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Journal of Bioresources and Bioproducts 2020年第4期5卷 276-282页

作者： Yanyan Wang Mengxing Zhao Tingzhi Liu Tianjin Key Laboratory of Pulp and Paper Tianjin University of Science and TechnologyTianjin 300457China

In this study,allelochemicals were extracted from pulping effluents rather than from the raw ma-terial of plants.Herein,five organic solvents(ethyl acetate(EAC),methyl tert-butyl ether(MTBE),dichloromethane(DCM),carbon tetrachloride(CTC),and petroleum(PE))were applied to sep-arately extracting the allelochemicals from alkaline peroxide mechanical pulp(APMP)effluents.The results from the algal density,inhibition ratio,and optical density of 446 nm(OD 446nm)concluded that the extractives from the APMP effluents can act as effective allelochemicals and showed noticeable allelopathic inhibition effects on Microcystis aeruginosa growth.The results in-dicated that organic solvent extraction could be a practical approach to isolate the allelochemicals from the APMP effluents,which would broaden the potential application of the APMP effluents in the production of antimicrobial agents and other value-added materials.

关键词： Allelopathic inhibition Allelochemicals Organic solvent extraction Microcystis aeruginosa Alkaline peroxide mechanical pulping(APMP) effluents

Alkaline Hydrolysis to Reduce the AOX Concentrations in effluents from Chlorination Treatment of Wool

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Journal of China Textile University(English Edition) 1999年第1期16卷 53-55页

作者：朱泉闫茹 China Textile Univ Shanghai China

Organic halogens generated in the chlorlnatlon treatment of wool are proven to be acutely toxic to human beings. Legislation on environmental pollution has become more and more stringent in recent years. So the chlorlnation treatment is faced with disuse. Alkaline hydrolysis is adopted to reduce the AOX (Absorbable Organic Halogen) concentrations in the effluents from the chlorlnatlontreatment under 40℃ and pH values 9, 10, 11 and 12. After treatment the reduction of AOX appears approximately 65%.

关键词： wool chlorination treatment effluents organic halogens AOX alkaline hydrolysis reduction of AOX.

The Physico-Chemical Quality of effluents of Selected Sewage Treatment Plants Draining into River Rwizi, Mbarara Municipality, Uganda

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Journal of Water Resource and Protection 2019年第1期11卷 20-36页

作者： Jeninah Atwebembeire Morgan Andama Jane Yatuha Julius Bunny Lejju Grace Kagoro Rugunda Joel Bazira Department of Biology Faculty of Science Mbarara University of Science and Technology Mbarara Uganda Department of Biology Faculty of Science Muni University Arua Uganda Department of Microbiology Faculty of Medicine Mbarara University of Science and Technology Mbarara Uganda

As population increases in urban areas, the domestic and industrial activities increase resulting in an increase in the volumes of wastewater and anthropogenic pollution, hence posing a threat to public health and environment. This study assessed the physical chemical quality of two main sewage plant effluents discharging into River Rwizi. Effluent water samples were analyzed for dissolved oxygen, colour, turbidity, total suspended solid, total iron, phosphates, alkalinity, magnesium, calcium carbonate, temperature, pH, ammonium, electrical conductivity, chloride and nitrates. Parameters were analyzed following standard methods of APHA (1985). The values obtained were compared with EPA (2001), NWSC (2015) and NEMA (1999) standards for waste water. Results showed that the mean values most of the parameters tested were higher than the recommended EPA, NWSC and NEMA standards. The mean colour was 1627.67°C and 1414.33°C in Kakoba and Taso sewage effluents respectively compared to EPA (20-150), NWSC (500) and NEMA (300) standards (p > 0.05). The mean alkalinity was 1390.17 mg/l and 1308.33 mg/l for Kakoba and Taso respectively compared with EPA (400) and NWSC (800) standards. DO had a mean concentration of 68.27 mg/l and 63.03 mg/l in Taso and Kakoba respectively compared to EPA and NEMA standard of 5 mg/l. Mg was 243.29 mg/l and 246.49 mg/l in Kakoba and Taso sewage effluents respectively compared to NEMA standard for waste water of 100 mg/l (p > 0.05). The mean pH was 8.26 and 8.16 in Taso and Kakoba sewage effluents respectively compared to NWSC and NEMA standard of 6.0 - 8.0. Phosphate mean concentration levels were 32.2 mg/l and 27.11 mg/l for Taso and Kakoba respectively compared to standards of EPA (0.5 - 0.7 mg/l) and NEMA (10 mg/l). NO3 was 10 mg/l and 5.83 mg/l in Kakoba and Taso sewage effluents respectively compared to NWSC maximum permissible limit of 5 mg/l. The mean NH4 concentration was 385.33 mg/l (Kakoba) and 50.0 mg/l (Taso) compared to the EPA guideline range (0.2 - 4 mg/l). Chloride (Cl) had a me

