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Study on Active Oxygen Quantum Yield,Insecticidal Activities and Stability of diphenylthiophene

Agricultural Sciences in China 2007年第4期6卷 458-465页

作者： CHEN Xiao-jun XU Han-hong WANG Yu-jian HU Shan ZHANG Zhi-xiang ZHANG Yao-mou Key Laboratory of Pesticide and Chemical Biology Ministry of Education/Laboratory of Insect Toxicology South China Agricultural University Guangzhou 510642 P.R.China

Active oxygen quantum yield, insecticidal activities and stability of diphenylthiophene were studied for the first time. The results showed that maximum diphenylthiophene absorbency variety was 0.438 after irradiation for 280 min and that of α- terthienyl （α-T） was 0.480 after irradiation for 200 min with UV. LCs0 values ofdiphenylthiophene and α-T against 3rd instar larvae ofAedes albopictus were 9.18 × 10^-3 and 9.69× 10^-4 μg mL^-1 when treated for 24 h, respectively. LC50 values of the two chemicals against the 3rd instar larvae of Plutella xylostella were 267.87 and 222.22 μg mL^-1 when treated for 24 h, respectively. The half lives of diphenylthiophene and α-T in methanol were 113.62 and 10.65 h. Difference between quantum yield of diphenylthiophene and α-T was not significant and they all possessed high toxicity to Aedes albopictus and Plutella xylostella, but diphenylthiophene was more stable than α-T. It could be concluded that diphenylthiophene has overcome the deficiency of photoactivated insecticides which degraded quickly in the environment and could not be applied on the field. diphenylthiophene could kill the insects and accelerate the degradation rate of triazophos. The benefits of diphenylthiophene can be further exploited and applied on the field.

关键词： diphenylthiophene insecticidal activities photocatalysis degradation

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