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Switchable polyolefins from Polar Functionalization to Degradability

CCS Chemistry 2024年第8期6卷 1941-1950页

作者： Kangkang Li Zhongbao Jian State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022 School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026

polyolefins are synthetic plastics that exist on the largest scale and are ubiquitous in human *** are also the most frequently discarded ***,the ability to either upgrade polyethylene(PE)plastic for value-added applications or to degrade PE plastic for value-added chemicals and monomers is highly desirable and sought after to mitigate the plastic waste ***,we report an advanced strategy for tackling the issue of PE plastics,first through a sequential upgrading and then through a degrading *** optimal Diels–Alder-type polar comonomer diester-substituted norbornadiene is copolymerized with ethylene to produce the desired polar-functionalized PEs with both high comonomer incorporations of 42.4 mol%(-COOMe:as high to 59.6 mol%)and high molecular weights of up to 224 kg mol^(−1)in high catalytic activities of>100 kg mol^(−1)h^(−1).By means of a decisive retro-Diels–Alder reaction,this upgraded PE,namely polar-functionalized PE,can completely switch to a clean and soluble vinylene PE with a high content(28.7 mol%)of dispersed internal double bonds,which are *** of the highmolecular–weight(∼30 kg mol^(−1))vinylene PE with ethylene yields industrially relevant telechelic oligomers(∼360 g mol^(−1))of long-chainα,ω-dienes and C9/C9+hydrocarbon *** chemical upgrading and recycling method makes polyolefin plastic more sustainable.

关键词： chemical recycling plastics polar polyolefin degradable polyolefin cyclic olefin

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