关键词： Physico-Chemical effluents Sewage River Rwizi Mbarara Municipality

Comparison of Different Sampling Techniques for the Identification of Aromatic Hydrocarbons from Fire effluents

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American Journal of Analytical Chemistry 2019年第1期10卷 23-37页

作者： Abdulrhman M. Dhabbah A. Yacine Badjah-Hadj-Ahmed Anna A. Stec T. Richard Hull King Fahd Security College Riyadh Kingdom of Saudi Arabia Chemistry Department College of Science King Saud University Riyadh Kingdom of Saudi Arabia Centre for Fire Hazards and Science School of Physical Sciences and Computing University of Central Lancashire Preston UK

Huge amounts of various polymers are being used in many fields with numerous benefits. However, their great ability to ignition and rapid flame spreading make these materials dangerous for human life and properties due to the release of highly toxic combustion products. The present work aims to investigate several methods of sampling and identification of aromatic hydrocarbons produced by controlled burning of low-density polyethylene (LDPE) using a toxicity tube furnace. Five different sampling methods were used: solid phase micro extraction (SPME), syringe, tedlar bags, sorption tubes, and gas-solution absorbers (midget impingers). The produced hydrocarbons were analysed by gas chromatography coupled to mass spectrometry with and without pyrolysis. Among the tested techniques, the most convenient sampling method was using syringe with a glass vessel which allowed detection of the highest amount of aromatic hydrocarbons at both 800°C and 600°C, and then followed by SPME. On the other hand, the use of gas-solution absorber (midget impinger) showed poorer results. Regarding the use of tedlar bags and sorption tubes, they did not give satisfactory results. Several carcinogenic or possibly carcinogenic compounds were identified in the combustion products, such as benzene, naphthalene, anthracene and pyrene.

关键词： Polyethylene Combustion Fire effluents Sampling Polycyclic Aromatic Hydrocarbons GC-MS

Heavy Metals Accumulation in Soil Irrigated with Industrial effluents of Gadoon Industrial Estate, Pakistan and Its Comparison with Fresh Water Irrigated Soil

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Journal of Agricultural Chemistry and Environment 2014年第2期3卷 80-87页

作者： Noor Amin Dawood Ibrar Sultan Alam Department of Chemistry Abdul Wali Khan University Mardan Pakistan Department of Chemistry University of Malakand Chakdara Pakistan

Wastewater mixed with industrial effluents is used for irrigation in Gadoon Industrial estate and thus contaminating soil. This soil was tested for heavy metal content by using atomic absorption spectrophotometer (perkin elmer 700) and compared with control soil irrigated with tube well water at seven selected spots. Accumulation of the toxic metal was significantly greater in the soil irrigated with industrial effluent than control soil (p < 0.05). Manganese (Mn) was the most significant pollutant, accumulated up to 9.95 ppm in the soil irrigated with industrial waste water. It was found that the samples were containing Zn in the range of 1.596 - 6.288, Cu 0.202 - 1.236, Co 0.074 - 0.115, Ni 0.0002 - 0.544, Cr 0.243 - 0.936, Mn 3.667 - 9.955 and Pb 0.488 - 1.259 ppm. No sample was containing the heavy metal above the critical level mentioned in typical and unsafe heavy metal levels in soil.

