygen Sustainable chemistry

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Assessment of Pesticide Contamination in Cidade Dos Meninos, Rio de Janeiro, Brazil, Using Regional Screening Levels (RSL)

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Journal of environmental Protection 2023年第11期14卷 889-902页

作者： Deiwid Ferreira Gomes Nilce Ortiz Sabine Neusatz Guilhen Nuclear and Energy Research Institute IPEN/SP S&atildeo Paulo Brazil

In the mid-20th century, the Malaria Institute in Brazil researched hexachlorocyclohexane (HCH), dichlorodiphenyltrichloroethane (DDT), and other organochlorines in Cidade dos Meninos, Rio de Janeiro, Brazil. After Malaria Institute closure, there was a 200-ton stock of chemicals compounds abandoned without any surveillance, which led to massive contamination of the nearby community by carcinogenic organochlorines. This article presents a new review of the Cidade dos Meninos’ case, analyzing the HCH and DDT contamination using a Haddon Matrix and Regional Screening Levels (RSL).

关键词： Organochlorines DDT HCH Cidade Dos Meninos Contamination environmental chemistry Haddon Matrix RSL

GIS and Remote Sensing Applications in Biogeography and Ecology 1

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Dynamic Modeling of environmental Systems 1

丛书名： The Springer International Series in Engineering and Computer Science

2001年

作者： Andrew C. Millington Stephen J. Walsh Patrick E. Osborne

ISBN: (数字)9781461515234

ISBN: (纸本)9780792374541;9781461355960

In recent years, the conservation of tropical forests has received worldwide publicity whereas effective forest management, particularly for timber extraction, has attracted little attention and gained some notoriety. The overall aim of the present paper was to examine how environmental micro-variation in the Chiquibul Forest Reserve of Belize can influence species distribution and thereby inform management strategy. The paper deals first with the background to forest management in Belize, then considers the methodology used in the present study and fin~~ly assesses the preliminary results. The specific objectives are: (1) to assess the effects of changing scale on the variability of selected individual soil properties in forest plots within the same vegetation class; and (2) to examine the variation in soil properties and tree species distribution, and to integrate environmental and ecological data over a range of scales. BACKGROUND Whereas the global and regional distribution of tropical forests is broadly governed by climatic and altitudinal variation, individual forest tracts need to consider a range of other, locally important factors to explain species distribution and change. With very high species diversity, tropical forests present a major challenge in the attempt to unravel controlling factors in distribution and growth (Swaine et aI. 1987). Research that attempts to explain diversity has looked at species distribution according to a range of factors, with a general recognition that soil fertility plays a significant if ill defined role (Swaine 1996).

关键词： Geographical Information System Ecology environmental chemistry Physical Geography

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超疏水多孔泡沫的宏量制备及其在油水分离中的应用

丛书名： Modeling Dynamic Systems

2000年

作者： Michael L. Deaton James J. Winebrake

ISBN: (数字)9781461213000

ISBN: (纸本)9780387988801;9781461270850

Dynamic Modeling of environmental Systems is a primer on using models to understand environmental problems. With their many natural, economic, political, and technical aspects, environmental problems require a systems approach. This book provides an introduction to modeling concepts and applications that is specifically geared toward the environmental field. Sections on modeling terminology, the uses of models, the model-building process, and the interpretation of output provide the foundation for detailed applications. After an introduction to the basics of dynamic modeling, the book leads students through an analysis of several environmental problems, including surface-water pollution, matter-cycling disruptions, and global warming. The scientific and technical context is provided for each problem, and the methods for analyzing and designing appropriate modeling approaches is provided. While the mathematical content does not exceed the level of a first-semester Calculus course, the book gives students all of the background, examples, and practice exercises needed both to use and understand environmental modeling. It is suitable for upper-level undergraduate and beginning-graduate-level environmental science courses. The text is also useful for environmental professionals seeking an introduction to modeling in their field.

关键词： Mathematical Modeling and Industrial Mathematics environmental Sciences Ecology Applied Ecology environmental Management environmental chemistry

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超疏水多孔泡沫的宏量制备及其在油水分离中的应用