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desulfurization kinetics of ZnO sorbent loaded on semi-coke support for hot coal gas

Journal of Natural Gas Chemistry 2012年第5期21卷 556-562页

作者： Zhiwei Ma Xianrong Zheng Liping Chang Ruiyuan He Weiren Bao Key Laboratory of Coal Science and Technology Taiyuan University of TechnologyMinistry of Education and Shanxi ProvinceTaiyuan 030024ShanxiChina

Zn-based sorbent （Z20SC） prepared through semi-coke support in 20 wt% zinc nitrate solution by high-pressure impregnation presents an excellent desulfurization capacity in hot coal gas,in which H2 S can not be nearly detected in the outlet gas before 20 h breakthrough *** effects of the main operational conditions and the particle size of Z20SC sorbent on its desulfurization performances sorbent were investigated in a fixed-bed reactor and the desulfurization kinetics of Z20SC sorbent removing H2 S from hot coal gas was calculated based on experimental *** showed that the conversion of Z20SC sorbent desulfurization reaction increased with the decrease of the particle size of the sorbent and the increases of gas volumetric flow rate,reaction temperature and H 2 S content in inlet gas.Z20SC sorbent obtained from hydrothermal synthesis by high-pressure impregnation possessed much larger surface area and pore volume than semi-coke support,and they were significantly reduced after the desulfurization *** equivalent grain model was reasonably used to analyze experimental data,in which k s=4.382×10-3 exp（-8.270×103/RgT） and Dep=1.262×10-4exp（1.522×104/RgT）.It suggests that the desulfurization reaction of the Z20SC sorbent is mainly controlled by the chemical reaction in the initial stage and later by the diffusion through the reacted sorbent layer.

关键词： desulfurization kinetics Zn-based sorbent hot coal gas medium-temperature desulfurization

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Fractal desulfurization kinetics of high-sulfur coal

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International Journal of Mining Science and Technology 2012年第1期22卷 111-114页

作者： Xu Longjun Peng Tiefeng Zhang Dingyue Zhang Fukaia State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing UniversityChongcling 400044China School of Chemical Engineering University of QueenslandBrisbane.OLD 4072Australia

The pore structure characteristics of high-sulfur coal from Wansheng in Chongqing have been studied by a nitrogen adsorption method （BET）. The effects of grinding and pre-treating with nitric acid on the inorganic sulfur content of coal have been investigated. Organic sulfur in coal pretreated with nitric acid was desulfurized by using propylene-glycol-KOH （PG-KOH）. Fractal kinetic properties of these two desulfurization procedures were investigated by using fractal geometric theory. The results show that both the specific surface area and pore volume increased with the decrease in particle diameter. The microspore surface of coal had fractal characteristics; the fractal dimension was 2.48. The sulfur content decreased with the decrease in particle diameter by grinding. After pretreatment with nitric acid, the desulfurization ratio （DFR） of inorganic sulfur increased to over 99% and the DFR of total sulfur to over 70%. The desulfurization procedure of inorganic sulfur had fractal kinetic characteristics; its reactive frac- tal dimension was 2.94. The organic sulfur desulfurization procedure by PG-KOH was also tallied with fractal kinetic properties; the reactive fracta! dimension was 2.57. The effect of temperature on the desul- furization ratio of organic sulfur can be described with an Arrhenius empirical equation. The rate constant, pre-exponential factor and the activation energy of the reaction increased with the decrease in particle diameter.

关键词： Coal desulfurization kinetics Fractal Particle diameter Nitric acid Propylene-glycoI-KOH

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