关键词： Industrial effluents Soil Tube Well Water Heavy Metals Pollutio

Isotherm and Thermodynamic Studies on the Bio Adsorption of Textile Industrial effluents onto Chitosan Nanoparticle from Macolor Niger (White Snapper)

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Journal of Biomaterials and Nanobiotechnology 2019年第1期10卷 1-10页

作者： Gokulalakshmi Elayaperumal Bhaskaran Sathyapriya M. Vanitha Chinnathambi Human Genetics Laboratory Sree Balaji Dental College and Hospital Bharath Institute of Higher Education and Research Chennai Tamilnadu India Department of Anatomy Sree Balaji Dental College and Hospital Bharath Institute of Higher Education and Research Chennai Tamilnadu India Department of Biotechnology Guru Nanak College Chennai Tamilnadu India

Fish scale wastes are generally discarded in the environment through fish processing industries and local market vendors. It is one of the excellent and efficient renewable bioproducts. Consequently, a number of bioactive compounds have been identified including bioactive peptides, collagen, chitosan, and gelatin which are commercially marketed. The current study involves the extraction and generation of chitosan nanoparticles from fish scales. The synthesized chitosan nanosubstances were categorized by Field Emission Scanning Electron Microscopy (FESEM). The viability of utilizing fish scales as an economical bio-adsorbent for elimination of textile dye was studied on industrial effluent. Fourier transform infrared spectroscopy (FTIR) was used to study the dye adsorption of chitosan nanoparticles before and after the dye treatment. With chitosan nanoparticle treatment of the textile effluents, removal of COD was improved to 80% and the turbidity removal efficiency was improved up to 90%. Thus, the present study provides an excellent bio-adsorbent chitosan nanoparticle generated from fish scales which have potential application as an adsorbent in bioremediation like wastewater treatment.

关键词： Chitosan Nanoparticle Fish Scale Bio Adsorption Textile effluents

Ways of Analysis of Fire effluents and Assessment of Toxic Hazards

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Journal of Analytical Sciences, Methods and Instrumentation 2015年第1期5卷 1-12页

作者： Abdulrhman M. Dhabbah Department of Forensic Science King Fahad Security College Riyadh Saudi Arabia

Fire effluents, in most cases, have an adverse effect on human health and the environment. Exposure to some compounds may show both acute and chronic toxicity. There is a lack of knowledge on the effect of organic products on the human body in terms of the rate of organic material production in fires and their degree of toxicity. Thus, there is a need to expand the scope of studies about the organic products generated from fires and improve the methods of assessment to be included as part of fire hazard assessment. Different factors can be contributed to this lack of knowledge. For example, the composition of organic products generated from fires changes progressively and rapidly with progression of combustion and in a manner that is dependent on the fire condition. It is difficult to identify individual organic compounds produced during combustion. Another key factor is the lack of suitable instruments for measuring organic products generated from a fire. Also, the lack of procedures that are used to evaluate the lethal concentration limits and the lethal dose for a broad range of organic compounds generated from a fire may be another important factor which can be contributed to this lack of knowledge.

关键词： Fire effluents Volatile Organic Compounds (VOCs) Semi-Volatile Organic Compounds (SVOCs) Polycyclic Aromatic Hydrocarbons (PAHs) Dioxins Isocyanates

Removal of Carbonyl-Containing effluents by Photodegradation Using β-Carotene Embedded onto Zinc Oxide Particles

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Journal of Health Science 2019年第4期7卷 262-272页

作者： Bakari Chaka Aloys Mosima Osano Department of Mathematics and Physical SciencesSchool of Science and Information SciencesMaasai Mara UniversityNarok 20500Kenya

Environmental pollution especially in the form of effluent wastewater from industries has been a major challenge. Carbonyl-containing organic standards and sewage sample were effectively photo degraded. ZnO nanoparticles were prepared by emulsification of zinc-carbamate solution using 1 N NaOH and grafted chemically by Molecular Layer Doping method at 180 °C with β-carotene extracted using methanol by refluxing at 50 °C at varying concentrations. Intrinsic and grafted β-carotene ZnO were characterized using FTIR (Fourier transform infrared spectroscopy) and their spectra differed in an additional peak at around 1,435 nm corresponding to the organ metallic bond Zn-C. UV-Vis spectra of the two composites indicated a blue shift in the grafted samples. This translated to a reduced band gap from 3.5 eV to 3.4 eV. Comparison in the rates of photodegradation of pure organic compounds, organic effluents and color change of dyes was in the order 1% grafted, 0.5% grafted, intrinsic ZnO and blank sample. When 10.0 mL of sewerage water was photo degraded using both sunlight and UV-Lamp for 40 minutes, the amount of carbonyls present decreased by 28.5% for β-carotene grafted ZnO, 24.5% for intrinsic ZnO and 0.6% for a blank sample.

