检索结果-南通市图书馆

Striking Stabilization Effect of Spinel Cobalt Oxide Oxygen Evolution Electrocatalysts in Neutral pH by dual-sites iron Incorporation

引用

Energy & Environmental Materials 2024年第2期7卷 156-164页

作者： Shuairu Zhu Xue Wang Jiabo Le Na An Jianming Li Deyu Liu Yongbo Kuang Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Zhejiang Institute of Tianjin University Research Center of New Energy Research Institute of Petroleum Exploration & Development Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences

Developing stable and efficient nonprecious-metal-based oxygen evolution catalysts in the neutral electrolyte is a challenging but essential goal for various electrochemical ***,cobalt-based spinels have drawn a considerable amount of attention but most of them operate in alkali ***,the frequently studied Co-Fe spinel system never exhibits appreciable stability in nonbasic conditions,not to mention attract further investigation on its key structural motif and transition states for activity ***,we report exceptional stable Co-Fe spinel oxygen evolution catalysts（～30% Fe is optimal） in a neutral electrolyte,owing to its unique metal ion arrangements in the crystal *** introduced iron content enters both the octahedral and tetrahedral sites of the spinel as Fe2+and Fe3+（with Co ions having mixed distribution as well）.Combining density functional theory calculations,we find that the introduction of Fe to Co3O4lowers the covalency of metal-oxygen bonds and can help suppress the oxidation of Co2+/3+and O2-.It implies that the Co-Fe spinel will have minor surface reconstruction and less lattice oxygen loss during the oxygen evolution reaction process in comparison with Co3O4and hence show much better *** findings suggest that there is still much chance for the spinel structures,especially using reasonable sublattices engineering via multi metal doping to develop advanced oxygen evolution catalysts.

关键词： dual-sites iron electrocatalyst stability neutral electrolyte oxygen evolution reaction spinel oxides

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：