关键词： Intrinsic ZnO β-carotene organic effluents carbonyls photo-degradation

Laboratory scale studies on removal of chromium from industrial wastes

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Journal of Environmental Sciences 2003年第3期15卷 417-422页

作者： M.A.Baig Mohsin Mir Shazad Murtaza Zafar I. Bhatti Institute of Environmental Science & Engineering National University of Science & EngineeringInstitute of Environmental Science & Engineering National University of Science & EngineeringInstitute of Environmental Science & Engineering National University of Science & EngineeringInstitute of Environmental Science & Engineering National University of Science & Engineering Rawalpindi PakistanRawalpindi PakistanRawalpindi PakistanRawalpindi Pakistan

Chromium being one of the major toxic pollutants is discharged from electroplating and chrome tanning processes and is also found in the effluents of dyes, paint pigments, manufacturing units etc. Chromium exists in aqueous systems in both trivalent (Cr 3+) and hexavalent (Cr 6+) forms. The hexavalent form is carcinogenic and toxic to aquatic life, whereas Cr 3+ is however comparatively less toxic. This study was undertaken to investigate the total chromium removal from industrial effluents by chemical means in order to achieve the Pakistan NEQS level of 1 mg/L by the methods of reduction and precipitation. The study was conducted in four phases. In phase Ⅰ, the optimum pH and cost effective reducing agent among the four popular commercial chemicals was selected. As a result, pH of 2 was found to be most suitable and sodium meta bisulfate was found to be the most cost effective reducing agent respectively. Phase Ⅱ showed that lower dose of sodium meta bisulfate was sufficient to obtain 100 % efficiency in reducing Cr 6+ to Cr 3+, and it was noted that reaction time had no significance in the whole process. A design curve for reduction process was established which can act as a tool for treatment of industrial effluents. Phase Ⅲ studies indicated the best pH was 8.5 for precipitation of Cr 3+ to chromium hydroxide by using lime. An efficiency of 100 % was achievable and a settling time of 30 minutes produced clear effluent. Finally in Phase Ⅳ actual waste samples from chrome tanning and electroplating industries, when precipitated at pH of 12 gave 100 % efficiency at a settling time of 30 minutes and confirmed that chemical means of reduction and precipitation is a feasible and viable solution for treating chromium wastes from industries.

关键词： tannery waste effluents reduction precipitation efficiency chromium

Distribution and ecological risks of heavy metals in Lake Hussain Sagar,India

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Acta Geochimica 2020年第2期39卷 255-270页

作者： Arulpoomalai Ayyanar Shashidhar Thatikonda Department of Civil Engineering Indian Institute of Technology HyderabadKandiTelangana 502285India

Lake contamination by anthropogenic activities has become a serious threat to the aquatic ecosystem due to the presence of a high concentration of toxic heavy metals.In this study,a contaminated Lake Hussain Sagar in India was assessed for toxic heavy metal pollutants at sites associated with industrial discharges and idol immersion activities.The observed high concentration of As,Cd,Pb,Zn,Cu,and Ni in the surface water was due to industrial effluent discharge.About 1.5 times the high concentration of the same elements were observed in surface sediments(0-10 cm)by both industrial discharges and idol immersion activities,compared to deep sediments(0-40 cm)associated only with industrial discharge.The depth-wise variation of heavy metal concentration in surface sediments is due to sorption and settling behavior of suspended solids;whereas in deep sediment,it is due to constant loading of effluents,over a period of time.The sorption capacity of surface sediments is in increasing order as Pb>Cd≥Ni>Cr>Zn>Cu,and the desorption revealed that Pb and Cu were retained to a greater extent due to high clay and organic content.By fractionation study,20-50%of Zn and 50-80%of Cd were associated with exchangeable and carbonate fraction of sediments.By risk assessment code,Zn and Cd are classified under high risk to a very high-risk category,and Cr,Pb,Ni,and Cu are classified under the medium risk category.The enrichment factor value of sediments for Cd(20.42-119.48),Zn(2.19-4.85),Cu(2.02-3.19),and Pb(2.85-7.72)signifies the significant pollution by anthropogenic activities.Therefore,this study evaluates the intensity and distribution of heavy metals in the lake environment for remediation and restoration of the lake ecosystem.

关键词： Trace metals Lake sediment Geochemistry Speciation Industrial effluents Idol immersion